4.7 Article

Sm2O3 nanoparticles green synthesis via Callistemon viminalis' extract

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 650, Issue -, Pages 357-362

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2015.07.272

Keywords

Samarium (III) oxide; Nanoparticles; Green chemistry; Callistemon viminalis

Funding

  1. National Research Foundation of South Africa [92541]
  2. French Centre National pour la Recherche Scientifique (CNRS) (CNRS-NRF) [4200220]
  3. iThemba LABS
  4. UNESCO-UNISA Africa Chair in Nanosciences and Nanotechnology
  5. Abdus Salam International Centre for Theoretical Physics (ICTP) via the Nanosciences African Network
  6. African Laser Centre (ALC)

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In this contribution, it is demonstrated for the first time in the literature the possibility of synthesizing Sm2O3 nano-scaled particles as small as similar to 21.9 +/- 5 nm using an entirely new green process. This latter is based on the usage of natural extract of the Callistemon viminalis as a strong chelating agent at room temperature. The selected area electron diffraction and the high resolution transmission electron microscopy confirmed the polycrystallinity of the Sm2O3 nano-particles upon annealing at 500 degrees C. The complementary investigations by X-rays diffraction, infrared, Raman and X-rays photoelectron spectroscopy substantiated the single phase and the elemental purity of the Sm2O3 nano-particles. (C) 2015 Elsevier B.V. All rights reserved.

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