4.7 Article

Effect of pH on the synthesis and characteristics of RGO-CdS nanocomposites

Journal

APPLIED SURFACE SCIENCE
Volume 317, Issue -, Pages 1015-1021

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2014.09.029

Keywords

Reduced graphene oxide; Cadmium sulfide; pH; Photocatalyst; Staircase band structure

Funding

  1. ERC (Center for Materials and Processes of Self Assembly) program of MOST/KOSEF [R11-2005-048-00000-0]
  2. Basic Science Research Program through the National Research Foundation of Korea (NRF), -Ministry of Education, Science and Technology [KRF-2011-0024104]

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The effect of pH on the synthesis of reduced graphene oxide (RGO)-CdS nanocomposites via a hydrothermal method was investigated. Higher pH is more favorable for the formation of good quality RGO-CdS nanocomposites. The photocatalytic performance of the composites was investigated by measuring the reduction of Cr(VI), and the composite synthesized at high pH (=11) exhibited a 76% removal rate of Cr(VI). At high pH, the development of CdS particles of smaller sizes and the maximum number of Tr-electrons available in RGO increased the effective surface area available for light absorption, fast electron transport, and enhanced light absorption intensity. The staircase band structure of CdS in combination with RGO helped to inhibit electron-hole recombination, which enhanced photocatalytic activity. (C) 2014 Elsevier B.V. All rights reserved.

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