4.6 Article

Poly(phenylene ethynylene)-coated aligned ZnO nanorod arrays for 2,4,6-trinitrotoluene detection

Journal

APPLIED PHYSICS LETTERS
Volume 93, Issue 26, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3063045

Keywords

chemical sensors; crystal growth from solution; explosives; fluorescence; II-VI semiconductors; nanostructured materials; nanotechnology; optical waveguides; polymers; spectral line intensity; zinc compounds

Funding

  1. National Science Foundation of China [20773156, 50503024]
  2. 863 Program [2006AA03Z312]
  3. Chinese Academy of Sciences [KGCX2-YW-118]
  4. Bairen program of CAS
  5. Shanghai Science and Technology Committee [071111010, 08JC1421900]

Ask authors/readers for more resources

The structure of ZnO nanorods coated with fluorescent polymer poly(phenylene ethynylene) (PPE) have been fabricated for 2,4,6-trinitrotoluene (TNT) detection. In this structure, hydrothermally synthesized crystalline ZnO nanorod arrays were used as waveguides and supporting materials for the TNT sensitive polymer, PPE. The evanescent-wave guiding property of the ZnO nanorod waveguide considerably increased fluorescence intensity. The space between the adjacent nanorods and the larger surface-to-volume ratio of the nanorods enhanced the fluorescence response (quenching) to TNT vapor. This work will contribute to design of combining ZnO nanorod arrays with a functional polymer for sensor applications.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Review Materials Science, Textiles

A review on piezoelectric fibers and nanowires for energy harvesting

Bilal Zaarour, Lei Zhu, Chen Huang, XiangYu Jin, Hadeel Alghafari, Jian Fang, Tong Lin

Summary: Recent advances in self-powered electronic devices have led to the development of energy-harvesting technology, with a focus on piezoelectric energy harvesters. Materials such as piezoelectric polymeric fibers, inorganic piezoelectric fibers, and inorganic nanowires show great potential for energy-harvesting applications.

JOURNAL OF INDUSTRIAL TEXTILES (2021)

Article Chemistry, Analytical

A facile approach for significantly enhancing fluorescent gas sensing by oxygen plasma treatments

Yanyan Fu, Jinming Chen, Hao Sun, Keke Li, Wei Xu, Qingguo He, Antonio Facchetti, Jiangong Cheng

Summary: Organic thin-film fluorescent probes for vapor sensing have gained increasing attention for their advantages of simple operation, non-pollution of analytes, and fast response. Modulating surface morphologies through oxygen plasma treatment can significantly enhance sensing performance by shortening response times and lowering detection limits.

SENSORS AND ACTUATORS B-CHEMICAL (2021)

Article Chemistry, Analytical

Detecting methylphenethylamine vapor using fluorescence aggregate concentration quenching materials

Keke Li, Linxin Wang, Jinming Chen, Mingzhu Yan, Yanyan Fu, Qingguo He, Jiangong Cheng

Summary: A high-performance vapor sensor utilizing ACQ fluorescent material was successfully prepared based on doping/breath figure method, achieving solid-state fluorescence emission and porous sensing film fabrication with quick response and low detection limit towards MPEA gas.

SENSORS AND ACTUATORS B-CHEMICAL (2021)

Article Chemistry, Multidisciplinary

Fluorescent Enhancement of CaF2: Nd3+ Nanoparticles through a Concentration-Gradient Core/Shell Hybrid Structure

Tan Wang, Bo Wang, Qingguo He, Jiangong Cheng

Summary: In this study, an efficient core/shell structure for CaF2 : Nd3+ based core/shell NPs was proposed, which successfully synthesized core/shell nanoparticles with gradient doping ions of hybrid Ce3+ and activator (Nd3+), enhancing the fluorescence up to 21.4 times compared to core-only nanoparticles by controlling the doping density and overcoming surface quenching.

CHEMISTRYSELECT (2021)

Article Nanoscience & Nanotechnology

Supramolecule-Originated Emission: A Room-Temperature Phosphorescence 2D Ionic H-Bond Network from Nonemissive Aliphatic Derivatives

Wei Xu, Huan Liu, Fen Mei, Yanyan Fu, Huimin Cao, Qingguo He, Jiangong Cheng

Summary: This study introduces a novel emission strategy from a 2D ionic hydrogen bond supramolecular network, with high-quality crystals obtained from rapid self-assembly of liquid amine and ketone. The charge-separated transition process and high spin-orbital coupling constants in the rigid supramolecular structure contribute to enhanced singlet-triplet intersystem crossing, leading to stable room-temperature phosphorescence with a maximum quantum efficiency of 26% and a lifetime of 0.45 s. These findings will bring fresh thinking to photoluminescence and other functions purely originated by the supramolecular structure.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Analytical

In Situ Turn-On Room Temperature Phosphorescence and Vapor Ultra-sensitivity at Lifetime Mode

Fen Mei, Wei Xu, Bin Li, Zhen Zhu, Yanyan Fu, Huimin Cao, Qingguo He, Jiangong Cheng

Summary: This research achieved in situ phosphorescence "turn-on" sensing for methamphetamine vapor detection by changing the properties of a film, enabling sensitive detection of low-concentration MPEA vapor.

ANALYTICAL CHEMISTRY (2022)

Article Chemistry, Physical

Micro-interfaces modulation by UV-ozone substrate treatment for MPEA vapor fluorescence detection

Bin Li, Keke Li, Wei Xu, Mingzhu Yan, Jianhao Zhao, Wukun Zhang, Mingshuai Yuan, Yanyan Fu, Qingguo He, Jiangong Cheng

Summary: Drug abuse poses a direct threat to human health and social security, making rapid and sensitive detection crucial. The use of organic film-based fluorescent sensing technology has gained attention for its simplicity and speed in drug and explosive detection. This study introduces a novel fluorescent polymer probe and a UV-ozone substrate treatment method to modify the surface morphology of the film. The results show improved sensing performance in detecting methylphenethylamine vapor, with a significantly reduced detection limit.

NANO RESEARCH (2023)

Article Chemistry, Analytical

Tri-probe fluorescent sensor array for a wide concentration range and high precision identification of aqueous organic amines

Mingzhu Yan, Jinming Chen, Bo Wang, Bin Li, Huan Liu, Wei Xu, Huimin Cao, Yanyan Fu, Qingguo He, Jiangong Cheng

Summary: The study introduced a sensing method based on a trTprobe sensor array, which efficiently differentiated aqueous organic amines by designing molecules with various sensing units for rich spectral changes. Different interactions between the probes and amines were identified by NMR, enabling 99.35% accurate discrimination using HCA and LDA.

SENSORS AND ACTUATORS B-CHEMICAL (2022)

Article Engineering, Environmental

A universal strategy for large-scale and controlled fabrication of conductive mesoporous polymer monolayers

Facai Wei, Bowen Chen, Jianwei Fu, Qingguo He, Chengbin Jing, Jiangong Cheng, Miharu Eguchi, Jongbeom Na, Yusuke Yamauchi, Shaohua Liu

Summary: A surface modification method was used to achieve the oriented growth of various mesoporous materials and device fabrication in one step, enabling the construction of large-area ultrathin nanolayers with meso-architectures and simultaneous patterning. This work provides a general control on engineering mesoscale materials and effective integration of material growth, structural control, and device fabrication for potential applications.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Chemistry, Multidisciplinary

Direct Active Site at the Van der Waals Heterostructure Interface with Synthetic Drug Analogue N-Methylphenethylimine Ultrasensitivity

Zhen Zhu, Huan Liu, Pengfei Ding, Yanyan Fu, Huimin Cao, Wei Xu, Qingguo He, Jiangong Cheng

Summary: A one-dimensional van der Waals heterostructure was designed for ultrasensitive vapor sensing by forming a stable SWCNT-probe molecule system with high sensitivity and specificity. The interfacial recognition sites played a crucial role in the sensing response. The sensor achieved a detection limit as low as 3.6 ppt and showed excellent stability over 10 days.

ACS SENSORS (2023)

Article Chemistry, Multidisciplinary

Directional Activated Exciton Highway via Fractal Electric Field Modulation for Ultrasensitive Carbon Nanotube-Based Sensors

Pengfei Ding, Huan Liu, Zhen Zhu, Yanyan Fu, Huizi Li, Huimin Cao, Fanbing Meng, Wei Xu, Qingguo He, Jiangong Cheng

Summary: The electrical vapor sensor based on carbon nanotubes (CNTs) has gained wide attention due to its excellent conductivity and stable interfacial structure. However, limited performance was observed due to the random distribution of coated CNTs. A new strategy was developed to align the CNTs using fractal designing of the electrode system. This led to higher carrier mobility and an ultrasensitive vapor sensor with a detection limit of 0.998 ppq.

ACS SENSORS (2023)

Article Chemistry, Applied

Efficient fluorescent vapour sensing induced by ZnO buffer

Mingshuai Yuan, Wei Xu, Wukun Zhang, Jianhao Zhao, Huizi Li, Qingguo He, Wei Huang, Jiangong Cheng, Yanyan Fu

Summary: Fluorescent film sensors are widely used for detecting toxic gases, but the design and synthesis of high-performance sensitive materials are complex. This study demonstrates that the sensing performance of fluorescent sensors can be enhanced by simply growing or depositing zinc oxide film on a quartz substrate. The catalytic properties of the zinc oxide buffer effectively accelerate the sensing process between the probe molecules and H2O2 gas.

DYES AND PIGMENTS (2023)

Article Chemistry, Analytical

High-sensitivity sensor array base on molecular design and machine learning for amine differentiation in exhaled vapor

Ming-Zhu Yan, Jin-Ming Chen, Bo Wang, Wei Xu, Hui-Min Cao, Yan-Yan Fu, Qing-Guo He, Jian-Gong Cheng

Summary: Most current studies on diagnosing diseases through exhaled gas only focus on single markers, but there are actually biomarkers with similar properties corresponding to different diseases. Existing sensing techniques cannot achieve simultaneous multi-label classification of the targets. By introducing multiple hydrogen bond receptors and adjusting the aromatic ring end group, the strength of the interaction between target molecules and the sensor array can be modulated. Sensor responses related to molecular structure can be used as detection characteristics. Through machine learning, different types of amines can be successfully identified, and this method can also distinguish mixed amines at different concentrations in the range of ppm-ppb.

CHINESE JOURNAL OF ANALYTICAL CHEMISTRY (2022)

Article Chemistry, Analytical

Research progress of breath figure method in device application

Ming-Shuai Yuan, Wei Xu, Qing-Guo He, Jian-Gong Cheng, Yan-Yan Fu

Summary: This article summarizes the application of breath figure method in various fields and discusses its influencing factors and challenges.

CHINESE JOURNAL OF ANALYTICAL CHEMISTRY (2022)

Article Chemistry, Physical

Soft template-mediated coupling construction of sandwiched mesoporous PPy/Ag nanoplates for rapid and selective NH3 sensing

Facai Wei, Yonghui Zhong, Hao Luo, Yong Wu, Jianwei Fu, Qingguo He, Jiangong Cheng, Jongbeom Na, Yusuke Yamauchi, Shaohua Liu

Summary: The study has successfully developed a simple soft template-mediated coupling construction approach to create an unexplored sandwiched mesoporous polypyrrole nanocoating/single-crystal Ag nanoplate hybrid. This hybrid exhibits an adjustable meso-structure and architecture, strong near-infrared absorption and Raman enhancement effect, as well as outstanding chemical sensing performance.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

No Data Available