3.9 Article

Diagnostic screening of urban soil contaminants using diffuse reflectance spectroscopy

Journal

AUSTRALIAN JOURNAL OF SOIL RESEARCH
Volume 47, Issue 4, Pages 433-442

Publisher

CSIRO PUBLISHING
DOI: 10.1071/SR08068

Keywords

diffuse reflectance spectroscopy; vis-NIR; MIR; diagnostic screening tests; soil analysis; heavy metal soil contamination; OLR; ROC

Categories

Ask authors/readers for more resources

There is increasing demand for cheap and rapid screening tests for soil contaminants in environmental consultancies. Diffuse reflectance spectroscopy (DRS) in the visible-near infrared (vis-NIR) and mid infrared (MIR) has the potential to meet this demand. The aims of this paper were to develop diagnostic screening tests for heavy metals and polycyclic aromatic hydrocarbons (PAH) in soil using vis-NIR and MIR DRS. Cadmium, copper, lead, and zinc were analysed, as were total PAH and benzo[a]pyrene. An ordinal logistic regression technique was used for the screening and predictions of either contaminated or uncontaminated soil at different thresholds. We calculated the rates of false positive and false negative predictions and derived Receiver Operating Characteristic curves to explore how the choice of a threshold affects their proportion. Zinc and copper had the best prediction accuracies of the heavy metals, with 89% and 85%, respectively. Cadmium and lead had the lowest prediction accuracies, with 68% and 67%, respectively. PAH predictions averaged 78.9%. With an average prediction accuracy of 79.9%, MIR analysis was only slightly more accurate than vis-NIR analysis, which had an average prediction accuracy of 77.5%. However, vis-NIR may be used in situ, thereby reducing cost and time of analysis and providing diagnosis in 'real-time'. DRS in the vis-NIR can substantially decrease both the time and cost associated with screening for soil contaminants.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

3.9
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Agricultural Economics & Policy

The effect of social and personal norms on stated preferences for multiple soil functions: evidence from Australia and Italy

Cristiano Franceschinis, Ulf Liebe, Mara Thiene, Juergen Meyerhoff, Damien Field, Alex McBratney

Summary: Soil degradation is a global phenomenon with limited knowledge about the economic value of soil functions. This study investigates the value assessment of soil functions using choice experiments and hybrid choice models, and explores the influence of personal norm activation and social norms on stated preferences.

AUSTRALIAN JOURNAL OF AGRICULTURAL AND RESOURCE ECONOMICS (2022)

Article Chemistry, Applied

Comparison of flour mill stream blending approaches: Linear programming versus ash curve

John Kalitsis, Budiman Minasny, Ken Quail, Alexander McBratney

Summary: This study explores the opportunity to improve flour blending using linear programming and compares it to sequential ash curve blending. The findings show that linear programming could significantly improve flour blending outcomes, resulting in increased profitability and resource utilization in the milling industry.

CEREAL CHEMISTRY (2022)

Review Environmental Sciences

Ensuring planetary survival: the centrality of organic carbon in balancing the multifunctional nature of soils

Peter M. Kopittke, Asmeret Asefaw Berhe, Yolima Carrillo, Timothy R. Cavagnaro, Deli Chen, Qing-Lin Chen, Mercedes Roman Dobarco, Feike A. Dijkstra, Damien J. Field, Michael J. Grundy, Ji-Zheng He, Frances C. Hoyle, Ingrid Kogel-Knabner, Shu Kee Lam, Petra Marschner, Cristina Martinez, Alex B. McBratney, Eve McDonald-Madden, Neal W. Menzies, Luke M. Mosley, Carsten W. Mueller, Daniel V. Murphy, Uffe N. Nielsen, Anthony G. O'Donnell, Elise Pendall, Jennifer Pett-Ridge, Cornelia Rumpel, Iain M. Young, Budiman Minasny

Summary: Healthy soils play a crucial role in planetary survivability, providing not only calories but also other essential functions. However, intensive agriculture is rapidly degrading soils and diminishing their capacity to deliver vital functions, highlighting the need to focus on the multiple functions of soils for long-term human welfare and the survivability of the planet.

CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2022)

Article Soil Science

The cost-effectiveness of reflectance spectroscopy for estimating soil organic carbon

Shuo Li, Raphael A. Viscarra Rossel, Richard Webster

Summary: The study investigated the cost-effectiveness of estimating soil organic carbon concentrations through measuring reflectance spectra, and found that different instruments had varying impacts on the accuracy and cost of soil sample analysis.

EUROPEAN JOURNAL OF SOIL SCIENCE (2022)

Article Soil Science

Modelling soil water retention and water-holding capacity with visible-near-infrared spectra and machine learning

Philipp Baumann, Juhwan Lee, Thorsten Behrens, Asim Biswas, Johan Six, Gordon McLachlan, Raphael A. Viscarra Rossel

Summary: This study models the available water capacity (AWC) and soil water retention (SWR) of agricultural soils using visible-near-infrared spectra (vis-NIR) and the machine-learning method cubist. The spectroscopic approaches provide more accurate estimates compared to the traditional pedotransfer functions (PTFs). The results highlight the practicality and versatility of using spectroscopy with machine learning for assessing soil water characteristics.

EUROPEAN JOURNAL OF SOIL SCIENCE (2022)

Article Soil Science

To spike or to localize? Strategies to improve the prediction of local soil properties using regional spectral library

Wartini Ng, Budiman Minasny, Edward Jones, Alex McBratney

Summary: This study evaluates different strategies to improve the model accuracy of a regional spectral library for soil organic carbon prediction and found that local and localized models perform better than other strategies when more than 20 local samples are used.

GEODERMA (2022)

Article Geography, Physical

Deep transfer learning of global spectra for local soil carbon monitoring

Zefang Shen, Leonardo Ramirez-Lopez, Thorsten Behrens, Lei Cui, Mingxi Zhang, Lewis Walden, Johanna Wetterlind, Zhou Shi, Kenneth A. Sudduth, Yongze Song, Kevin Catambay, Raphael A. Viscarra Rossel

Summary: There is a growing interest in spectroscopy and soil organic carbon (SOC) modeling, but global models often struggle to generalize at local scales. To address this, the researchers propose using deep transfer learning (DTL) to extract useful information from large-scale soil spectral libraries (SSLs) and improve local modeling. The results demonstrate that this approach can enhance the accuracy of local SOC predictions and enable more accurate, rapid, and cost-effective estimation of SOC worldwide.

ISPRS JOURNAL OF PHOTOGRAMMETRY AND REMOTE SENSING (2022)

Article Chemistry, Analytical

Evaluation of Two Portable Hyperspectral-Sensor-Based Instruments to Predict Key Soil Properties in Canadian Soils

Nandkishor M. Dhawale, Viacheslav I. Adamchuk, Shiv O. Prasher, Raphael A. Viscarra Rossel, Ashraf A. Ismail

Summary: Through the analysis of 282 soil samples from Canadian agricultural fields, it was found that the portable mid-IR spectrophotometer can predict sand content more accurately, while the readily available dual-type vis-NIR spectrophotometer is better at predicting clay content. However, the ability to predict SOC content was not particularly good for the dataset used in this study.

SENSORS (2022)

Review Green & Sustainable Science & Technology

Regenerative Agriculture and Its Potential to Improve Farmscape Function

Tom O'Donoghue, Budiman Minasny, Alex McBratney

Summary: Regenerative agriculture is a movement focused on soil health, biodiversity, and socioeconomic disparities, aiming to achieve sustainable agriculture through the regeneration of agricultural resources and improvement of ecosystem function. While the definition of this movement is yet to be confirmed, there are potential avenues to deliver its intentions through iterative design and emerging markets.

SUSTAINABILITY (2022)

Article Soil Science

Diffuse reflectance spectroscopy for estimating soil properties: A technology for the 21st century

Raphael A. Viscarra Rossel, Thorsten Behrens, Eyal Ben-Dor, Sabine Chabrillat, Jose Alexandre Melo Dematte, Yufeng Ge, Cecile Gomez, Cesar Guerrero, Yi Peng, Leonardo Ramirez-Lopez, Zhou Shi, Bo Stenberg, Richard Webster, Leigh Winowiecki, Zefang Shen

Summary: Spectroscopic measurements of soil samples are reliable and cost-effective for estimating soil properties. Machine learning is becoming more powerful in extracting information from spectra, and methods for interpreting the models exist.

EUROPEAN JOURNAL OF SOIL SCIENCE (2022)

Article Soil Science

Diffuse reflectance spectroscopy characterises the functional chemistry of soil organic carbon in agricultural soils

Johanna Wetterlind, Raphael A. Viscarra Rossel, Markus Steffens

Summary: This study utilized diffuse reflectance spectroscopy to characterize and model the functional chemistry of SOC. NMR-derived C functional groups could be modeled with vis-NIR and mid-IR diffuse reflectance spectra, allowing for the characterization of SOC chemical composition on whole mineral soil samples and improving the spatial and temporal characterization of SOC composition.

EUROPEAN JOURNAL OF SOIL SCIENCE (2022)

Article Soil Science

Particulate and mineral-associated organic carbon turnover revealed by modelling their long-term dynamics

Xiaowei Guo, Raphael A. Viscarra Rossel, Guocheng Wang, Liujun Xiao, Mingming Wang, Shuai Zhang, Zhongkui Luo

Summary: This study used two carbon models to investigate the turnover of particulate (POC) and mineral-associated organic carbon (MOC) and predict long-term soil organic carbon (SOC) dynamics. The results showed that the models constrained by POC, MOC, and COC had less parameter collinearity and uncertainty compared to models constrained by total SOC alone.

SOIL BIOLOGY & BIOCHEMISTRY (2022)

Article Environmental Studies

Modelling the Whole Profile Soil Organic Carbon Dynamics Considering Soil Redistribution under Future Climate Change and Landscape Projections over the Lower Hunter Valley, Australia

Yuxin Ma, Budiman Minasny, Valerie Viaud, Christian Walter, Brendan Malone, Alex McBratney

Summary: Soil organic carbon (SOC) redistribution plays a significant role in affecting soil quality. This study introduces a coupled-model combining RothPC-1 and a soil redistribution model to simulate SOC changes in the Lower Hunter Valley area. Results show that erosion is mainly predicted in upslope areas and deposition in low-lying areas. The study emphasizes the importance of considering soil redistribution in SOC dynamics modeling to avoid overestimation of SOC stocks.
Article Ecology

Soil bacterial depth distribution controlled by soil orders and soil forms

Peipei Xue, Alex B. McBratney, Budiman Minasny, Tony O'Donnell, Vanessa Pino, Mario Fajardo, Wartini Ng, Neil Wilson, Rosalind Deaker

Summary: Human disturbances to soils can cause significant changes in soil physical, chemical, and biological properties. The impact of agricultural activities on the bacterial community in different soil orders and depths is still not well understood. This study used the concepts of genoform and phenoform to investigate the structure of soil bacterial communities at different depths in undisturbed forests (genosoils) and cultivated vineyards (phenosoils) in different soil orders. The results showed that cropping not only affected the bacterial community in the topsoil but also decreased its diversity in the subsoil. The similarity of bacterial structures among different soil orders increased with cropping. This study highlights the strong influence of agricultural activities on the distribution of soil microbes with depth, which is controlled by soil order.

SOIL ECOLOGY LETTERS (2022)

Article Soil Science

Estimating soil fungal abundance and diversity at a macroecological scale with deep learning spectrotransfer functions

Yuanyuan Yang, Zefang Shen, Andrew Bissett, Raphael A. Viscarra Rossel

Summary: This study developed a new method to estimate the relative abundance and diversity of fungi in Australian soil using a large-scale dataset. Spectrotransfer functions were developed with state-of-the-art machine learning and publicly available soil and environmental data. The method showed promising results in explaining fungal abundance and diversity, with important predictors identified. Although less accurate than direct molecular approaches, this method provides a cost-effective way to supplement soil fungal abundance and diversity research in different agricultural and ecological settings.
No Data Available