Influence of surface treatment on preparing nanosized TiO2 supported on carbon nanotubes

In this paper, nanosize titanium dioxide (TiO2) deposited on pristine and acid treated carbon nanotubes (CNTs) were prepared by a modified sol-gel method. The nanoscale materials were extensively characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectrometer (FTIR) and Raman spectra. The results indicated that about 6.8 nm TiO2 nanoparticles were successfully deposited on acid-treated CNTs surface homogeneously and densely, which was smaller than TiO2 coated on pristine CNTs. The surface state of CNTs was a critical factor in obtaining a homogeneous distribution of nanoscale TiO2 particles. Acid oxidization could etch the surface of CNTs and introduce functional groups, which were beneficial to controllable homogeneous deposition. The TiO2 coated on acid-treated CNTs was used as photocatalyst for Reactive Brilliant Red X-3B dye degradation under UV irradiation, which showed higher efficiency than that of TiO2 coated on pristine CNTs and commercial photocatalyst P25. (C) 2008 Elsevier B.V. All rights reserved.