4.8 Article

Interaction and its induced inhibiting or synergistic effects during co-gasification of coal char and biomass char

Journal

BIORESOURCE TECHNOLOGY
Volume 173, Issue -, Pages 11-20

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2014.09.007

Keywords

Co-gasification; Biomass char; Inhibiting effect; Synergistic effect; Kinetic models

Funding

  1. National Natural Science Foundation of China [21106173]
  2. Prospective Layout Program of the Institute of Coal Chemistry, Chinese Academy of Sciences [2011SQZBJ01]
  3. Strategic Priority Research Program of the Chinese Academy of Sciences [XDA07050100]
  4. Natural Science Fund of Shanxi Province [2013021007-2]

Ask authors/readers for more resources

Co-gasification of coal char and biomass char was conducted to investigate the interactions between them. And random pore model (RPM) and modified random pore model (MRPM) were applied to describe the gasification behaviors of the samples. The results show that inhibiting effect was observed during co-gasification of corn stalk char with Hulunbeier lignite coal char, while synergistic effects were observed during co-gasification of corn stalk char with Shenmu bituminous coal char and Jincheng anthracite coal char. The inhibiting effect was attributed to the intimate contact and comparable gasification rate between biomass char and coal char, and the loss of the active form of potassium caused by the formation of KAlSiO4, which was proved to be inactive during gasification. While the synergistic effect was caused by the high potassium content of biomass char and the significant difference of reaction rate between coal char and biomass char during gasification. (C) 2014 Elsevier Ltd. All rights reserved.

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