Journal
CARBOHYDRATE RESEARCH
Volume 394, Issue -, Pages 26-31Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2014.05.018
Keywords
Exocellular polysaccharide; Bioremediation; La(OTf)(3); TEMPO oxidation
Funding
- CSIR, New Delhi [01(2370)/10/EMR-II]
- UGC, New Delhi
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Chemical synthesis of the tetrasaccharide related to the exocellular polysaccharide from Rhodococcus sp. RHA1 is reported. The stereoselective glycosylations were achieved by activation of the thioglycoside donors using N-iodosuccinimide in the presence of La(OTf)(3) varying temperature per the need of 1,2-cis or 1,2-trans glycosylations. The target tetrasaccharide is reported in the form of its p-methoxyphenyl glycoside that can be cleaved selectively from the per-O-acetylated derivative allowing further glycoconjugate formation using trichloroacetimidate chemistry. (C) 2014 Elsevier Ltd. All rights reserved.
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