Global sensitivity analysis of a process-based model for ammonia emissions from manure storage and treatment structures

The development of process-based models to estimate ammonia emissions from animal feeding operations (AFOSs) is sought to replace costly and time-consuming direct measurements. Critical to process-based model development is conducting sensitivity analysis to determine the input parameters and their interactions that contribute most to the variance of the model output. Global and relative sensitivity analyses were applied to a process-based model for predicting ammonia emissions from the surface of anaerobic lagoons for treating and storing manure. The objectives were to compare global sensitivity analysis (GSA) to relative (local) sensitivity analysis (RSA) on a process-based model for ammonia emissions. Based on the first-order coefficient, both GSA and RSA showed the model input parameters in order of importance in process model for ammonia emissions from lagoon surfaces were: (i) pH, (ii) lagoon liquid temperature, (iii) wind speed above the lagoon surface, and (iv) the concentration of ammoniacal nitrogen in the lagoon. The GSA revealed that interactions between model parameters accounted for over two-thirds of the model variance, a result that cannot be achieved using traditional RSA. Also, the GSA showed that parameter interactions involving liquid pH had more impact on the model output variance than the single parameters: (i) temperature, (ii) wind speed, or (iii) total ammoniacal nitrogen. This study demonstrates that GSA provides a more complete analysis of model input parameters and their interactions on the model output compared to RSA. A comprehensive tutorial regarding the application of GSA to a process model is presented. (C) 2010 Elsevier Ltd. All rights reserved.