Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 7, Issue -, Pages 1562-1569Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.7.184
Keywords
activity grid; single-molecule studies; synthetic ion channels; voltage clamp experiment
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Funding
- Natural Sciences and Engineering Research Council of Canada
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Voltage-clamp experiments of eight oligoester bolaamphiphiles in two subclasses are described. Syntheses of three new terephthalate-based compounds were achieved in three linear steps. Together with five previously described, related compounds, the ion transport activity was assessed by means of the voltage-clamp technique. All of the compounds show multiple types of conductance behavior in planar bilayers, a subset of which was exponentially voltage-dependent. The varied and irregular activities were summarized with the aid of a recently developed activity-grid method.
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