Article
Engineering, Mechanical
Longjiang Peng, Jian Li, Meng Zhang, Huaijun Lin, Zu Li, Wei Li
Summary: This study characterized the tribological behaviors of a Zr-based BMG material against GCr15 steel balls under different loads and frequencies. It was found that high coefficient of friction (COF) was observed under low load and high frequency, while low COF was observed under high loads or at low frequencies. The specific wear rate increased with both load and frequency, with frequency playing a more crucial role. Transition of wear mechanisms from oxidative wear and abrasive wear to adhesive wear was detected with increasing load and frequency, and the role of plastic deformation of BMG was illustrated. This study helps to understand the tribological properties of Zr-based BMGs under sliding conditions.
Article
Materials Science, Multidisciplinary
Yunyun Ge, Jiangbo Cheng, Chen Yan, Lin Xue, Baosen Zhang, Xiubing Liang
Summary: Thermal-induced changes in microstructure and wear behaviors of AlFeSi metallic glass coatings were investigated. Different annealing temperatures resulted in various hardening responses and wear rates.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Materials Science, Coatings & Films
Anderson G. M. Pukasiewicz, Willian R. de Oliveira, Rodolpho F. Vaz, Gelson B. de Souza, Francisco C. Serbena, Sergi Dosta, Irene G. Cano
Summary: The FeMnCrSi alloy deposited by Cold Gas Spray (CGS) process using N2 working gas at 1000 degrees C showed higher hardness, elastic modulus, cavitation resistance, and sliding wear resistance compared to deposition at 900 and 1100 degrees C. Samples sprayed with N2 at 1000 degrees C and He at 600 degrees C demonstrated higher compressive residual stress and flatness ratio as well. Tests were conducted on CGS sprayed 316 L stainless steel as a benchmark material.
SURFACE & COATINGS TECHNOLOGY
(2021)
Article
Materials Science, Coatings & Films
Rahul Jude Alroy, M. Kamaraj, G. Sivakumar
Summary: In this study, fine and coarse Cr3C2-25NiCr particles were sprayed using HVAF and oxygen-augmented HVAF(O) modes. Heat treatment was conducted to enhance the microstructural features and mechanical properties of the coatings. The phase composition, microstructural features, and mechanical properties of the as-deposited and heat-treated coatings were extensively examined. Subsequently, a high-load sliding test was performed to assess the influence of processing conditions and heat treatment on the sliding wear performance of Cr3C2-25NiCr coatings. Detailed post-wear analyses were then conducted to analyze the wear rate/mechanism. The results demonstrated that the appropriate choice of process parameters and heat treatment conditions improved the sliding wear performance of Cr3C2-25NiCr coatings.
SURFACE & COATINGS TECHNOLOGY
(2023)
Article
Engineering, Mechanical
Xiulin Ji, Yiping Shan, Cuicui Ji, Hui Wang, Zhanxi Zhao
Summary: The slurry erosion behaviors of Zr BMGs were investigated, showing an increase in volume loss rate with higher impact angles and velocities, indicating their brittle erosion characteristics. Additionally, surface devitrification and element variations were observed during the erosion tests on the BMGs.
Article
Materials Science, Multidisciplinary
Fei Sun, Shengtao Deng, Jianan Fu, Jiahua Zhu, Dandan Liang, Pengfei Wang, Hang Zhao, Feng Gong, Jiang Ma, Yanhui Liu, Jun Shen
Summary: In this study, an Ir-Ta-Ni-Nb bulk metallic glass (BMG) with outstanding high-temperature wear resistance was demonstrated and its potential applications in extreme environments were revealed. The wear behavior and mechanism were systematically investigated from room temperature to 750 degrees C. The results showed an improvement in wear resistance at a higher temperature of 750 degrees C, attributed to the formation of an oxide layer, which avoids violent wear of the BMG.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Tunji A. Owoseni, Irene Ciudad de Lara, Sribalaji Mathiyalagan, Stefan Bjorklund, Shrikant Joshi
Summary: This study investigates the microstructure, dry sliding, and solid particle erosive wear performance of four different coatings engineered through the configuration of the nozzle of an HVAF spray gun. The densest of the coatings shows comparable performance to the bulk material tested under the same conditions. The results have implications for the potential adoption of HVAF-sprayed coatings in metal component repair.
Article
Materials Science, Multidisciplinary
Yue Ren, Tingyi Yan, Zhuobin Huang, Qing Zhou, Ke Hua, Xiaolin Li, Yin Du, Qian Jia, Long Zhang, Haifeng Zhang, Haifeng Wang
Summary: This study demonstrates an improvement in wear resistance for a Ti-based bulk metallic glass composite at cryogenic temperatures. The wear resistance improvement is associated with the suppressed martensitic transformation and increased strength, making the material an excellent candidate for cryogenic wear applications.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Tianzeng Liu, Yanchun Zhao, Li Feng, Pan Gong
Summary: An ultra-strong Ti-based bulk metallic glass composite was developed using the transformation-induced plasticity effect. This composite enhances the ductility and work-hardening capability of the amorphous matrix and possesses a continuous gradient microstructure. It exhibits good plasticity, toughness, strength, hardness, and wear corrosion resistance.
Article
Materials Science, Ceramics
Bozhuan Lin, Kaihuai Yang, Xiaogang Bao, Jialiang Liu, Qiaohang Guo, Lei Zhang, Qianting Wang, Nengbin Hua
Summary: The study found that oxidation treatment can improve the wear resistance and corrosive-wear performance of Ti-based BMG, especially under wet-friction conditions. Increasing annealing temperature can enhance the resistance to pitting corrosion on the alloy surface.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2022)
Article
Materials Science, Multidisciplinary
Vladislav S. Shikalov, Tomila M. Vidyuk, Artem A. Filippov, Ivanna D. Kuchumova
Summary: This paper presents the investigation results of copper-tungsten coatings with different compositions on aluminum alloy substrates. It was found that increasing tungsten content in the coatings improves their microhardness and Young's modulus, as well as bonding strength. Cu-W coatings show better wear resistance compared to pure copper coatings under dry sliding wear conditions.
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS
(2022)
Article
Engineering, Mechanical
Yongming Zou, Zhaoguo Qiu, Zhigang Zheng, Gang Wang, Xingchen Yan, Shuo Yin, Min Liu, Dechang Zeng
Summary: This study investigated the tribological properties and wear mechanisms of ex-situ additively manufactured FeCrMoCB/Cu bulk metallic glass composite under different normal loads and sliding speeds. The findings showed that the composite exhibited good wear resistance, with the coefficient of friction decreasing and the wear rate increasing as the sliding speed increased. Additionally, the wear mechanisms shifted from abrasive wear to oxidation wear and adhesive wear with increasing normal load, and adhesive wear and fatigue wear became dominant as the sliding speed increased.
TRIBOLOGY INTERNATIONAL
(2021)
Article
Engineering, Manufacturing
Ningsong Fan, Chunjie Huang, Zhongyu Wang, Pengfei Yu, Wen Chen, Rocco Lupoi, Qingge Xie, Lin Liu, Shuo Yin
Summary: In this study, the bonding mechanisms of metallic glass particles and the evolution mechanism of amorphous phase into nanocrystal structures in cold sprayed bulk metallic glass deposits were systematically investigated.
ADDITIVE MANUFACTURING
(2022)
Article
Engineering, Mechanical
Giovanni Bolelli, Daniel Steduto, Jarkko Kiilakoski, Tommi Varis, Luca Lusvarghi, Petri Vuoristo
Summary: Plasma sprayed Cr2O3 is commonly used for wear protection in industrial components. This study investigates how alloying with other oxides can alter its properties. It was found that the addition of TiO2 and ZrO2 to Cr2O3 coatings resulted in lower indentation hardness but higher toughness, impacting sliding wear resistance and abrasion differently.
Article
Materials Science, Multidisciplinary
Qian Jia, Qing Zhou, Yue Ren, Yin Du, Xiaoxing Zhao, Xian-Zong Wang, Haifeng Wang, Ben D. Beake, Feng Zhou
Summary: Ti45Zr16Cu10Ni9Be20 bulk metallic glass with deep cryogenic-cycling treatment (DCT) exhibited increased wear resistance at the cost of decreased hardness in macroscopic wear tests. The wear mechanism shifted from severe fatigue wear to mild ductile ploughing, while oxidation wear played a minor role. The competition between lower hardness and higher elastic recovery resulted in a lower friction coefficient, indicating the potential of DCT in designing wear-resistant BMGs.
MATERIALS CHARACTERIZATION
(2021)
Article
Energy & Fuels
E. R. Kavitha, S. Meiyazhagan, S. Yugeswaran, P. Balraju, K. Suresh
Summary: The study demonstrated the efficient synthesis of Mn3O4 nanoparticles using microplasma array method, which showed high specific capacitance as an electrode material for supercapacitor application. The synthesized nanoparticles exhibited high cyclic stability and energy density, making them promising for practical applications.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Chemistry, Physical
Karuppusamy Mariyappan, Ramasamy Velmurugan, Balasubramanian Subramanian, Pitchai Ragupathy, Mani Ulaganathan
Summary: Platinum-decorated graphite felt can serve as an active electrode material to improve the kinetics of bromine/bromide redox reaction, leading to enhanced efficiency of zinc-bromine flow cell system. The use of low-loading platinum on graphite felt significantly influences the kinetics of the Bromine/Bromide redox reactions, resulting in an average Coulombic efficiency of 99.96% and an ever best average energy efficiency of around 88% when tested at 50 mA cm(-2).
JOURNAL OF POWER SOURCES
(2021)
Retraction
Materials Science, Multidisciplinary
Balasubramanian Subramanian, Ramadoss Ananthakumar, Muthirulandi Jayachandran
Article
Energy & Fuels
Jayashree Swaminathan, Subbiah Ravichandran, Parthiban Palani, Mahendran Mathankumar, Subramanian Balasubramanian
Summary: A series of defect-rich titania with different intrinsic characteristics were prepared and studied in this work, showing that TiO1.81 exhibits better photoelectrocatalytic water splitting activity while TiO1.54 demonstrates superior electrocatalytic hydrogen evolution performance.
Article
Physics, Fluids & Plasmas
Selvakumar Meiyazhagan, Subramaniam Yugeswaran, P. V. Ananthapadmanabhan, Kalidass Suresh
Summary: An array of microplasma jets was used to degrade malachite green dye in aqueous solution under atmospheric conditions. Oxygen plasma generated more hydrogen peroxide and demonstrated higher energy yield compared to air and argon plasma. Treatment with oxygen microplasma significantly reduced the toxicity of the dye and improved tomato seed germination.
IEEE TRANSACTIONS ON PLASMA SCIENCE
(2021)
Article
Biophysics
S. Thanka Rajan, Mitun Das, P. Sasi Kumar, A. Arockiarajan, B. Subramanian
Summary: This study investigates the effect of boron in Ti-Cu-Pd-Zr metallic glass matrix for biomedical implants fabricated by PLD. The results show that increasing boron content in TFMG leads to improved glass transition temperatures and enhances corrosion resistance, passivity, and biocompatibility. This combination of properties makes these TFMG systems potential candidates for biomedical implants.
COLLOIDS AND SURFACES B-BIOINTERFACES
(2021)
Article
Engineering, Electrical & Electronic
V. Anbumannan, R. T. Rajendra Kumar, K. Suresh
Summary: A novel GO/WO3 nanocomposite material was successfully prepared and used for the electrochemical detection of dopamine on a glassy carbon electrode, showing wide linear range, outstanding selectivity, and great performance in real samples with high selectivity and good stability.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2021)
Article
Physics, Fluids & Plasmas
Yugesh Vadikkeettil, Pasupathi Amarnath, Subramaniam Yugeswaran, P. Ananthapadmanabhan
Summary: The study compared the effects of CO2 and air on a DC nontransferred arc plasma torch operated at atmospheric pressure, finding that CO2 has a stronger influence on arc voltage fluctuation, electrothermal efficiency, and operating regime of the plasma torch.
IEEE TRANSACTIONS ON PLASMA SCIENCE
(2022)
Article
Physics, Applied
B. Indumathy, J. Ananthanarasimhan, Lakshminarayana Rao, S. Yugeswaran, P. Ananthapadmanabhan
Summary: This study investigates the production of ammonia using a gliding arc plasma reactor without a catalyst. The formation of ammonia was aided by the vibrational and rotational excitation observed at the tip of the plasma plume when it came into contact with water. The results demonstrate the potential of using gliding arc plasmas to generate eco-friendly ammonia.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2022)
Review
Engineering, Environmental
P. R. Sreedevi, K. Suresh, Guangming Jiang
Summary: Bioremediation, particularly using bacteria, is a sustainable and cost-effective technology for alleviating heavy metal pollution. This review comprehensively discusses the various mechanisms employed by bacteria in heavy metal remediation, such as bioadsorption, bioaccumulation, bioprecipitation, and bioleaching. The study highlights the need for further research to optimize bacterial remediation efficiency and to address challenges in technology translation.
JOURNAL OF WATER PROCESS ENGINEERING
(2022)
Review
Biochemistry & Molecular Biology
P. R. Sreedevi, K. Suresh, S. Yugeswaran
Summary: Cold atmospheric plasma (CAP), as the fourth state of matter, has shown promising applications in medical field, especially in cancer treatment and immunotherapy. It generates reactive oxygen and nitrogen radicals that trigger immune response and induce cell death in tumor cells. CAP also has inhibitory effects on HIV and herpes simplex virus.
FREE RADICAL RESEARCH
(2022)
Article
Materials Science, Multidisciplinary
S. Sivaranjani, V. V. Anusha Thampi, M. Shalini, Gopal Shankar Krishnakumar, Murugan Veerapandian, Dmitry Shtansky, B. Subramanian
Summary: Surface-modified implant materials with improved physicochemical properties and biocompatibility are crucial for osseointegration and bone anchorage. In this study, titanium boron nitride (TiBN) thin films were coated on sandblasted Ti plates, and bioglass (BG) 45S5 overlay was introduced using electrophoretic deposition. The bioglass overlaid TiBN/Ti plates showed excellent cytocompatibility and corrosion resistance.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Karunanithi Balamurugan, Sacratees Santhosh, Mahendran Mathankumar, Balasubramanian Subramanian
Summary: An attempt was made to improve the efficiency of electrochromic (EC) windows by fabricating Nb-NTO thin films using ion-assisted pulsed DC unbalanced confocal magnetron sputtering. A metallic seed layer was incorporated between the substrate and the film to enhance the EC efficiency. The Nb-NTO film showed better EC properties, stability, and recyclability compared to the as-prepared NTO film. The successful fabrication of Nb-NTO devices with a polymer gel electrolyte holds promise for the commercialization of EC windows.
Article
Chemistry, Physical
P. R. Sreedevi, K. Suresh
Summary: Delivery of genetic material is an important tool for analyzing and understanding genetic interventions. Traditional methods rely on viral vectors or xenogenic carrier molecules, which can have carcinogenic, immunogenic, and toxic effects. Cold atmospheric plasma-induced transfection is a new physical method that does not require vectors or carriers. It creates temporary pores on cell membranes for gene delivery. This method has been successfully used in various cell lines and mouse models without adverse effects on cell activity and function.
ADVANCES IN COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou
Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.
APPLIED SURFACE SCIENCE
(2024)
Review
Chemistry, Physical
George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira
Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu
Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata
Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu
Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng
Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong
Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)