4.3 Article

BNBTS More than Brominating Agent: Green and One-pot Route for the C-N Bond Formation in Water from Alkenes

Journal

BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 34, Issue 2, Pages 500-504

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.5012/bkcs.2013.34.2.500

Keywords

C-N bond formation; BNBTS; N-bromo sulfonamide; Bromo hydrin; Building blocks

Funding

  1. Institute for Advanced Studies in Basic Sciences (IASBS)

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In this paper, in addition to introducing efficient method for bromohydrin and bromoether preparation, simple, green and efficient method to C-N bond formation from alkene and N-N'-Dibromo-N,N'-1,2-ethanediyl-bis(p-toluenesulfonamide) [BNBTS] in water was investigated. The reaction between alkenes, beta-cyclodexterin, and BNBTS took place in water afterward, by making media basic; it will give the corresponding valuable building blocks in good yields (45-79%).

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