Multiple pressure-induced transitions in HgCr2S4

We have performed combined experimental and theoretical high-pressure investigations on magnetoelectric HgCr2S4 spinel. Overall, HgCr2S4 exhibits three reversible structural transitions under pressure: the starting Fd-3m phase adopts a tetragonal I4(1)/amd structure at 20GPa, an orthorhombic distortion occurs above 26 GPa, whereas a third structural transition takes place beyond 37 GPa. During the Fd-3m to I4(1)/amd structural transition, HgCr2S4 experiences a volume change of 4% which is unexpected from space group symmetry considerations alone. Furthermore, the Fd-3m to I4(1)/amd transformation appears to be concomitant with an insulator-to-metal transition whereas compression of HgCr2S4 leads to a gradual suppression of its ferromagnetism. (C) 2013 AIP Publishing LLC.