Journal
APPLIED SURFACE SCIENCE
Volume 285, Issue -, Pages 309-316Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2013.08.056
Keywords
Carbon nanotube; Chitosan; Calcium carbonate; Electrochemical impedance
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Funding
- Chemistry Department (University of Taff, Kingdom of Saudi Arabia)
- Faculty of Science Cairo University
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In an attempt to increase the stability, bioactivity and corrosion resistance of Ti-6Al-4V alloy, chitosan (CS) biocomposite coatings reinforced with multiwalled-carbon nanotubes (MWCNTs), and calcium carbonate (CaCO3) for surface modification were utilized by electroless deposition. Scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR) reveals the formation of a compact and highly crosslinked coatings. Electrochemical techniques were used to investigate the coats stability and resistivity for orthopedic implants in simulated body fluid (SBF). The results show that E-st value is more positive in the following order: CaCO3/MWCNTs/CS > CS/MWCNTs > CS > MWCNTs. The calculated i(corr) was 0.02 nA cm(-2) for CaCO3/MWCNTs/CS which suggested a high corrosion resistance. (C) 2013 Elsevier B.V. All rights reserved.
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