Journal
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 31, Issue 11, Pages 3212-3216Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.5012/bkcs.2010.31.11.3212
Keywords
Colorimetric; Chemosensor; Rhodamine B; Copper recognition
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Funding
- Foundation of Educational Department of Liaoning Province [2008-T002]
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A new rhodamine-based sensor 1 was designed and synthesized by incorporating rhodamine B and benzimidazole moieties Sensor 1 exhibits high selectivity and sensitivity to Cu2+ in CH3CN-water solution (HEPES buffer, pH = 7 0) with an obvious color change from colorless to pink Other metal ions such as Hg2+, Ag+, Pb2+, Sr2+, Ba2+, Cd2+, Ni2+, Co2+, Fe2+, Mn2+, Cu2+, zn(2+), Ce2+, Mg2+, K+ and Na+ had no such color change and have no significant Influence on Cu2+ recognition process The interaction of Cu2+ and sensor 1 was proven to adopt a 1 1 binding stoichiometry and the recognition process is reversible
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