4.6 Article

Novel synthesis of pinacols and sulfones promoted by Sm-NiCl2 bimetallic system

Journal

APPLIED ORGANOMETALLIC CHEMISTRY
Volume 25, Issue 5, Pages 331-334

Publisher

WILEY
DOI: 10.1002/aoc.1763

Keywords

Sm-NiCl2; reductive coupling; pinacols; sulfones; bimetallic system

Funding

  1. Natural Science Foundation of Zhejiang Province [Y4100783]

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Sm-NiCl2 as a reductive system promoted reductive coupling of aryl adehydes and aryl ketone into pinacols in good yields and also promoted coupling reaction of aryl sulfonyl chlorides and active halides into sulfones in good yields. Copyright (C) 2011 John Wiley & Sons, Ltd.

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