Journal
AUSTRALIAN JOURNAL OF CHEMISTRY
Volume 63, Issue 7, Pages 1084-1090Publisher
CSIRO PUBLISHING
DOI: 10.1071/CH09641
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Funding
- Australian Research Council
- CNRS
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The 9.24 eV ionization energy often quoted in photoelectron spectroscopic investigations of benzyne is not due to benzyne 1 but to benzene, C6H6. The 8.9 eV ionization is not due to benzyne either but to cyclopentadienylideneketene 12 when a 10.2 eV band is also present, or to biphenylene 5 when a 7.6 eV band is simultaneously present. Cyclopentadienylideneketene 12 has been generated by flash vacuum thermolysis of four different precursors, which permit a linking of infrared, mass, and photoelectron spectroscopic observations.
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