Article
Chemistry, Physical
Gerrit Karl Mertin, Marc Oldenburger, Ernst Richter, Markus Hans Hofmann, Kai Peter Birke
Summary: This article challenges the conventional theory regarding reversible heat in working galvanic cells, proposing a new theory that reversible heat does not exist. Instead, it suggests that temperature changes in electrochemical systems are caused by variations in heat capacity depending on the state of charge. It concludes that the change in heat capacity is generated through internal particle transport, leading to a general theory for reversible energy and power conversion in galvanic cells.
JOURNAL OF POWER SOURCES
(2021)
Article
Materials Science, Multidisciplinary
Jason L. Baker, Josh T. White, Aiping Chen, Tasheima Ulrich, Robert R. Roback, Hongwu Xu
Summary: This study investigated the low-temperature heat capacity of U3Si5 intermetallic compound, observing an enhancement in heat capacity at low temperatures attributed to potential spin-fluctuations. Several thermodynamic parameters were determined based on the experimental data.
JOURNAL OF NUCLEAR MATERIALS
(2021)
Article
Physics, Condensed Matter
E. N. Tkachev, N. I. Matskevich, D. A. Samoshkin, V. N. Shlegel, S. V. Stankus
Summary: The heat capacity of Li2W0.9Mo0.1O4 single crystals in the temperature range of 319-910 K was studied using differential scanning calorimetry for the first time. The temperature dependence was well described by a polynomial equation, and based on the smoothed heat capacity values, the enthalpy and entropy increments were calculated. No phase transitions were observed throughout the temperature range.
PHYSICA B-CONDENSED MATTER
(2021)
Article
Geochemistry & Geophysics
K. Jayanthi, Grace Neilsen, Peter F. Rosen, Clark Andersen, Matthew S. Dickson, Samuel F. Evans, M. Parans Paranthaman, Brian F. Woodfield, Alexandra Navrotsky
Summary: Lithium aluminum chloride layered double hydroxide (LDH) sorbents have been found to selectively recover lithium from geothermal brines, promoting domestic production of lithium for rechargeable batteries. By measuring heat capacity and calculating thermodynamic functions, it was found that a higher water content results in a less negative Gibbs energy for both doped and undoped samples. The anomaly in heat capacity in one of the samples suggests that interactions between species in the interlayer play a crucial role in stabilizing the LDH structure.
AMERICAN MINERALOGIST
(2022)
Article
Construction & Building Technology
K. -D. Grevel, F. Bellmann, J. Majzlan, E. Dachs, A. Benisek, H. -M. Ludwig
Summary: The study investigated the crystalline phases of Ca2SiO4 in Portland cement clinker through calorimetry, recording and comparing low-temperature heat capacity data. Recommended values for beta-C2S and gamma-C2S were obtained.
CEMENT AND CONCRETE RESEARCH
(2022)
Article
Materials Science, Multidisciplinary
Rahul Kumar, Premakumar Yanda, A. Sundaresan
Summary: The study presents the detailed structural and magnetic properties of Li2Mn3O7, revealing its rhombohedral structure, glassy behavior, and cluster-glass characteristics. The presence of a triangular lattice leads to a disordered ground state as evidenced by competing exchange interactions.
Article
Chemistry, Multidisciplinary
Xin-Yang Yue, Qi-Yang Zhou, Jian Bao, Cui Ma, Si-Yu Yang, Xun-Lu Li, Dalin Sun, Fang Fang, Xiao-Jing Wu, Yong-Ning Zhou
Summary: A stable Li21Si5 alloy host with low Li diffusion barriers was designed and prepared using a low-cost micron silicon precursor in this study, enabling dendrite-free Li deposition behavior and superior structural stability. The new Li metal anode with Li21Si5 host showed promising cycle stability and rate capability with low polarization in both symmetric and full cells, indicating potential for alloy-based materials as hosts for Li composite anodes.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Juan Kuang, Ping Zhang, Qianqian Wang, Zhenfeng Hu, Xiubing Liang, Baolong Shen
Summary: A high-entropy silicide coating was successfully prepared on NbMoTaW refractory alloy using a halide activated pack cementation process. The coating demonstrated excellent oxidation resistance at high temperatures due to the selective oxidation of Si and the precipitation of WSi2.
Article
Biochemistry & Molecular Biology
Nikolay N. Khechinashvili, Maxim S. Kondratyev, Robert Polozov
Summary: The temperature dependence of the partial heat capacity of the native protein structure in an aqueous solution has been analyzed. It is shown that the strictly linear temperature dependence is due to the contributions of the vibrational and conformational components, indicating volume consistency and the absence of conformational transitions up to the main two-state transition. The two-level structural and functional organization of the protein three-dimensional structure are considered in relation to energy and conformational entropy properties in accordance with the principles of protein macromolecule organization.
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2023)
Article
Chemistry, Physical
Pavel Novak, Katerina Nova
Summary: The novel high-entropy alloy based on Fe-Al-Si-Ni-Ti shows high compressive strength and excellent wear resistance, but with brittleness. It exhibits good plasticity at high temperatures.
Article
Thermodynamics
Marika Yokota, Sota Goto, Itaru Tsukushi
Summary: In this study, we investigated the relationship between the absolute configurational entropy of TMCD and temperature. We calculated the configurational entropy by subtracting the heat capacity due to lattice vibrations and intramolecular vibrations from the measured heat capacity above the glass-transition temperature. The configurational heat capacity was fitted using both a power law and a logarithmic function based on Landau's critical-point theory. The results showed that the configurational entropy increases gradually with increasing temperature. The temperature at which the configurational entropy vanishes (TK) for TMCD was found to be between 280 K and 298 K, which is about 50 K lower than the glass-transition temperature and consistent with expectations.
THERMOCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Francisco Javier Romero, Jose-Maria Martin-Olalla, Javier S. Blazquez, Maria Carmen Gallardo, Daniel Soto-Parra, Eduard Vives, Antoni Planes
Summary: The study investigated the ferroelastic/martensitic and para-ferromagnetic phase transitions of a Ni50.53Mn33.65In15.82 metamagnetic shape memory alloy through calorimetric, magnetic, and acoustic emission measurements. The research focused on distinguishing the latent heat contribution and specific heat contribution to the total excess enthalpy of the phase transition, revealing step-like behavior in specific heat and intermittent dynamics of the ferroelastic/martensitic transition. Critical behavior of the para-ferromagnetic austenite phase transition was also studied, showing a critical exponent in agreement with previous findings for Ni-Mn-Ga alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Johan Aqvist
Summary: Despite advances in computational design of protein structures, designing efficient enzyme catalysts remains challenging. This study uses extensive computer simulations to analyze the reasons for low catalytic activity and anomalous temperature behavior in a designed enzyme. The results reveal a lower energy state of the enzyme-substrate complex that explains the low activity and suggest two possible explanations for the temperature optimum: a change of rate-limiting step or a heat capacity change upon substrate binding.
Article
Chemistry, Physical
Ya-Qi Wang, Hui-Min Wang, Yi-Cheng Jiang, Guo-Ran Li, Sheng Liu, Xue-Ping Gao
Summary: In this study, high-entropy oxide (HEO) nanofibers were used as sulfur hosts for the first time, showing good rate capacity and cycling stability due to strong chemical interaction with lithium polysulfides. The tap density of the sulfur/HEO composite was also significantly higher than that of the sulfur/CNT composite, leading to a higher volumetric capacity. This research provides a promising strategy for improving the volumetric energy density and electrochemical performance of lithium-sulfur batteries.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Sun Woong Baek, Kira E. Wyckoff, Danielle M. Butts, Jadon Bienz, Ampol Likitchatchawankun, Molleigh B. Preefer, Matevz Frajnkovic, Bruce S. Dunn, Ram Seshadri, Laurent Pilon
Summary: TiNb2O7, a shear-phase compound, has emerged as a safe and high-volumetric density replacement for graphite anodes in lithium ion batteries, retaining capacity even at high cycling rates. Pure and crystalline TiNb2O7 can be rapidly prepared using a high-temperature microwave synthesis method, with operando calorimetry revealing key thermodynamic parameters and Joule heating dominating heat generation. The small enthalpy of mixing across different degrees of lithiation indicates the rapid rate performance is due to the high rate of lithium ion diffusion.
JOURNAL OF POWER SOURCES
(2021)
Article
Physics, Multidisciplinary
Xiaochen Hong, Federico Caglieris, Rhea Kappenberger, Sabine Wurmehl, Saicharan Aswartham, Francesco Scaravaggi, Piotr Lepucki, Anja U. B. Wolter, Hans-Joachim Grafe, Bernd Buechner, Christian Hess
PHYSICAL REVIEW LETTERS
(2020)
Article
Materials Science, Multidisciplinary
I. O. Chernyavskii, S. E. Nikitin, Y. A. Onykiienko, D. S. Inosov, Q. Stahl, J. Geck, X. C. Hong, C. Hess, S. Gass, A. U. B. Wolter, D. Wolf, A. Lubk, D. V. Efremov, F. Yokaichiya, S. Aswartham, B. Buchner, I. V. Morozov
PHYSICAL REVIEW MATERIALS
(2020)
Article
Physics, Multidisciplinary
Gael Bastien, Bastian Rubrecht, Ellen Haeussler, Philipp Schlender, Ziba Zangeneh, Stanislav Avdoshenko, Rajib Sarkar, Alexey Alfonsov, Sven Luther, Yevhen A. Onykiienko, Helen C. Walker, Hannes Kuhne, Vadim Grinenko, Zurab Guguchia, Vladislav Kataev, Hans-Henning Klauss, Liviu Hozoi, Jeroen van den Brink, Dmytro S. Inosov, Bernd Buechner, Anja U. B. Wolter, Thomas Doert
Article
Chemistry, Inorganic & Nuclear
Sebastian Selter, Francesco Scaravaggi, Rhea Kappenberger, Marco Naumann, Vitaliy V. Romaka, Martin Knupfer, Saicharan Aswartham, Anja U. B. Wolter, Sabine Wurmehl, Bernd Buechner
INORGANIC CHEMISTRY
(2020)
Article
Chemistry, Physical
Paul Gebauer, Hagen Poddig, Laura T. Corredor-Bohorquez, Tatiana Menshchikova, Igor P. Rusinov, Pavlo Golub, Federico Caglieris, Christopher Benndorf, Tobias Lindemann, Evgueni Chulkov, Anja U. B. Wolter, Bernd Buechner, Thomas Doert, Anna Isaeva
Summary: GdBiTe is a magnetic topological semimetal with unique features in terms of lattice symmetry, magnetism, and topology. Its diverse properties make it potentially valuable for applications in spintronics.
CHEMISTRY OF MATERIALS
(2021)
Article
Physics, Multidisciplinary
L. Heinze, H. O. Jeschke, I. I. Mazin, A. Metavitsiadis, M. Reehuis, R. Feyerherm, J. U. Hoffmann, M. Bartkowiak, O. Prokhnenko, A. U. B. Wolter, X. Ding, V. S. Zapf, C. Corvalan Moya, F. Weickert, M. Jaime, K. C. Rule, D. Menzel, R. Valenti, W. Brenig, S. Suellow
Summary: The mineral atacamite Cu2Cl(OH)(3) was studied experimentally and theoretically, revealing a complex evolution of magnetic order with the possibility of a magnetization plateau under the influence of a magnetic field. Theoretical approaches suggest that the magnetization process in atacamite involves a field-driven canting of a 3D network of weakly coupled sawtooth chains, leading to the formation of giant magnetic moments.
PHYSICAL REVIEW LETTERS
(2021)
Article
Crystallography
Maria Lourdes Amigo, Andrey Maljuk, Kaustuv Manna, Quirin Stahl, Claudia Felser, Christian Hess, Anja U. B. Wolter, Jochen Geck, Silvia Seiro, Bernd Buechner
Summary: High-quality single crystals of BaFe2S3 are grown using a laser-assisted floating zone method, which yields large samples free of ferromagnetic impurities. These crystals show improved quality and purity compared to samples obtained using the procedure reported in the literature.
Article
Materials Science, Multidisciplinary
S. Selter, Y. Shemerliuk, M. Sturza, A. U. B. Wolter, B. Buchner, S. Aswartham
Summary: In this study, crystal growth and magnetic characterization of (Fe1-xNix)(2)P2S6 were conducted, revealing an abrupt change in anisotropy at a critical Ni concentration and anisotropic magnetization in the range of 0 < x <= 0.9.
PHYSICAL REVIEW MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
M. L. Amigo, Q. Stahl, A. Maljuk, A. U. B. Wolter, C. Hess, J. Geck, S. Wurmehl, S. Seiro, B. Buechner
Summary: BaFe2S3 is a quasi-one-dimensional antiferromagnetic insulator that becomes superconducting under hydrostatic pressure. The Fe content has been found to play a decisive role in optimizing the magnetic ordering temperature and superconducting properties. However, an excess of Fe may lead to the presence of magnetic secondary phases. Magnetic ordering temperature and resistivity anomaly temperature seem to correlate with the level of disorder in the samples rather than with the value of Fe excess delta.
PHYSICAL REVIEW MATERIALS
(2021)
Article
Crystallography
Laura C. Folkers, Laura Teresa Corredor, Fabian Lukas, Manaswini Sahoo, Anja U. B. Wolter, Anna Isaeva
Summary: MnSb2Te4 is a candidate magnetic topological insulator with significant cation intermixing, which is being investigated through single-crystal X-ray diffraction for its implications on magnetic order. This study reveals apparent occupancy disorder between cations and subtle phase differences in the material, providing insights into tuning chemical composition and physical properties for spintronics applications. Understanding and analyzing this disorder is crucial for assessing the applicability of MnX2Te4 type materials in modern spintronics and energy-saving technologies.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Matthias Gillig, Xiaochen Hong, Piyush Sakrikar, Gael Bastien, A. U. B. Wolter, Leonie Heinze, Satoshi Nishimoto, Bernd Buechner, Christian Hess
Summary: The study explored the thermal conductivity of linarite mineral, revealing nonmonotonic behavior of heat conduction due to phonon scattering in magnetic fields, particularly at magnetic phase boundaries. Moreover, thermal activation of spin fluctuations was observed, indicating a complex interplay between phonons and critical magnetic fluctuations in the material.
Article
Materials Science, Multidisciplinary
Xiaochen Hong, Matthias Gillig, Richard Hentrich, Weiliang Yao, Vilmos Kocsis, Arthur R. Witte, Tino Schreiner, Danny Baumann, Nicolas Perez, Anja U. B. Wolter, Yuan Li, Bernd Buechner, Christian Hess
Summary: The study reveals that Na2Co2TeO6 is significantly enhanced by in-plane magnetic fields at low temperatures, showing a double-peak structure in thermal conductivity similar to α-RuCl3. The magnetic field strongly affects the phonon transport in Na2Co2TeO6, displaying characteristics of a quantum spin liquid.
Article
Materials Science, Multidisciplinary
F. Scaravaggi, S. Sauerland, L. Wang, R. Kappenberger, P. Lepucki, A. P. Dioguardi, X. Hong, F. Caglieris, C. Wuttke, C. Hess, H-J Grafe, S. Aswartham, S. Wurmehl, R. Klingeler, A. U. B. Wolter, B. Buechner
Summary: Through magnetic susceptibility studies and high-resolution capacitance dilatometry experiments, we identified the phase diagram properties of Co-doped LaFeAsO. As the Co content increases, the antiferromagnetic and nematic phases gradually weaken, with bulk superconductivity appearing around 6% Co content. However, superconductivity decreases as the Co content goes higher.
Article
Materials Science, Multidisciplinary
Piotr Lepucki, Raphael Havemann, Adam P. Dioguardi, Francesco Scaravaggi, Anja U. B. Wolter, Rhea Kappenberger, Saicharan Aswartham, Sabine Wurmehl, Bernd Buechner, Hans-Joachim Grafe
Summary: The phase diagram of LaFe1-xCoxAsO single crystals was determined using nuclear magnetic resonance (NMR). The results showed that F-doped samples exhibit superconductivity at low doping levels, while Co-doped samples exhibit structural and magnetic transitions. Short-range magnetic order was observed at doping levels up to x = 0.056, and magnetic fluctuations revealed the interplay of nematicity and magnetism.
Article
Materials Science, Multidisciplinary
T. Sakurai, B. Rubrecht, L. T. Corredor, R. Takehara, M. Yasutani, J. Zeisner, A. Alfonsov, S. Selter, S. Aswartham, A. U. B. Wolter, B. Buechner, H. Ohta, V Kataev
Summary: The pressure-dependent measurements of Cr2Ge2Te6 indicate a gradual suppression of ferromagnetic properties, with a reduction in critical transition temperature and transition width, as well as an increase in the field needed to saturate the magnetization. The anisotropy of the ferromagnetic resonance signal decreases with increasing pressure, suggesting a potential change in magnetocrystalline anisotropy at higher pressures.
Article
Thermodynamics
J. N. Zappey, E. E. Moore, O. Benes, J. -c. Griveau, R. J. M. Konings
Summary: In this study, the heat properties of technetium metal were measured and analyzed using various thermal measurement methods, including its superconductivity, zero-degree Debye temperature, electronic heat capacity coefficient, and the standard entropy of the superconducting state.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Pengshuai Zhang, Jixiu Deng, Xiaoyu Jiang, Liang Xu, Yu Huang, Han Sun, Mi Gao, Xianghan Wang, Yulong Gao, Kangning Fan, Lu Zhang, Shuoye Yang
Summary: In this study, the solubility of daminozide in twelve neat solvents was determined using the gravimetrical method. Various models were employed to analyze the experimental solubility, and the miscibility of daminozide in the selected solvents was discussed based on Hansen solubility parameters. The results showed that the dissolution mechanism of daminozide in all solvents was entropy-driven.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Jinju Ma, Hao Wu, Dongxu Yi, Wei Liu, Xinding Yao, Tao Li, Baozeng Ren
Summary: In this study, the solubility and compatibility of Agomelatine in different solvents were investigated through experimental and simulation methods. The results showed that Agomelatine forms more stable hydrogen bonds with alcohol solvents compared to other ester solvents. Additionally, the study analyzed the acidity and basicity characteristics of Agomelatine as well as the reasons for differences in solubility.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Angelica V. Sharapova, Marina V. Ol'khovich, Svetlana V. Blokhina
Summary: This study determined the key physico-chemical properties of cardiovascular carvedilol (CVD) in terms of solubility and distribution coefficients in modeling solvents and biphasic systems. The results showed that the solubility of CVD varied significantly depending on the solvent and pH conditions, and the dissolution process deviated from ideality in saturated solutions.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Wenxi Song, Na Wang, Mingzhe Tan, Meng Wang, Xin Huang, Ting Wang, Hongxun Hao
Summary: The solubility and thermodynamic behavior of climbazole in different solvents were investigated in this study. The results showed that solubility is influenced by temperature and solvent properties. Furthermore, the solvent effect was evaluated and the molecular mechanism behind the solubility behavior was revealed using solvation energy relationship models and molecular simulation methods.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Yuqi Su, Weijie Jia, Junshuai Chen, Songtao Cao, Maogang He, Ying Zhang
Summary: This paper presents a novel measurement method based on the finite volume method (FVM) for measuring the concentration-dependent mutual diffusion coefficient D(C) in binary solution. The measurement principle was derived by integrating Fick's second law and establishing discretization equation. The method was validated through experiments and a semi-empirical correlation was built to study the temperature and concentration influences on the diffusion coefficient D.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Bo Tang, Xiaoyu Yao, Xueqiang Dong, Bowen Sheng, Yanxing Zhao, Jun Shen, Maoqiong Gong
Summary: In this study, metal-bellows variable volumetry was used to measure the saturated vapor pressures and critical parameters of R1234ze(Z) and R1336mzz(Z). New vapor pressure correlations were formulated based on the obtained data. The low uncertainties of the measured values indicate the reliability and reproducibility of the data. The results provide important thermophysical data for the use and optimization of R1234ze(Z) and R1336mzz(Z) in HTHP systems.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Vivek Pathania, Ankita Garg, Navneet Kaur, Neha
Summary: The interaction between Isoniazid and beta-cyclodextrin in solutions was investigated to understand the molecular interactions between different components. The results showed that the interaction between Isoniazid and beta-cyclodextrin affected the volume and compressibility of the solutions, and the hydration behavior of Isoniazid in the solutions was influenced by the cosolvent.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Mauricio Vega-Teijido, Marc E. Segovia, Martina Kieninger, Oscar N. Ventura
Summary: A composite chemical model, SVECV-f12, has been developed to accurately reproduce barrier heights of hydrocarbon species. The model successfully corrects systematic errors between experimental and theoretical values and is used for predicting formation enthalpies and hydrogenation/isomerization enthalpies.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Kemal Ozcan, Aylin Boztepe, Erdog an Tarcan, Cagatay Tasdemirci
Summary: In this study, the enthalpy of combustion of methane, the main component of natural gas, was measured using a reference gas calorimeter. The experimental results were compared with the values specified in ISO 6976:2016. The average enthalpy of combustion was determined as -55518.2 kJ kg-1 with an error of 0.2%.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Kouki Mekaru, Takuto Miyagi, Ayaka Mishima, Isami Uehara, Ryo Ohmura, Keita Yasuda
Summary: This study investigated the four-phase equilibrium conditions of carbon dioxide + cyclopentane double clathrate hydrate forming systems coexisting with sodium chloride aqueous solution or pure water. The results showed that the double clathrate hydrate is more thermodynamically stable than simple clathrate hydrates under a given sodium chloride concentration.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Yameng Wan, Xiaoqiang Gao, Ruiai Wang, Fanfan Li, Yanxun Li, Haixia He
Summary: This study evaluated the solubility of Iminostilbene (IMB) in twelve organic solvents and found that the solubility increased with temperature and showed a specific order in different solvents. The analysis of molecular interactions and solubility parameters provided insights into the dissolution behavior. The UNIQUAC model was used to fit the solubility data, and the thermodynamic properties of the mixing and dissolution processes were thoroughly evaluated.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Yinan Liu, Mingcheng Li, Chunying Zhu, Xiqun Gao, Youguang Ma
Summary: This study successfully prepared amine-based functionalized deep eutectic solvents and investigated the effects of solvent composition, water content, and temperature on the properties of the solvent through density and viscosity measurements. The results contribute to a better understanding of hydration and intermolecular interactions in deep eutectic solvents.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Correction
Thermodynamics
Deepak Parmar, Kavitha Kumari, Naveen Kumar, Manju Rani, Mustapha Sahal, Sanjeev Maken
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)
Article
Thermodynamics
Ruslan N. Nagrimanov, Aliya R. Ibragimova, Boris N. Solomonov
Summary: In this study, the heats of solution of hydrocarbons and alcohols with 2-methyltetrahydrofuran are systematically analyzed. Structure-property relationships are developed to calculate the enthalpy of solvation of aliphatic alcohols in 2-methyltetrahydrofuran. Specific interactions in the alcohol-2-methyltetrahydrofuran systems are determined to better understand intermolecular interactions in 2-methyltetrahydrofuran solutions. This research provides valuable insights into the properties and energies of these interactions, facilitating the transition to more environmentally friendly solvents.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2024)