4.8 Article

Covalently-grafted polyaniline on graphene oxide sheets for high performance electrochemical supercapacitors

Journal

CARBON
Volume 71, Issue -, Pages 257-267

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2014.01.037

Keywords

-

Ask authors/readers for more resources

A simple route to achieve covalently-grafted polyaniline (PANI)/graphene oxide (GO) nanocomposites has been developed. The synthesized composites showed a uniform hierarchical morphology of the PANI thin film and short rod-like nanostructures that had densely grown on the GO sheets, in contrast to the nonuniform morphology of noncovalently-grafted PANI/GO. Compared to pure PANI and noncovalently-grafted PANI/GO composites, the covalently-grafted PANI/GO composites possessed a much larger specific surface area and pore volume, which increased the accessible surface area for the redox reaction and allowed faster ion diffusion. This unique hierarchical morphology maximized the synergistic effect between PANI and GO, resulting in excellent electrochemical performance (capacitance 442 F/g of PANI/GO (6:1) vs. 226 F/g of pure PANI) and improved cycling stability (83% @ 2000 cycles of PANI/GO (6:1) vs. 54.3% @ 1000 cycles of pure PANI). The enhanced electrochemical performance demonstrates the advantage of the PANI/GO composites prepared via this covalent grafting method. (C) 2014 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Biophysics

Simultaneous colorimetric and electrochemical detection of trace mercury (Hg2+) using a portable and miniaturized aptasensor

Ana M. Ulloa-Gomez, Alec Lucas, Abbey Koneru, Amit Barui, Lia Stanciu

Summary: We have developed a novel aptasensor that can detect mercury (Hg2+) through both colorimetric and electrochemical methods. This device is portable, rapid, and versatile, and can detect Hg2+ down to 0.01 ppm. It shows high selectivity against other heavy metals and offers a dual detection platform with quantification and multiplexing capabilities.

BIOSENSORS & BIOELECTRONICS (2023)

Article Biophysics

Smartphone-based colorimetric detection of cardiac troponin T via label-free aptasensing

Ana M. Ulloa-Gomez, Alejandra Agredo, Alec Lucas, Sandeep B. Somvanshi, Lia Stanciu

Summary: We developed an aptasensing platform for the detection of cTnT in the immediate and early phases of AMI. The platform uses a microfluidic paper-based analytical device modified with gold-decorated polystyrene microparticles functionalized with a highly specific cTnT aptamer. The platform showed high selectivity and stability, and provides a label-free, smartphone-based detection method with shorter processing time compared to traditional methods.

BIOSENSORS & BIOELECTRONICS (2023)

Article Nanoscience & Nanotechnology

Cold Atmospheric Plasma-Assisted Direct Deposition of Polypyrrole-Ag Nanocomposites for Flexible Electronic Sensors

Ulisses Heredia-Rivera, Venkat Kasi, Akshay Krishnakumar, Sachin Kadian, Amit Kumar Barui, Zihao He, Haiyan Wang, Lia Stanciu, Rahim Rahimi

Summary: Cold atmospheric plasma-assisted deposition technology is a solvent-free and scalable method for in situ polymerization and direct deposition of conductive polypyrrole-silver nanocomposites. By adjusting the precursor composition, PPy-Ag nanocomposite films with tunable degrees of polymerization and Ag nanoparticle loading can be fabricated.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Nanoscience & Nanotechnology

Manganese and Cobalt-Free Ultrahigh-Ni-Rich Single-Crystal Cathode for High-Performance Lithium Batteries

Adil Saleem, He Zhu, Muhammad K. Majeed, Rashid Iqbal, Bushra Jabar, Arshad Hussain, M. Zeeshan Ashfaq, Muhammad Ahmad, Sajid Rauf, Jean Pierre Mwizerwa, Jun Shen, Qi Liu

Summary: Current commercial nickel (Ni)-rich cathodes for high-energy lithium (Li) batteries often contain toxic and expensive Mn/Co, which causes issues like transition-metal dissolution and surface degradation. This study compares a Mn/Co-free Ni-rich Li-Ni0.94Fe0.05Cu0.01O2 (SCNFCu) cathode with acceptable electrochemical performance to a Mn/Co-containing cathode. Despite slightly lower discharge capacity, SCNFCu cathode maintains 77% of its capacity after 600 cycles, outperforming the high-Ni LiNi0.9Mn0.05Co0.05O2 (SCNMC) cathode (66%). Fe/Cu ions in the SCNFCu cathode reduce structural disintegration, undesirable reactions, and Li loss. This discovery opens up new possibilities for developing Mn/Co-free cathode materials for next-generation high-energy Li batteries with the flexibility and scalability of SCNFCu.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Chemistry, Physical

Structurally Robust Honeycomb Layered Strontium Iridate as an Oxygen Evolution Electrocatalyst in Acid

Lina Wang, Lei Shi, Qi Liu, Yalan Huang, Wensheng Yan, Xiao Liang, Xiao Zhao, Hui Chen, Xiaoxin Zou

Summary: We report the synthesis and characterization of honeycomb layered strontium iridate (SrIr2O6) as an efficient electrocatalyst for the acidic oxygen evolution reaction (OER) with robust structural stability. Unlike most iridate catalysts, SrIr2O6 can maintain its crystalline structure during OER instead of forming an amorphous active phase. The edges of SrIr2O6 demonstrate high catalytic activity for OER following the adsorbate evolution mechanism, while the basal planes are catalytically inert. SrIr2O6 exhibits about 10-fold higher intrinsic activity than the benchmark catalyst IrO(2), with minimal iridium leaching (approximately 0.03%) and long-term catalytic stability for over 300 hours.

ACS CATALYSIS (2023)

Article Chemistry, Physical

Molten Salt-Assisted Synthesis of Single-Crystalline Nonstoichiometric Li1+xNi1-xO2 with Improved Structural Stability

Guoyu Ding, Meng Yao, Jinhan Li, Tingting Yang, Yudong Zhang, Kuiming Liu, Xinhui Huang, Zhonghan Wu, Jiayu Chen, Ziyan Wu, Jiayong Du, Changru Rong, Qi Liu, Wei Zhang, Fangyi Cheng

Summary: In this study, nonstoichiometric Li1+xNi1-xO2 with submicron particle size and superior rate performance was successfully synthesized by molten salt-assisted synthesis combined with a Li-refeeding strategy. The single-crystalline Li1.045Ni0.955O2 exhibited high specific capacity, considerable rate capability, and initial Coulombic efficiency, outperforming near stoichiometric LiNiO2. This study highlights the significance of molten salt-assisted synthesis and Li-refeeding modification in upgrading Ni-based layered oxide cathode materials for advanced Li-ion batteries.

ADVANCED ENERGY MATERIALS (2023)

Article Chemistry, Applied

Towards extreme fast charging of 4.6 V LiCoO2 via mitigating high-voltage kinetic hindrance

Yu Tang, Jun Zhao, He Zhu, Jincan Ren, Wei Wang, Yongjin Fang, Zhiyong Huang, Zijia Yin, Yalan Huang, Binghao Zhang, Tingting Yang, Tianyi Li, Leighanne C. Gallington, Si Lan, Yang Ren, Qi Liu

Summary: Experiments combined with density functional theory calculations demonstrate that the co-doping of Mg2+ and Gd3+ can mitigate the kinetic limitations of high-voltage LiCoO2 cathode, improving the diffusion mobility of lithium ions and enabling a more homogeneous charge/discharge process. The doped LCO exhibits extreme fast charging capability and high-rate capacity retention when used with a Li metal anode.

JOURNAL OF ENERGY CHEMISTRY (2023)

Article Multidisciplinary Sciences

Predicting battery impedance spectra from 10-second pulse tests under 10 Hz sampling rate

Xiaopeng Tang, Xin Lai, Qi Liu, Yuejiu Zheng, Yuanqiang Zhou, Yunjie Ma, Furong Gao

Summary: Onboard measuring the electrochemical impedance spectroscopy (EIS) for lithium-ion batteries has been a challenging issue for the development of technologies like portable electronics and electric vehicles. In this study, we propose a fast and accurate EIS predicting system by combining the fractional-order electric circuit model with a median-filtered neural network machine learning. Our method allows using size-varying input data sampled at a rate down to 10 Hz and unlocks opportunities to detect the battery's internal electrochemical characteristics onboard via low-cost embedded sensors.

ISCIENCE (2023)

Article Chemistry, Physical

Enabling high-performance 4.6 V LiCoO2 in a wide temperature range via a synergetic strategy

Jincan Ren, Yu Tang, Weibao Li, Dong He, He Zhu, Xingyu Wang, Si Lan, Zijia Yin, Tingting Yang, Zhaowen Bai, Yang Ren, Xiangheng Xiao, Qi Liu

Summary: A synergetic strategy of La, Mg co-doping and LiAlO2@Al2O3 surface coating is designed to enhance the performance of LiCoO2 (CM-LCO) cathode material under extreme temperatures. CM-LCO exhibits excellent temperature adaptability and remarkable electrochemical performance, as well as excellent cycle stability and high-rate performance. The synergistic effects of this co-modification strategy are demonstrated by investigating the electrochemical reaction kinetics and structure evolution of CM-LCO, providing a promising strategy for the application of high-voltage LCO in a wide temperature range.

ECOMAT (2023)

Article Chemistry, Multidisciplinary

The d-orbital coupling modulation of CuNi alloy for acetonitrile electrochemical reduction and in-situ hydrogenation behavior characterization

Boling Liu, Dong He, Zunjian Ke, Hongbo Wang, Chongyang Tang, Qi Zhang, Hang Xu, Menghua Yang, Yafei Yang, Qi Liu, Xiangheng Xiao

Summary: The catalytic performance of CuNi alloy ultrafine-nano-particles synthesized through electrodeposition in the acetonitrile reduction reaction (ACNRR) has been systematically studied. It is found that CuNi alloy achieves a high ethylamine Faradic efficiency (FE) and good stability at high current density. Furthermore, CuNi alloy can also hydrogenate acetonitrile in the presence of other organics, showing high ethylamine FE.

SCIENCE CHINA-CHEMISTRY (2023)

Article Chemistry, Physical

P3-Na0.45Ni0.2Mn0.8O2/Na2SeO4 Heterostructure Enabling Long-Life and High-Rate Sodium-Ion Batteries

Tianyi Song, Chenchen Wang, Lei Kang, Wenjiao Yao, Heyi Wang, Huige Chen, Qi Liu, Yang Lu, Zhiqiang Guan, Anquan Zhu, Tianxing Kang, Yongbing Tang, Chun-Sing Lee

Summary: In this study, a potential Na+ conductor Na2SeO4 was discovered to form a heterostructure P3-Na0.45Ni0.2Mn0.8O2/Na2SeO4, which effectively promotes Na+ diffusion and suppresses P3-O3 phase transitions. This heterostructure exhibits excellent rate performance and cycling stability.

ADVANCED ENERGY MATERIALS (2023)

Article Chemistry, Physical

High-kinetic and stable antimony anode enabled by tuning coordination environment for ultrafast aqueous energy storage

Qiyu Liu, Haozhe Zhang, Jinhao Xie, Fan Yang, Zujin Yang, Xiaoqing Liu, Haibo Wu, Qi Liu, Xihong Lu

Summary: The coordination environment of antimony (Sb) is regulated by introducing high-affinity chloride ligands, which enables high-kinetic and reversible Sb stripping/plating behavior.

NANO ENERGY (2023)

Article Energy & Fuels

A Li-rich layered oxide cathode with negligible voltage decay

Dong Luo, He Zhu, Yi Xia, Zijia Yin, Yan Qin, Tianyi Li, Qinghua Zhang, Lin Gu, Yong Peng, Junwei Zhang, Kamila M. Wiaderek, Yalan Huang, Tingting Yang, Yu Tang, Si Lan, Yang Ren, Wenquan Lu, Christopher M. Wolverton, Qi Liu

Summary: A composite structure of lithium-rich materials can effectively mitigate the problem of voltage decay during cycling, improving the performance of Li-ion batteries.

NATURE ENERGY (2023)

Review Nanoscience & Nanotechnology

Cathode host engineering for non-lithium (Na, K and Mg) sulfur/selenium batteries: A state-of-the-art review

Tingting Yang, Yubin Niu, Qi Liu, Maowen Xu

Summary: Sulfur and selenium have gained increasing attention in energy storage systems due to their high theoretical specific gravimetric and volumetric capacities. As lithium resources become more scarce, secondary batteries utilizing sulfur and selenium coupled with other alkali metal/alkaline earth metals (e.g. Na, K, Mg) are expected to play a vital role in future production and human life. The design of the cathode, as an important component in metal-S/Se batteries, remains a challenging issue due to volume expansion, poor conductivity, and the shuttle effect. In this review, various host materials for S and Se are discussed, highlighting the widespread use of carbonaceous materials and the growing popularity of polar materials in metal-S/Se batteries. The aim is to provide valuable reference and guidance for the sustainable development of metal-S/Se batteries based on previous research experiences.

NANO MATERIALS SCIENCE (2023)

Article Chemistry, Physical

An in situ formed inorganic conductive network enables high stability and rate capability of single-crystalline nickel-rich cathodes

Xi Chen, Yu Tang, Zhibo Zhang, Muhammad Ahmad, Iftikhar Hussain, Tianyi Li, Si Lan, Kaili Zhang, Qi Liu

Summary: In this study, a strategy to construct a stable Li-conductive layer on the surface of single-crystalline Ni-rich cathode particles is reported, which significantly improves the Li-ion diffusion coefficients and suppresses surface phase transformation. The improved kinetics result in good durability and excellent rate capability of the single-crystalline cathode.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Chemistry, Physical

Dendritic growth lowers carbon electrode work function for efficient perovskite solar cells

Jie Sheng, Jingshan He, Dun Ma, Yuanbo Wang, Wu Shao, Tian Ding, Ronghao Cen, Jingwen He, Zhihao Deng, Wenjun Wu

Summary: This study presents an innovative approach to improve the photovoltaic conversion characteristics and stability of perovskite solar cells through carbon electrode interface modification. By in-situ polymerization and carbonization on the surface of nano-graphite, a dendritic structure carbon electrode is formed, reducing the work function and aligning the energy levels with perovskite. This leads to improved charge and hole collection efficiency, resulting in increased photovoltaic conversion efficiency. Furthermore, the modified carbon electrode-based perovskite solar cells exhibit exceptional stability, maintaining high efficiency even without encapsulation.

CARBON (2024)

Article Chemistry, Physical

High-performance epoxy nanocomposites via constructing a rigid-flexible interface with graphene oxide functionalized by polyetheramine and f-SiO2

Guodong Shi, Jian Song, Xiaoxiao Tian, Tongtong Liu, Zhanjun Wu

Summary: This study demonstrates the improvement of mechanical properties and reduction of coefficient of thermal expansion (CTE) in graphene oxide (GO)/epoxy (EP) nanocomposites by enhancing the interface between GO and EP through functionalization and incorporating rigid-flexible interphases. The results reveal that the SiO2-PEA-GO hybrid exhibits better strengthening and toughening effects, as well as lower CTE, compared to the PEA-GO hybrid due to the presence of rigid-flexible interfaces with higher bonding strength and better energy dissipation mechanisms. Additionally, the nanocomposites with longer polyetheramine (PEA) molecules in the rigid-flexible interphases demonstrate higher strength and toughness, while maintaining a lower CTE. This work provides a promising strategy for constructing adjustable flexible-rigid interfacial structures and offers potential in developing GO/EP nanocomposites with high mechanical properties and low CTE.

CARBON (2024)

Article Chemistry, Physical

A facile route to the synthesis of carbon replicas cast from narrow-mesoporous matrices

Rafal Janus, Sebastian Jarczewski, Jacek Jagiello, Piotr Natkanski, Mariusz Wadrzyk, Marek Lewandowski, Marek Michalik, Piotr Kustrowski

Summary: In this study, a facile procedure for the synthesis of CMK-1 and CMK-2 carbon replicas was developed. The method utilizes basic laboratory equipment and a renewable carbon source, and operates under mild conditions. The resulting carbon mesostructures exhibit exquisite replication fidelity and structural homogeneity, making them suitable for applications in various fields.

CARBON (2024)

Article Chemistry, Physical

Microstructure and energetic characteristics of direct ink printed polymer-free rGO/nanothermite aerogel

Anqi Wang, Connor J. MacRobbie, Alex Baranovsky, Jean-Pierre Hickey, John Z. Wen

Summary: In this study, a novel polymer-free nanothermite aerogel with a wide range of nanoparticle loading was fabricated via a new additive manufacturing process. The SEM images showed a unique porous structure formed by extra thin rGO sheets, wrapping individual nanothermite clusters. The DSC-TGA results and high-speed combustion videos confirmed the enhanced energetic performance of the printed specimen.

CARBON (2024)

Article Chemistry, Physical

A solar-driven interfacial evaporator for seawater desalination based on mussel-inspired superhydrophobic composite coating

Wanze Wu, Misheng Zhao, Shiwei Miao, Xiaoyan Li, Yongzhong Wu, Xiao Gong, Hangxiang Wang

Summary: Superhydrophobic solar-driven interfacial evaporator is an energy-efficient technology for seawater desalination, which is easily fabricated using robust photothermal superhydrophobic coating and substrate. The created bifunctional coating on the melamine sponge substrate shows stable and highly efficient photothermal and superhydrophobic performance for seawater desalination. This superhydrophobic solar-driven interfacial evaporator is expected to have wide applications in seawater desalination.

CARBON (2024)

Article Chemistry, Physical

Bead-like flexible ZIF-67-derived Co@Carbon composite nanofibre mat for wideband microwave absorption in C-band

Zichen Xiang, Zhi Song, Tiansheng Wang, Menghang Feng, Yijing Zhao, Qitu Zhang, Yi Hou, Lixi Wang

Summary: This study presents a co-electrospinning synthesis strategy to fabricate lightweight and porous Co@C composite nanofibres with wideband microwave attenuation capacity. The addition of MOF-derived Co additives enhances the low-frequency absorption performance.

CARBON (2024)

Article Chemistry, Physical

A perovskite-graphene device for X-ray detection

J. Snow, C. Olson, E. Torres, K. Shirley, E. Cazalas

Summary: This study investigates the use of a perovskite-based graphene field effect transistor (P-GFET) device for X-ray detection. The sensitivity and responsivity of the device were found to be influenced by factors such as X-ray tube voltage, current, and source-drain voltage. Simulation experiments were conducted to determine the dose rate and energy incident on the device during irradiation.

CARBON (2024)

Article Chemistry, Physical

Microporous carbon prepared by microwave pyrolysis of scrap tyres and the effect of K+ in its structure on xylene adsorption

Zuzana Jankovska, Lenka Matejova, Jonas Tokarsky, Pavlina Peikertova, Milan Dopita, Karolina Gorzolkova, Dominika Habermannova, Michal Vastyl, Jakub Belik

Summary: This study provides new insights into microwave-assisted pyrolysis of scrap tyres, demonstrating that it can produce microporous carbon black with potential application in xylene adsorption. Compared to conventional pyrolysis, microwave pyrolysis requires less time and energy while maintaining similar adsorption capacity.

CARBON (2024)

Article Chemistry, Physical

Ambipolar charge transfer of larger fullerenes enabled by the modulated surface potential of h-BN/Rh(111)

Max Bommert, Bruno Schuler, Carlo A. Pignedoli, Roland Widmer, Oliver Groning

Summary: A detailed understanding of the interaction between molecules and two-dimensional materials is crucial for incorporating functional molecular films into next-generation 2D material-organic hybrid devices. This study compares the energy level alignment of different-sized fullerenes on a Moire superstructure and finds that C-84 fullerenes can be either neutral or negatively charged depending on slight variations of the electrostatic potential. This discovery suggests a new path to achieve ambipolar charge transfer without overcoming the electronic gap of fullerenes.

CARBON (2024)

Article Chemistry, Physical

Flexible SiO2/rGO aerogel for wide-angle broadband microwave absorption

Yuanjing Cheng, Xianxian Sun, Ye Yuan, Shuang Yang, Yuanhao Ning, Dan Wang, Weilong Yin, Yibin Li

Summary: The dual-structure aerogel (GS) consisting of flexible silica fibers and graphene honeycomb structures exhibits excellent resilience, flexibility, and reliability. It also shows remarkable wave absorbing performance, making it an ideal candidate for microwave absorption applications such as flexible electronics and aerospace.

CARBON (2024)

Article Chemistry, Physical

In situ self-adaptive growth of graphene coatings on hard substrates via competitive NiCo catalysis reaction

Shuyu Fan, Yinong Chen, Shu Xiao, Kejun Shi, Xinyu Meng, Songsheng Lin, Fenghua Su, Yifan Su, Paul K. Chu

Summary: Graphene coatings are promising solid lubrication materials due to their mechanical properties. This study presents a new method for in situ deposition of high-quality graphene coatings on hard substrates using NiCo solid solution and competitive reaction strategies. The graphene coating deposited on substrates with deep NiCo solid solution demonstrates superior low-friction and durability.

CARBON (2024)

Article Chemistry, Physical

Monodispersed semiconducting SWNTs significantly enhanced the thermoelectric performance of regioregular poly(3-dodecylthiophene) films

Mengdi Wang, Sanyin Qu, Yanling Chen, Qin Yao, Lidong Chen

Summary: The improved thermoelectric properties of conducting polymers are achieved by selectively capturing single-walled carbon nanotubes (SWNTs) in a conducting polymer film, leading to increased carrier mobility and reduced thermal conductivity. The resulting composite film exhibits significantly higher electrical conductivity and lower thermal conductivity compared to films with a mixture of SWNTs. This work provides a convenient and efficient method to enhance the thermoelectric properties of conducting polymers.

CARBON (2024)

Review Chemistry, Physical

Component optimization and microstructure design of carbon nanotube-based microwave absorbing materials: A review

Heng Wei, Weihua Li, Kareem Bachagha

Summary: This article reviews the research progress of carbon nanotube-based microwave absorbing materials (MAMs) in recent years, covering the fundamental theory, design strategies, synthesis methods, and future development directions.

CARBON (2024)

Article Chemistry, Physical

MXene-based polymer brushes decorated with small-sized Ag nanoparticles enabled high-performance lithium host for stable lithium metal battery

Chenguang Shi, Junlong Huang, Zongheng Cen, Tan Yi, Shaohong Liu, Ruowen Fu

Summary: This study developed a high-performance Li metal host material, which achieved dendrite-free Li deposition with a low nucleation overpotential and high Coulombic efficiencies through the combination of Ti3C2-g-PV4P sheets and Ag nanoparticles. The full cells assembled with the Li@host anode and LiFePO4 cathode exhibited high discharge capacity and excellent cycling stability, demonstrating a perspective design for future energy storage devices.

CARBON (2024)

Article Chemistry, Physical

A stable full cell having high energy density realized by using a three-dimensional current collector of carbon nanotubes and partial prelithiation of silicon monoxide

Tomotaro Mae, Kentaro Kaneko, Hiroki Sakurai, Suguru Noda

Summary: A new partial prelithiation method for SiO/C-CNT electrodes was developed, which showed reduced irreversible capacity and achieved high energy densities with good reversibility. The method allows for precise control of the degree of prelithiation and is applicable to various chemistries.

CARBON (2024)