Article
Chemistry, Applied
Osmin Aviles-Garcia, Jaime Espino-Valencia, Arisbeht Mendoza-Zepeda, Kingsley Donkor, Sharon Brewer, Rubi Romero, Reyna Natividad
Summary: In this study, the degradation of beta-blocker metoprolol was achieved through photocatalysis and photo-Fenton catalyzed by doped TiO2. The addition of Cu/TiO2 showed the highest degradation and mineralization extent, while doping also reduced the energy band gap of TiO2.
Article
Engineering, Chemical
Keting Feng, Wenqian Huang, Zhongyuan Fu, Xiaoyun Hu, Jun Fan, Enzhou Liu
Summary: In this study, it was found that the in-situ photocatalytic generation of H2O2 using ZnSe nanosheets combined with Fe2+ for Fenton reaction can effectively degrade dyes and antibiotics. The photo-Fenton degradation rate is higher than that of photocatalytic and Fenton processes alone. ZnSe also shows excellent stability and hydrophilicity, which facilitates the contact between the catalyst and pollutants. The kinetic analysis demonstrates that the photo-Fenton degradation of ZnSe follows a pseudo-first-order kinetic.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2022)
Article
Engineering, Environmental
Anka Jevremovic, Ana Stanojkovic, Dragana Arsenijevic, Aleksandar Arsenijevic, Grigory Arzumanyan, Kahramon Mamatkulov, Jelena Petrovic, Bojana Nedic Vasiljevic, Danica Bajuk-Bogdanovic, Maja Milojevic-Rakic
Summary: This study investigates the effects of different pesticide remediation methods on cytotoxicity and finds that materials used for adsorption and oxidative degradation can have different effects on cells. It is concluded that a combination of adsorption and catalytic degradation is the optimal approach for reducing pesticide toxicity.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Engineering, Environmental
Yanhua Wu, Hong Wang
Summary: A CuMoO4/MnO2/tourmaline (CMT) heterogeneous photocatalyst was constructed and applied for organic contaminant degradation using visible light illumination. The CMT catalyst exhibited impressive degradation efficiencies and the degradation mechanisms were investigated through various experiments and tests.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Engineering, Environmental
Pellegrino La Manna, Marco De Carluccio, Patrizia Iannece, Giovanni Vigliotta, Antonio Proto, Luigi Rizzo
Summary: This study investigated the application of Fe3+-iminodisuccinic acid (Fe:IDS) based solar photo Fenton (SPF) in quaternary treatment of real urban wastewater and compared it with Fe3+-ethylenediamine-N,N'-disuccinic acid (Fe:EDDS) for the first time. Fe:EDDS was more effective in pharmaceuticals removal, while Fe:IDS was more effective in pathogens inactivation. Fe:IDS SPF alone is an attractive option for urban wastewater reuse.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Chemistry, Physical
Ziyang Xiang, Hui Wang, Ruizhi Wen, Yanmei Li, Junhui Yang, Jinglin Yin, Jing Wang, Wenlei Wang
Summary: In this study, FeSe2 and Fe2O3 were synthesized on macroporous biochar through a hydrothermal method for enhanced H2O2 adsorption. The mechanism of H2O2 adsorption and decomposition to produce hydroxyl radicals was explored using density functional theory and electron paramagnetic resonance. Experimental results showed that the catalyst had high efficiency in degrading As(III) in a Fenton reaction.
APPLIED SURFACE SCIENCE
(2022)
Article
Engineering, Chemical
Weilong Shi, Lijing Wang, Juan Wang, Haoran Sun, Yuxing Shi, Feng Guo, Changyu Lu
Summary: In this study, CdS/rGO/ZFO nanocomposite was constructed for efficient Photo-Fenton degradation of tetracycline. The nanocomposite exhibited excellent photoactivity and recyclability, providing potential application prospects.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Environmental Sciences
Naiara de Oliveira Dos Santos, Rosa Busquets, Luiza C. Campos
Summary: Water treatment plants' effluents are a major source of microplastics (MPs) and microfibres (MFs) in aquatic environments. Advanced Oxidation Processes (AOPs) show promise in degrading these particles, but more research is needed. This review highlights the impacts of AOPs on MPs/MFs, focusing on degradation efficiency, toxicity, and sustainability. It also suggests the need for standardized analysis methods and further investigation into the operational feasibility of AOPs for MP removal.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Engineering, Environmental
Carlos Dante Gamarra-Guere, Dawany Dionisio, Gessica Oliveira Santiago Santos, Marcos Roberto Vasconcelos Lanza, Artur de Jesus Motheo
Summary: Endocrine disruptors, such as MeP, are persistent pollutants in aquatic ecosystems. Among various advanced oxidation processes, electro-Fenton was found to be the most effective method for degrading MeP efficiently and quickly, outperforming other alternatives.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Green & Sustainable Science & Technology
Qingliang Liu, Yu Wang, Ying Zhao, Zhiqiang Sun, Jun Ma, Xu He
Summary: A novel MnO2-H2O2 system was developed for efficient removal of As. This system achieved a high removal efficiency of 88% for As (100 μg/L) within 30 min under specified conditions without external mechanical stirring. The removal efficiency was attributed to the turbulent conditions generated by the catalytic decomposition of H2O2, efficient adsorption of As on MnO2, and the generation of reactive radicals. The MnO2-H2O2 system shows great potential for practical water treatment applications.
Article
Environmental Sciences
Zhelin Song, Yu Xu, Honghai Wu, Jiahui Huang, Yanlin Zhang
Summary: Acetamiprid, a recalcitrant pollutant in wastewater treatment plant effluents, poses a potential threat to human health, aquatic life, soil microorganisms, and beneficial insects. In this study, α-Fe2O3-pillared bentonite (FPB) was synthesized and used in the photo-Fenton process, with the assistance of L-cysteine (L-cys) present in natural aquatic environments, for the degradation of acetamiprid. The degradation rate constant (k) of acetamiprid by FPB/L-cys in the photo-Fenton process was significantly higher than that in the Fenton process of FPB/L-cys without light and the photo-Fenton process of FPB without L-cys. The synergistic effect of L-cys and visible light was found to accelerate the cycle of Fe(III) to Fe(II) in FPB/L-cys, enhancing the visible light response of FPB and promoting interfacial and photo-generated electron transfer for acetamiprid degradation.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2023)
Article
Environmental Sciences
Sankar Sekar, Ji-Seop Yun, Sejoon Lee
Summary: A novel electroanalytical technique utilizing nanocomposites for simultaneous sensing of paracetamol and 4-aminophenol was developed. The technique showed high active electrochemical surface area and excellent electron transfer properties. Satisfactory results were obtained when tested in tap water and artificial urine models, demonstrating its potential for industrial and clinical applications.
ENVIRONMENTAL RESEARCH
(2023)
Article
Engineering, Environmental
Yong Chen, Yuangang Li, Ningdan Luo, Weike Shang, Shaosen Shi, Huajing Li, Yaodong Liang, Anning Zhou
Summary: The study developed a H2O2-free photo-Fenton process using BiVO4 as a semiconductor and Fe3+ as an additive to effectively degrade antibiotics. Comparisons between H2O2-free photo-Fenton and photocatalytic reactions showed the former had higher degradation rates under optimized conditions. The study deepened the understanding of mechanism and kinetics between photo-Fenton and photocatalytic reactions on the same catalyst, and highlighted the potential of H2O2-free photo-Fenton reactions on other semiconductors in treating wastewater with various antibiotics.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Environmental Sciences
Xiaohan Huang, Jianfei Xiao, Qing Yi, Dejian Li, Chenrui Liu, Yun Liu
Summary: A novel core-shell structured Fe3O4@GO-CoPc magnetic catalyst with excellent photo-Fenton catalytic activity was successfully prepared. The effective transfer of photo-generated electrons between CoPc and Fe3O4 by GO was found to be the key factor contributing to the high catalytic activity. The analysis of active species further confirmed the reaction mechanism.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2022)
Article
Nanoscience & Nanotechnology
Vitor M. Miguel, Maria Paula de S. Rodrigues, Adriano H. Braga, Susana I. Cordoba de Torresi
Summary: This study demonstrates that the catalytic activity of MnO2 can be greatly improved by the localized surface plasmon resonance (LSPR) effect when decorated with gold nanoparticles (Au NPs). Under visible light irradiation, the gold decorated nanowires show higher sensitivity and increased current for H2O2 oxidation. The improved performance is attributed to more efficient charge separation by plasmonic generated hot electrons and holes.
ACS APPLIED NANO MATERIALS
(2022)
Article
Chemistry, Physical
Ghazaleh Khoshroo, Andras Sapi, Imre Szenti, Anastasiia Efremova, Henrik Bali, Kornelia B. Abrahamne, Andras Erdohelyi, Akos Kukovecz, Zoltan Konya
Summary: This work investigates the effect of Potassium promoter and calcination temperature on the catalytic activity in the dry reforming of methane reaction. Trimetallic catalysts showed a more favorable CO/H2 ratio and better coke resistance compared to the reference catalyst Ni-Al2O3.
Article
Chemistry, Physical
Owais Al-Aqtasha, Ferenc Farkas, Andras Sapi, Imre Szenti, Tamas Boldizsar, Kornelia B. Abrahamne, Akos Kukovecz, Zoltan Konya
Summary: This paper discusses the overlooked source of emissions from non-road mobile machinery and proposes a solution using an efficient catalyst. By analyzing the relevant properties of the catalyst and its performance, a significant reduction in CO and NOx emissions is achieved. This research will be the first part of a tailored solution to reduce emissions from non-road mobile machinery.
REACTION KINETICS MECHANISMS AND CATALYSIS
(2023)
Article
Chemistry, Physical
Mahsa Abedi, Akos Szamosvolgyi, Andras Sapi, Akos Kukovecz, Zoltan Konya, Tamas Gyulavari, Zsolt Pap
Summary: Strontium titanate (STO) photocatalysts were prepared using a modified Pechini sol-gel method, with a unique rapid calcination technique. The samples were characterized and evaluated for their photocatalytic activity against various pollutants under UV light irradiation. The STO catalysts showed higher activity than the commercial reference, and their stability was demonstrated by retaining their crystalline composition after exposure to chemicals. Additionally, the unique calcination technique was found to be 35% more cost-effective compared to a conventional method.
Article
Chemistry, Physical
Aleksandar Markovic, Sladana Savic, Andrej Kukuruzar, Zoltan Konya, Dragan Manojlovic, Milos Ognjanovic, Dalibor M. Stankovic
Summary: In this study, different synthesis procedures for making PbO2-graphitic carbon nitride (g-C3N4) electrode were examined for the electrochemical degradation of Reactive Black 5 (RB5) textile azo dye. PbO2 with varying morphology was formed through the reaction of PbOH3- with ClO- in the presence of different surfactants (CTAB and TBAP) under conventional conditions. The obtained materials were combined with g-C3N4 and characterized morphologically and electrochemically. The composite of PbO2 synthesized using CTAB as template and g-C3N4 showed the best performance for RB5 dye removal, suggesting its potential for wastewater treatment and pollutant removal.
Article
Chemistry, Physical
Gabor Vari, Csaba Vass, Gyula Halasi, Laszlo Szabo, Krisztian Palotas, Peter Dombi, Andras Berko, Laszlo Ovari, Zoltan Konya
Summary: In this study, the thermal properties of Au and Rh deposits on hexagonal boron nitride (h-BN) nanomesh prepared on Rh(1 1 1) were compared using various techniques. Both metals showed Volmer-Weber growth at room temperature, and agglomeration, intercalation, and desorption were observed upon annealing. For Rh, an additional encapsulation mechanism was suggested. The agglomeration of gold nanoparticles was found to be faster than that of rhodium, and gold atoms diffused below h-BN at higher temperatures. Intercalation of individual adatoms was observed during deposition, and it required higher temperatures for rhodium due to its slower diffusion and higher probability of nucleation.
APPLIED SURFACE SCIENCE
(2023)
Article
Pharmacology & Pharmacy
Ferenc Istvan Nagy, Dora Izabella Adamecz, Adam Baji, Agnes Kiricsi, Ildiko Huliak, Andrea Ronavari, Zoltan Konya, Eva Frank, Mohana Krishna Gopisetty, Monika Kiricsi
Summary: In this study, novel semi-synthetic dihydrotestosterone derivatives were found to inhibit the efflux activity of multidrug-resistant cancer cells and enhance their sensitivity to chemotherapy drugs. These derivatives induced endoplasmic reticulum stress and triggered apoptosis in cancer cells. Therefore, they have the potential to overcome multidrug resistance in cancer therapy.
Article
Multidisciplinary Sciences
Hadid Sukmana, Gergo Ballai, Tamas Gyulavari, Erzsebet Illes, Gabor Kozma, Zoltan Konya, Cecilia Hodur
Summary: The study investigated the removal of methylene blue (MB) and basic red 9 (BR9) dyes using Hungarian rice husk (HRH) and Indonesian rice husk (IRH) as bioadsorbents. Various factors influencing the biosorption were evaluated using different techniques. The results showed that both HRH and IRH were effective in removing MB and BR9 through binary biosorption.
Article
Chemistry, Physical
Mohit Yadav, Haythem S. Basheer, Adam Agfalvi, Kornelia B. Abrahamne, Janos Kiss, Gyula Halasi, Andras Sapi, Akos Kukovecz, Zoltan Konya
Summary: Enhanced photocatalytic performance of CO2 reduction was achieved with noble metal-deposited TiO2 photocatalysts (NMD/TiO2) under visible light and UV. NMD-TiO2 samples showed improved photoefficiency for CO2 reduction and selectivity towards CO. Different noble metals had varying effects on the conversion yields of CO2 to CO.
APPLIED CATALYSIS A-GENERAL
(2023)
Article
Chemistry, Physical
Endre-Zsolt Kedves, Claudiu Fodor, Akos Fazekas, Istvan Szekely, Akos Szamosvolgyi, Andras Sapi, Zoltan Konya, Lucian Cristian Pop, Lucian Baia, Zsolt Pap
Summary: This study showed that MoO3 can effectively inhibit the rate of Fenton reactions, thus reducing the decomposition of organic compounds, which might be due to the scavenging effect of MoO3 on OH radicals. The results also demonstrated that the inhibition efficiency of MoO3 is strongly correlated with the acidification rate of the solution.
APPLIED SURFACE SCIENCE
(2023)
Article
Environmental Sciences
Zsuzsanna Kolbert, Arpad Molnar, Kamilla Kovacs, Sara Liptak-Lukacsik, Peter Benko, Reka Szollosi, Katalin Gemes, Laszlo Erdei, Andrea Ronavari, Zoltan Konya
Summary: This study compared the effects of different doses of multi-walled carbon nanotubes (MWCNTs) on Brassica napus and Solanum lycopersicum seedlings. It was found that higher concentrations of MWCNTs negatively affected root viability and cell proliferation, leading to oxidative stress and increased toxicity. The toxicity was more severe in Solanum lycopersicum compared to Brassica napus.
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
(2023)
Article
Green & Sustainable Science & Technology
Loghman Rezaei, Samrand Saeidi, Andras Sapi, M. R. Abdollahi Senoukesh, Gyula Grof, Wei-Hsin Chen, Zoltan Konya, Jiri Jaromir Klemes
Summary: The solar chimney power plant is a simple and clean technology to generate electricity from solar radiation. This study developed a novel collector design with hanging metallic tubes to improve efficiency. Experimental and computational fluid dynamics analysis validated the new design and found that the metallic tubes significantly affected temperature and velocity distribution. The efficiency of the collector increased with the hanging metallic tubes and was also influenced by the geometry variation.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Chemistry, Multidisciplinary
Marton Szabados, Tamara Szabados, Robert Mucsi, Kornelia Baan, Janos Kiss, Akos Szamosvolgyi, Andras Sapi, Zoltan Konya, Akos Kukovecz, Pal Sipos
Summary: The use of rare nickel-poor and aluminum-rich layered double hydroxides (LDHs) as catalyst precursors in CO2 hydrogenations highlights the importance of the chemical quality of the interlayer anions. The thermal stability and chemical properties of the anions significantly affect the reaction outcomes. The choice and removal of the anions result in differences in LDH transformation, reducibility of Ni(II), and specific surface area of the resulting metal oxides. Furthermore, the conversion and selectivity are correlated with the abundance and strength of base and acid sites in the LDHs.
JOURNAL OF CO2 UTILIZATION
(2023)
Article
Nanoscience & Nanotechnology
Gergo Ballai, Tomaz Kotnik, Matjaz Finsgar, Albin Pintar, Zoltan Konya, Andras Sapi, Sebastijan Kovacic
Summary: Highly porous metal oxide-polymer nanocomposites with unique structural and functional features were prepared by coating metal oxide nanolayers onto polyHIPE beads using the ALD technique. It was found that the number of ALD cycles affected the thickness and crystallinity of the nanolayers. Furthermore, the ALD-derived TiO2-polyHIPE beads exhibited superior activity in photocatalytic oxidation.
ACS APPLIED NANO MATERIALS
(2023)
Article
Green & Sustainable Science & Technology
Hadid Sukmana, Etelka Tombacz, Gergo Ballai, Gabor Kozma, Zoltan Konya, Cecilia Hodur
Summary: This study compares Indonesian and Hungarian rice husks as bio-adsorbents for removing dyes from aqueous solutions and finds that they are potential adsorbents.
Article
Chemistry, Analytical
Sanja Mutic, Jasmina Anojcic, Milan Vranes, Jovana Panic, Snezana Papovic
Summary: The rapid and sensitive determination of organic UV filters BP-3 and AVO was achieved using an ionic liquid carbon paste electrode (IL-CPE), with [N-C4-3C1Py]Cl-CPE showing more favorable interactions. The IL-based voltammetric sensor demonstrated good selectivity and potential for quantifying the selected UV filters in various real samples.