4.7 Article

Rational design of magnetic infinite coordination polymer core-shell nanoparticles as recyclable adsorbents for selective removal of anionic dyes from colored wastewater

Journal

APPLIED SURFACE SCIENCE
Volume 462, Issue -, Pages 453-465

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2018.08.122

Keywords

Fe3O4@Tb/AMP core-shell nanoparticles; Recyclable adsorbents; Anionic dyes; Selective adsorption; Magnetic separation; Colored wastewater

Funding

  1. National Natural Science Foundation of China [21505046, 21675053]
  2. China Postdoctoral Science Foundation [2016M590336, 2017T100286]
  3. Chenguang Program - Shanghai Education Development Foundation
  4. Shanghai Municipal Education Commission [15CG21]

Ask authors/readers for more resources

In this study, novel magnetic infinite coordination polymer Fe3O4@Tb/AMP core-shell nanoparticles were rationally designed and fabricated as recyclable adsorbents for selective removal of anionic dyes from colored wastewater. The core-shell nanoparticles used in this study are composed of two components: the shell is the supramolecular infinite coordination polymers (ICPs) network formed by terbium ions (Tb3+) and adenosine 5'-monophosphate monohydrate (AMP) ligands and the core is the Fe3O4 nanoparticles which are encapsulated into the ICP network by the self-adaptive inclusion process. The prepared core-shell nanoparticles showed superiority in strong magnetism and selective adsorption towards anionic dyes, such as Alizarin Red (AR) and Congo Red (CR). Parameters that influenced the adsorption process, such as solution pH, salt concentration and adsorbent dosage were investigated. Under the optimal conditions, adsorption kinetics, isotherms and thermodynamics were also determined. Notably, this nano-adsorbent exhibited rapid adsorption feature (almost 96% dye removal in 5 min) and the adsorption isotherm data fitted quite well with the Langmuir model with an estimated maximum adsorption capacity of 357.14 mg g(-1) for AR and 909.09 mg g(-1) for CR at 298 K. This capacity could be further enhanced at the higher temperatures. In addition, the Fe3O4@Tb/AMP core-shell nanoparticles could be regenerated by a simple salt/ethanol-washing method and used with high recyclability over five cycles. With the magnetically separable Fe3O4@Tb/AMP core-shell nanoparticles as adsorbents, selective removal of toxic anionic dyes from colored wastewater could be realized directly, which is of great importance for the sustainable development of dye contaminated wastewater treatment technology.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Analytical

Competitive redox reaction of Au-NCs/MnO2 nanocomposite: Toward colorimetric and fluorometric detection of acid phosphatase as an indicator of soil cadmium contamination

Miao Xu, Ruixue Ma, Chunyu Huang, Guoyue Shi, Tianshu Zhou, Jingjing Deng

ANALYTICA CHIMICA ACTA (2020)

Article Chemistry, Analytical

A smartphone-based platform for point-of-use determination of alkaline phosphatase as an indicator of water eutrophication

Xinrui You, Chunyu Huang, Yuxin Luo, Guoyue Shi, Tianshu Zhou, Jingjing Deng

MICROCHIMICA ACTA (2020)

Article Chemistry, Analytical

Functionalized ionic liquids-supported metal organic frameworks for dispersive solid phase extraction of sulfonamide antibiotics in water samples

Dingkun Lu, Chang Liu, Menghan Qin, Jingjing Deng, Guoyue Shi, Tianshu Zhou

ANALYTICA CHIMICA ACTA (2020)

Article Nanoscience & Nanotechnology

Ionic Liquid-Functionalized Magnetic Metal-Organic Framework Nanocomposites for Efficient Extraction and Sensitive Detection of Fluoroquinolone Antibiotics in Environmental Water

Dingkun Lu, Menghan Qin, Chang Liu, Jingjing Deng, Guoyue Shi, Tianshu Zhou

Summary: A novel water-stable IL-COOH/Fe3O4@Zr-MOF nanocomposite was synthesized for the selective adsorption and detection of fluoroquinolone antibiotics, with IL-COOH/Fe3O4@UiO-67-bpydc showing the best adsorption performance. Coupled magnetic solid-phase extraction with HPLC-DAD was developed as a convenient, sensitive, and efficient method for extraction and detection of FQs in environmental water, with recoveries ranging from 90.0 to 110.0% and detection limits lower than 0.02 μg L-1.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Analytical

pH-Regulated H4TCPE@Eu/AMP ICP Sensor Array and Its Fingerprinting on Test Papers: Toward Point-of-Use Systematic Analysis of Environmental Antibiotics

Chunyu Huang, Yuxin Luo, Jiacheng Li, Chang Liu, Tianshu Zhou, Jingjing Deng

Summary: In this study, a lab-on-an-AIE@Ln/ICP sensor array was developed using H4TCPE as a guest and Eu/AMP ICP as a host for simultaneous identification and sensing of environmental antibiotics. The sensor array showed diverse fluorescence responses for different antibiotics and demonstrated great potential for systematic analysis of environmental antibiotics. The fingerprinting pattern of the sensor array on test paper holds promise for point-of-use systematic analysis of environmental antibiotics in complex real samples.

ANALYTICAL CHEMISTRY (2021)

Article Chemistry, Analytical

Lab-on-a-ZnO-Submicron-Particle Sensor Array for Monitoring AD upon Cd2+ Exposure with CSF Tau441% as an Effective Hallmark

Chang Liu, Yuanting Li, Yuxin Luo, Ying Zhang, Tianshu Zhou, Jingjing Deng

Summary: This study explores the spectral changes of blue-color-emissive and red-color-emissive ZnO submicron particles towards different tau species to construct a lab-on-a-ZnO-submicron-particle sensor array. Using principal component analysis, the sensor array can differentiate and quantitatively detect different tau species simultaneously. The study demonstrates the potential application of the sensor array in monitoring the dynamic changes of tau441% in cerebrospinal fluid during Alzheimer's disease onset and provides valuable insights for early diagnosis and therapy.

ANALYTICAL CHEMISTRY (2021)

Article Nanoscience & Nanotechnology

Lanthanide-Free Infinite Coordination Polymer Nanoparticles for Real-Time Monitoring of Alkaline Phosphatase and Its Application for Digital Algal Bloom Detection

Yuxin Luo, Jiacheng Li, Yuanting Li, Bowen Yang, Tianshu Zhou, Jingjing Deng

Summary: The H4TCPE/SR101/Cu-GMP ICP nanoparticles were developed for highly sensitive and specific ALP detection and real-time monitoring of ALP activity. The nanoparticles exhibited ratiometric emission changes based on the substrate, allowing for dynamic monitoring of ALP in environmental samples under different conditions. The color changes of the nanoparticles could be recognized using a smartphone, offering great potential for the establishment of a new digital analytical platform for algal bloom warning based on surging ALP levels.

ACS APPLIED NANO MATERIALS (2021)

Article Chemistry, Analytical

Au/Lum/RhB@Ag-DMcT ICP-Based Double-Ratio Colorimetric and Fluorometric Dual Mode Assay and Multi-Responsive Coffee Ring Chips for Point-of-Use Analysis of Phosphate Ions

Junxuan Zhu, Jiacheng Li, Miao Xu, Bowen Yang, Yiling Zhang, Juan Xu, Guoyue Shi, Tianshu Zhou, Jingjing Deng

Summary: In this study, a dual-mode colorimetric and fluorometric assay for phosphate ions (Pi) and multi-responsive coffee ring chips were proposed based on guest-functionalized infinite coordination polymers (ICPs). The ICPs exhibited purple-blue color and blue fluorescence, which changed to purple-red and orange-red, respectively, in the presence of Pi, enabling dual-mode Pi detection. Additionally, the coffee ring deposition pattern on the glass substrate reflected the changes in surface wettability/size/amount of ICPs, providing a signal readout for multi-responsive coffee ring chips.

ANALYTICAL CHEMISTRY (2023)

Article Chemistry, Analytical

A dual-channel colorimetric and fluorescent sensor for the rapid and ultrasensitive detection of kanamycin based on gold nanoparticles-copper nanoclusters

Qi Nie, Jingjing Deng, Bing Xie, Guoyue Shi, Tianshu Zhou

Summary: A dual-channel assay was developed using gold nanoparticles and copper nanoclusters for colorimetric and fluorescent detection of kanamycin. The assay showed a low limit of detection for kanamycin and offered great opportunities for on-site monitoring of antibiotics in environmental samples.

ANALYTICAL METHODS (2021)

Article Chemistry, Multidisciplinary

Red-to-blue paper-based colorimetric sensor integrated with smartphone for point-of-use analysis of cerebral AChE upon Cd2+ exposure

Chang Liu, Yuxin Luo, Huijie Wen, Yanxia Qi, Guoyue Shi, Jingjing Deng, Tianshu Zhou

Summary: The red-to-blue fluorescent color changes of CDs@Eu/GMP ICPs can be integrated with smartphones for the point-of-use analysis of cerebral AChE upon Cd2+ exposure, providing a new analytical platform for understanding the environmental risk of Alzheimer's Dementia (AD) and holding great potential in the early diagnosis of AD.

NANOSCALE (2021)

Article Chemistry, Physical

Multifunctional continuous solid solution Na0.9Mg0.45Ti3.55O8-Na2Fe2Ti6O16: Preparation, characterization, magnetism, dual absorption, adsorption, and photocatalysis

Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou

Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.

APPLIED SURFACE SCIENCE (2024)

Review Chemistry, Physical

Critical advances in the field of magnetron sputtered bioactive glass thin-films: An analytical review

George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira

Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Corrosion mode evaluation of Fe-based glassy alloys with metalloid elements by electrochemical noise (EN)

Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang

Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Impacts of Zr content of HfZrOx-Based FeFET memory on resilience towards proton radiation

Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu

Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Excellent crystalline silicon surface passivation by transparent conductive Al-doped ZnO/ITO stack

Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong

Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Hydrogen sensing capabilities of highly nanoporous black gold films

Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata

Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Abnormal stability of hydrogenic defects and magnetism near the HSrCoO2.5(001) surface

Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu

Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Space variant fiber nanogratings induced by femtosecond laser direct writing

Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng

Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Wetting mechanisms in the mass transfer process of CuSi3 droplets on the TC4 and 304SS multi-metal system controlled by the hybrid shielding gas atmosphere

Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun

Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Size-regulated Co-doped hetero-interfaced 3D honeycomb MXene as high performance electromagnetic absorber with anti-corrosion performance

Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu

Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Ultrafine Ru nanoparticles on nitrogen-doped CNT arrays for HER: A CVD-based protocol achieving microstructure design and strong catalyst-support interaction

Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng

Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Novel biphenylene as cisplatin anticancer drug delivery carrier; insight from theoretical perspective

Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty

Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Platform for surface-enhanced Raman scattering in layered quantum materials

Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong

Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Cyclotriphosphazene (P3N3) derived FeOx@SPNO-C core-shell nanospheres as peroxymonosulfate activator for degradation via non-radical pathway

Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun

Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Hierarchical confinement of Prussian blue nanoparticles via NH2-MIL-88B (Fe): Rational design and electrocatalytic application

Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan

Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.

APPLIED SURFACE SCIENCE (2024)