4.7 Article

The effects of low power density CO2 laser irradiation on graphene properties

Journal

APPLIED SURFACE SCIENCE
Volume 273, Issue -, Pages 502-506

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2013.02.069

Keywords

Graphene; Laser irradiation; Thermal annealing; Raman spectrum; XPS

Funding

  1. China National Key Basic Research and Development Program [2011CB013000]
  2. British Royal Academy of Engineering
  3. Tsinghua University Initiative Scientific Research Program [2010THZ0]

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We report the investigations on structural modifications in monolayer graphene induced by low-power-density CO2 laser irradiation (2-60 W/cm(2)). Observed modifications in graphene include the disassembly of crystalline graphene into nanocrystalline structure and the generation of amorphous carbon. It was found that thermal effect played an important role during laser irradiation. By adjusting laser power density, irradiation time and temperature, the structure of graphene can be modified accordingly in a controlled manner. Our approach may enable high-efficiency and economical modification of large-area graphene, which relies on large-area irradiation using low-power-density laser. (C) 2013 Elsevier B.V. All rights reserved.

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