4.8 Article

The effect of organic loading rate and retention time on hydrogen production from a methanogenic CSTR

Journal

BIORESOURCE TECHNOLOGY
Volume 102, Issue 19, Pages 8952-8957

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2011.07.020

Keywords

Grass silage; Hydrogen; Methane; Shifting; VFA

Funding

  1. Finnish Graduate School for Energy Science and Technology (EST)
  2. Nordic Energy Research (BioHydrogen)

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The possibility of shifting a methanogenic process for hydrogen production by changing the process parameters viz., organic loading rate (OLR) and hydraulic retention time (HRT) was evaluated. At first, two parallel semi-continuously fed continuously stirred tank reactors (CSTR) were operated as methanogenic reactors (M1 and M2) for 78 days. Results showed that a methane yield of 198-218 L/kg volatile solids fed (VSfed) was obtained when fed with grass silage at an OLR of 2 kgVS/m(3)/d and HRT of 30 days. After 78 days of operation, hydrogen production was induced in M2 by increasing the OLR from 2 to 10 kgVS/m(3)/d and shortening the HRT from 30 to 6 days. The highest H-2 yield of 42 L/kgVS(fed) was obtained with a maximum H-2 content of 24%. The present results thus demonstrate that methanogenic process can be shifted towards hydrogen production by increasing the OLR and decreasing HRT. (C) 2011 Elsevier Ltd. All rights reserved.

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