Journal
APPLIED SURFACE SCIENCE
Volume 257, Issue 23, Pages 10134-10140Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2011.06.163
Keywords
Zinc oxide; Nanowires; Seed layer; Fluorination; Photoluminescence
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Funding
- Ministry of Science and Technology of China [2009AA03Z218]
- National Natural Science Foundation of China [90923012]
- Xi'an Applied Materials Innovation Fund [XA-AM-200909]
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ZnO nanowire (NW) arrays are assembled on the Al-doped ZnO (AZO) seed layer by a hydrothermal process. Effects of the temperature and growth time of the hydrothermal process on morphological and photoluminescence properties of the as-assembled ZnO NW arrays are characterized and studied. Results indicate that the length and diameter of the ZnO NWs increase with a lengthening of the growth time at 80 degrees C and the hydrothermal temperature has a significant effect on the growth rate and the photoluminescence properties of the ZnO NW arrays. The patterned AZO seed layer is fabricated on a silicon substrate by combining a sol-gel process with an electron-beam lithography process, as well as a surface fluorination technique, and then the ZnO NW arrays are selectively grown on those patterned regions of the AZO seed layer by the hydrothermal process. Room-temperature photoluminescence spectra of the patterned ZnO NW arrays shows that only a strong UV emission at about 380 nm is observed, which implies that few crystal defects exist inside the as-grown ZnO NW arrays. (C) 2011 Elsevier B.V. All rights reserved.
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