Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 10, Issue -, Pages 2461-2469Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.10.257
Keywords
block copolymer; gamma-CD; loose-fit; poly(2-hydroxyethyl methacrylate); polypseudorotaxane
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Funding
- Natural Science Foundation of China [20974015]
- Doctoral Program Foundation of the Ministry of Education of China [20091101110029]
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A pentablock copolymer was prepared via the atom transfer radical polymerization of 2-hydroxyethyl methacrylate (HEMA) initiated by 2-bromoisobutyryl end-capped PPO-PEO-PPO as a macroinitiator in DMF. Attaching PHEMA blocks altered the self-assembly process of the pentablock copolymer with gamma-CDs in aqueous solution. Before attaching the PHEMA, the macroinitiator was preferentially bent to pass through the inner cavity of gamma-CDs to give rise to tight-fit double-chain stranded polypseudorotaxanes (PPRs). After attaching the PHEMA, the resulting pentablock copolymer was single-chain stranded into the interior of gamma-CDs to form more stable, loose-fit PPRs. The results of H-1 NMR, WXRD, DSC, TGA, C-13 CP/MAS NMR and FTIR analyses indicated that gamma-CDs can accommodate and slip over PHEMA blocks to randomly distribute along the entire pentablock copolymer chain. This results in unique, single-chain stranded PPRs showing no characteristic channel-type crystal structure.
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