Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 23, Issue 5, Pages 179-182Publisher
WILEY-BLACKWELL
DOI: 10.1002/aoc.1490
Keywords
chiral N-heterocyclic carbene; rhodium complex; ferrocene; asymmetric transfer hydrogenation; ketones
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Funding
- National Natural Science Foundation of China [20302014, 20672141, 20872180]
- Shaanxi Province [2007K01-35]
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A novel chelated ferrocene-based planar chiral N-heterocyclic carbene-Rh(I) complex was synthesized by a simple method. It was applied to the asymmetric transfer hydrogenation of prochiral ketones. Enantioselectivities of up to 67% ee were observed. Copyright (C) 2009 John Wiley & Sons, Ltd.
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