Journal
CARBOHYDRATE RESEARCH
Volume 357, Issue -, Pages 16-22Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2012.04.016
Keywords
Fluorination; Fluorosugars; Thioglycoside; Selenoglycoside
Funding
- Australian Research Council
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Glycosyl fluorides can be synthesized from thio-, seleno-, and telluroglycosides and glycosyl sulfoxides using the aminodifluorosulfinium tetrafluoroborate reagents Xtalfluor-E and -M, with or without added N-bromosuccinimide. Mechanistic studies provide evidence that fluoride is delivered from the tetrafluoroborate counterion. (C) 2012 Elsevier Ltd. All rights reserved.
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