Journal
AUSTRALIAN JOURNAL OF CHEMISTRY
Volume 62, Issue 9, Pages 1027-1033Publisher
CSIRO PUBLISHING
DOI: 10.1071/CH09237
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Supported niobium oxides are investigated as green catalysts for Fischer indole reaction. By means of wet impregnation, 10-40 wt-% Nb2O5 were loaded onto hydrous zirconia as a support. Pore size distribution curves showed that the niobium oxide overlayer was uniformly dispersed onto the mesoporous support. Samples with close to a monolayer coverage of niobium oxide had the highest activity in the Fischer indole reaction of phenylhydrazine with both 3-heptanone and cyclohexanone. A coverage higher than a monolayer led to lower activity. In comparison, the supported catalysts were more active than bulk niobium oxide or a sample prepared by co-precipitation of hydrous zirconia and niobium oxide.
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