Journal
ANALYTICAL METHODS
Volume 7, Issue 9, Pages 3685-3691Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ay00325c
Keywords
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Funding
- Jiangxi Technology support plan of China [20133ACG70002, 20143ACG70005]
- Natural Science Foundation of China [21465017]
- State Key Laboratory of Food Science and Technology in Nanchang University [SKLF-ZZA-201302]
- Natural Science Foundation for Young Scholars of China [201105043]
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Considerable numbers of organotin compounds, which are widely used in people's lives, have serious toxic effects to human health. In this paper, a simple, low-cost method for the simultaneous determination of four organotins in plant oil samples by gas chromatography-mass spectrometry (GC-MS) has been established for the first time. The method uses dispersive-solid phase extraction (d-SPE) clean-up after a low-temperature precipitation procedure, in situ derivatization with NaBEt4 and liquid-liquid extraction (LLE). The relevant experimental variables influencing the whole results were optimized; a good accuracy and precision were attained under the optimal conditions. The average recoveries obtained for analytes were in the range of 75.6-114.9% with a relative standard deviation (RSD) of 3.9-12.6%, and the limits of detection for each organotin ranged between 0.19 and 0.33 mu g kg(-1). Finally, these four organotins in different oil samples were detected using this method, which demonstrated the feasibility of our developed method in this study.
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