Journal
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
Volume 89, Issue 7, Pages 863-869Publisher
CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS
DOI: 10.1139/V10-176
Keywords
1,10-phenanthroline; lead(II) bromide; lead(II) iodide; Pb-207 NMR; solid-state NMR; density functional theory; zeroth-order regular approximation (ZORA)
Categories
Funding
- American Chemical Society [33633-AC5]
- National Science Foundation [CHE-0411790, CHE-0956006]
- US Department of Energy [DE-AC0205CH11231]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0956006] Funding Source: National Science Foundation
Ask authors/readers for more resources
Experimental and predicted Pb-207 nuclear magnetic resonance (NMR) parameters of solid-state coordination complexes of lead(II) bromide, lead(II) iodide, and lead(II) chloride with 1,10-phenanthroline are reported. Structural and electronic differences between the 1:1 and 1:2 adducts are reflected by the NMR parameters. The NMR chemical shieldings of the isostructural complexes indicate that the electronic state of the lead(II) center depends on the number of ligands and the halogen anion. The NMR results suggest that the 1:2 adduct may be more stereochemically active than the 1:1 adduct.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available