Journal
CARBON
Volume 47, Issue 3, Pages 856-865Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2008.11.038
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Ni, Fe and Ni-Fe alloy particles were vapour deposited on thin films of amorphous carbon (a-C) inside a specially equipped transmission electron microscope, and reactions with the substrate were observed at elevated temperatures. The influence of oxidation of the particles was also investigated. In contrast to Ni, which was found in earlier work to graphitise the carbon at above 600 degrees C without bulk carbide being involved, pure Fe reacted with the a-C support at about 500 degrees C to Fe(3)C, which graphitised the carbon similar to Ni, starting at about 600 degrees C. No carbide was formed from oxidised Fe particles. FeO decomposes above 500 degrees C, higher oxides (Fe(3)O(4), Fe(2)O(3)) only above 750 degrees C. The remaining Fe particles graphitised the carbon support directly. Alloy particles with composition Ni80:Fe20 (permalloy) graphitised a-C in the same way as pure Ni, without any phase separation. Annealing of a mixed phase of finely dispersed Ni-Fe-oxide or deposition of Ni-Fe under oxygen at above 300 degrees C resulted in nucleation of three-dimensional crystallites of virtually pure Ni, which graphitised the carbon, while the remaining phase of small particles was converted to inactive Ni-ferrite, NiFe(2)O(4). (C) 2008 Elsevier Ltd. All rights reserved.
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