4.8 Article

Interaction and kinetic analysis for coal and biomass co-gasification by TG-FTIR

Journal

BIORESOURCE TECHNOLOGY
Volume 154, Issue -, Pages 313-321

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2013.11.101

Keywords

Coal and biomass blends; CO2 gasification; Interaction; Reaction kinetics; Produce gas

Funding

  1. National Science Foundation of China (NSFC) [21176098, 51076052, 51176062]
  2. National High Technology Research and Development of China [2012AA063504]

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This study aims to investigate the interaction and kinetic behavior of CO2 gasification of coal, biomass and their blends by thermogravimetry analysis (TG). The gas products evolved from gasification were measured online with Fourier Transform Infrared Spectroscopy (FTIR) coupled with TG. Firstly, TG experiments indicated that interaction between the coals and biomasses mainly occurred during co-gasification process. The most significant synergistic interaction occurred for LN with SD at the blending mass ratio 4:1. Furthermore, thermal kinetic analysis indicated that the activation energy involved in co-gasification decreased as the SD content increased until the blending ratio of SD with coal reached 4:1. The rise of the frequency factor indicated that the increase of SD content favored their synergistic interaction. Finally, FTIR analysis of co-gasification of SD with LN indicated that except for CO, most gases including CH3COOH, C6H5OH, H2O, etc., were detected at around 50-700 degrees C. (C) 2014 Published by Elsevier Ltd.

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