Article
Multidisciplinary Sciences
Jie Zhang, Junsheng Li, Guoxia Huang, Liujuan Yan
Summary: This study investigated an efficient and inexpensive method for the removal of EtBr using chromatin extracted from common carp testis. The results showed that chromatin had a high removal efficiency and adsorption capacity for EtBr. The adsorption process followed pseudo-second-order kinetics and Langmuir isotherm model. Thermodynamic analysis revealed that the adsorption of EtBr by chromatin was a spontaneous process dominated by hydrogen bonding and van der Waals forces. This work offers a potential solution for the decontamination of EtBr and removal of analogs.
Article
Chemistry, Analytical
Xiuchao Sun, Menglu Duan, Rongteng Li, Yuan Meng, Qiang Bai, Lina Wang, Manhong Liu, Zhugen Yang, Zhiling Zhu, Ning Sui
Summary: In this study, a two-dimensional ultrathin GDY/graphene nanostructure was utilized as an electrode material for electrochemical sensing. The graphene acted as a template for the growth of few-layered GDY and conductive layers. The GDY/G modified with hemin enzyme mimic showed excellent detection performance and demonstrated the feasibility of this electrochemical sensor as a wearable biosensor.
ANALYTICAL CHEMISTRY
(2022)
Review
Nanoscience & Nanotechnology
Abdelrahman Brakat, Hongwei Zhu
Summary: Naturally derived nanocellulose and graphene hybrid nanocomposites exhibit unique physiochemical properties and huge potential for multi-sensing applications, achieving high performance through green and simple approaches. These hybrids have a wide range of applications in fields such as mechanical, environmental, and biological signal detection.
NANO-MICRO LETTERS
(2021)
Article
Spectroscopy
Jiaxin Zhang, Wenhui Yang, Shasha Li, Liujiao Bian
Summary: A fluorescent reversible regulation mechanism was studied using fluorescence spectra and molecular docking, showing the mechanism of PET and fluorescence quenching between hsDNA and QDs under specific conditions.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Chemistry, Analytical
Reda Elshafey, Ghada Fathey Abo-Sobehy, Abd-Elgawad Radi
Summary: A nanocomposite of graphene oxide and graphene quantum dots was utilized to detect ds-DNA-dimethoate interaction and fabricate DNA biosensors. The modified electrodes were characterized by microscopic and electrochemical methods to confirm the mechanism of DMT oxidation on the platform.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Analytical
Yanying Wang, Hui Zhang, Hao Hu, Xiaoming Jiang, Xinfeng Zhang, Peng Wu
Summary: Development of an important and easy analytical method for screening silver ore samples is crucial for resource exploration and mining. A selective Ag+-promoted photosensitization colorimetric assay was developed, which allowed highly sensitive colorimetric detection of Ag+ with a visual limit of quantification as low as 0.2 ng/mL. The accuracy of the method was verified through analyzing certified reference material and real ore samples, showing good agreement with the results obtained by electrothermal atomic absorption spectrometry (ET-AAS).
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Guillaume Libeert, Ramasamy Murugesan, Marton Guba, Wout Keijers, Simon Collienne, Bart Raes, Steven Brems, Stefan De Gendt, Alejandro Silhanek, Tibor Holtzl, Michel Houssa, Joris Van de Vondel, Ewald Janssens
Summary: This paper presents a new method to quantify the energy barriers for adsorption and desorption of gas molecules on few-atom clusters by utilizing reaction-induced changes of the doping level of a graphene substrate. The method is illustrated for oxygen adsorption on Au-3 clusters.
Article
Biochemistry & Molecular Biology
Fayezeh Samari, Bahram Hemmateenejad, Santiago Aparicio, Mehdi Rashidi, Mojtaba Shamsipur, Sayed Mostafa Hosseini
Summary: The binding interaction between two organoplatinum complexes and calf thymus DNA (CT-DNA) was investigated using various biophysical techniques. The results showed that the complexes exhibited a tight intercalative interaction with CT-DNA, which was confirmed by both experimental and computational studies. These findings suggest that these organoplatinum complexes have potential for cancer therapeutic applications.
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2023)
Article
Chemistry, Inorganic & Nuclear
Dejan Simic, Milan Zaric, Ivana Nikolic, Radica Zivkovic-Zaric, Petar Canovic, Aleksandar Kocovic, Ivana Radojevic, Ivana Rakovic, Sandra Jovicic Milic, Dorde Petrovic, Danijela Stojkovic, Nenad Vukovic, Miroslava Kacaniova, Milena Vukic, Verica Jevtic
Summary: The study investigates the properties and antimicrobial activity of five complexes of the palladium(ii) ion, revealing significant activities against certain microorganisms and good binding capabilities with DNA. Additionally, the complexes show high cytotoxicity against human prostate cancer cells and minimal activity towards non-cancerous human fibroblasts, indicating potential for further exploration in clinical applications.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Multidisciplinary
Amol Pansare, Amol A. Shedge, Maryappa C. Sonawale, Shubham Pansare, Akshay D. Mahakal, Shyam R. Khairkar, Shraddha Y. Chhatre, Dnyaneshwar K. Kulal, Vishwanath R. Patil
Summary: This study investigates the binding of the naturally occurring small molecule alpha-amyrin acetate (alpha-AA) with herring sperm deoxyribonucleic acid (hs-DNA). The results suggest that alpha-AA acts as a minor groove sensor for hs-DNA.
Article
Chemistry, Multidisciplinary
Kiran Devi Tulsiyan, Subhrakant Jena, Maria Gonzalez-Viegas, Rajiv K. Kar, Himansu S. Biswal
Summary: Recent advancements in biological chemistry have identified amino acid-based ionic liquids as suitable preservation media for RNA, showing their ability to maintain structural stability and avoid degradation. Through various spectroscopic techniques and molecular dynamics studies, a protective mechanism of ILs on RNA structure has been determined.
ACS CENTRAL SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
K. Sanjeev Kumar, K. Giribabu, R. Suresh, R. Manigandan, S. Praveen Kumar, V Narayanan
Summary: This study reported the synthesis of Bi2S3/rGO nanocomposite using bismuth tris-(hexadecyldithiocarbamate) complex and graphene oxide, prepared through microwave assisted one-pot tandem reaction. The nanocomposite showed better electrochemical behavior compared to Bi2S3, with good response towards HNDA detection.
Article
Chemistry, Analytical
Hui Ma, Shaoqing Lu, Qinghua Xie, Tao Wang, Haifeng Lu, Li Yu
Summary: A liquid crystals sensing platform was demonstrated to detect thrombin based on aptamer recognition, showing changes in optical appearance due to electrostatic interactions. By observing the optical changes of liquid crystals, thrombin could be analyzed with low cost and simple operation.
MICROCHEMICAL JOURNAL
(2021)
Article
Spectroscopy
Zahra Abolghasemi-Fakhri, Mohammad Amjadi
Summary: A facile method for preparing a gold nanostar-graphene quantum dot composite was reported, which resulted in highly active surfactant-free gold nanostars. The composite was used in a new sensing strategy for colorimetric detection of cysteine by studying its etching reaction with Na2SO3. Larger gold nanostars showed greater activity in the etching reaction, and pre-added cysteine protected the nanostars from etching, allowing for sensitive detection of cysteine with a detection limit of 0.35 nM.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Chemistry, Analytical
Churat Weeraphan, Pongsakorn Thawornpan, Supinya Thanapongpichat, Kanitta Srinoun, Aung Win Tun, Chantragan Srisomsap, Jisnuson Svasti, Hansuk Buncherd
Summary: The magnetic fraction of fly ash was used as a catalyst for degrading ethidium bromide in aqueous solution with a degradation efficiency of 98% achieved under optimal conditions. The catalyst showed good stability and reusability, making it a cost-effective alternative for removing ethidium bromide.
ANALYTICAL LETTERS
(2022)
Article
Chemistry, Physical
Rama K. Layek, Ashok Kumar Das, Min Jun Park, Nam Hoon Kim, Joong Hee Lee
Article
Engineering, Multidisciplinary
Md. Elias Uddin, Rama Kanta Layek, Nam Hoon Kim, David Hui, Joong Hee Lee
COMPOSITES PART B-ENGINEERING
(2015)
Article
Electrochemistry
Ashok Kumar Das, Rama K. Layek, Nam Hoon Kim, Jitendra Samdani, Myung Chul Kang, Joong Hee Lee
ELECTROCHIMICA ACTA
(2015)
Article
Engineering, Multidisciplinary
Md Elias Uddin, Rama Kanta Layek, Hak Yong Kim, Nam Hoon Kim, David Hui, Joong Hee Lee
COMPOSITES PART B-ENGINEERING
(2016)
Article
Engineering, Chemical
Parthasarathi Bandyopadhyay, Woong Bi Park, Rama K. Layek, Md Elias Uddin, Nam Hoon Kim, Hong-Gun Kim, Joong Hee Lee
JOURNAL OF MEMBRANE SCIENCE
(2016)
Article
Materials Science, Characterization & Testing
Seon Hyeong Bae, Rama K. Layek, Seung Hee Lee, Tapas Kuila, Nam Hoon Kim, Joong Hee Lee
Article
Chemistry, Physical
Rama Kanta Layek, Karthik Ram Ramakrishnan, Essi Sarlin, Olli Orell, Mikko Kanerva, Jyrki Vuorinen, Mari Honkanen
JOURNAL OF MATERIALS CHEMISTRY A
(2018)
Article
Biochemistry & Molecular Biology
Mikko Kanerva, Jacob Mensah-Attipoe, Arja Puolakka, Timo M. Takala, Marko Hyttinen, Rama Layek, Sarianna Palola, Vladimir Yudin, Pertti Pasanen, Per Saris
Summary: This study focused on the use of pine rosin as a natural antibacterial chemical and analyzed the weathering of melt-spun polyethylene (PE) and poly lactic acid (PLA) polyfilaments. The results showed that adding a copolymer surfactant can help achieve a high content of rosin in the fibers while reducing total emissions. PE fibers were found to be more durable throughout the aging study, and fibers containing rosin showed similar antibacterial effects to commercial silver-containing antimicrobial.
Article
Nanoscience & Nanotechnology
Shib Shankar Banerjee, Subhradeep Mandal, Injamamul Arief, Rama Kanta Layek, Anik Kumar Ghosh, Ke Yang, Jayant Kumar, Petr Formanek, Andreas Fery, Gert Heinrich, Amit Das
Summary: This study presents a novel method to prepare liquid metal-embedded soft elastomeric composites, showing significant improvements in mechanical properties and enhanced thermal and dielectric performance.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Nanoscience & Nanotechnology
Riya Nag, Rama Kanta Layek, Abhijit Bera
Summary: Transparent, flexible, and chemically stable conducting electrodes are crucial for optoelectronic device fabrication. This study explores metal-semiconductor (MS) junctions utilizing two-dimensional (2D) MXene nanosheets and Al-doped ZnO nanoparticles. The heterojunctions were formed by layer-by-layer self-assembly on an indium tin oxide (ITO) substrate and characterized using scanning tunneling microscopy (STM) and spectroscopy. The results demonstrate the ability to manipulate the MS junction properties, such as rectification ratio and contact resistance, by functionalizing the 2D-metal MXene and doping the ZnO nanoparticles.
ACS APPLIED NANO MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Cuiyun Liu, Hongyu Liu, Yingli Zheng, Jie Luo, Chang Lu, Yuxin He, Xinchang Pang, Rama Layek
Summary: A versatile foam based on Schiff base crosslinking of oxidized nanofibrillated cellulose (ONFC) with amino modified graphene oxide (NGO) and chitosan (CS) was prepared for the efficacious selective removal of anionic dyes.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Materials Science, Multidisciplinary
Rama K. Layek, Vijay Singh Parihar, Mikael Skrifvars, Farzin Javanshour, Mart Kroon, Mikko Kanerva, Jyrki Vuorinen, Minna Kellomaki, Essi Sarlin
Summary: This study achieved composite nanolaminates with enhanced ductility and toughness by utilizing a simple vacuum filtration method, resulting in significant improvements in mechanical properties and biocompatibility, making them very promising for various biomedical applications.
MATERIALS ADVANCES
(2021)
Article
Materials Science, Multidisciplinary
Rama K. Layek, Vijay Singh Parihar, Jukka Seppala, Alexander Efimov, Sarianna Palola, Mikko Kanerva, Shambhavee Annurakshita, Minna Kellomaki, Essi Sarlin
Summary: The study successfully fabricated composite paper with enhanced hydrophobicity, ductility, and toughness through vacuum filtration of rGO/NFC-graft-PIL aqueous dispersion. NFC-graft-PIL was synthesized by growing PIL chains from the NFC surface using free radical polymerization of a pyridinium acrylate-based ionic liquid monomer.
MATERIALS ADVANCES
(2021)
Article
Engineering, Multidisciplinary
Rama K. Layek, Md. Elias Uddin, Nam Hoon Kim, Alan Kin Tak Lau, Joong Hee Lee
COMPOSITES PART B-ENGINEERING
(2017)
Review
Energy & Fuels
Manashjit Gogoi, Rama Kanta Layek, Jyrki Vuorinen, Mrityunjoy Mahato
ENERGY AND ENVIRONMENT FOCUS
(2017)