Article
Environmental Sciences
Oxana N. Fedyaeva, Sergey Morozov, Anatoly A. Vostrikov
Summary: This study investigated the oxidation of watered toxic waste from the pulp and paper industry in supercritical water-oxygen fluid, revealing that only CO2, CO, N2, and N2O were detected in volatile oxidation products at higher oxygen content. Increasing the oxygen ratio led to a decrease in phenols and chlorophenols produced, with 2,6-dichlorophenol and 2-chlorophenol being the most resistant to oxidation.
Review
Chemistry, Multidisciplinary
Shaoxuan Yang, Yihuan Yu, Xinjin Gao, Zhengping Zhang, Feng Wang
Summary: The applications of phthalocyanines (Pcs) in electrocatalysis have attracted attention due to their advantages of low cost, facile synthesis, and good chemical stability. Pcs offer high tailorability and structural diversity, making them promising for optimization in electrochemical devices and for various electrochemical reactions. Further research is needed to explore the structure-composition catalytic activity relationships of different Pc materials for future practical applications.
CHEMICAL SOCIETY REVIEWS
(2021)
Article
Engineering, Environmental
Jing Ai, Dominique J. Tobler, Cecilie Gry Duncan-Jones, Maria Eckardt Manniche, Kirstine Evald Andersson, Hans Christian B. Hansen
Summary: This study found that HCO3- has the greatest impact on the dechlorination rates of CE in the reaction process of GR-BC, and the presence of silicic acid leads to varying degrees of reduction in reaction rate. Contaminated groundwater matrices significantly decrease the reactivity of the GR-BC composite.
ENVIRONMENTAL SCIENCE-WATER RESEARCH & TECHNOLOGY
(2021)
Article
Chemistry, Physical
Youxuan Ni, Weiwei Xie, Jun Chen
Summary: This study investigates the influence of axial coordination on the activity of Fe/Co/Ni-tetraphenylporphyrin covalent organic frameworks (Fe/Co/Ni-TPP COFs) in the oxygen reduction reaction (ORR) using the density functional theory (DFT) method. The commonly used descriptors are found to be insufficient in explaining the axial coordination effect on metal reactivity. The hybridization between the dz2 orbital of metal centers and pz orbital of axial coordination atoms leads to the formation of new active orbitals, which should be considered in the design of activity descriptors.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Multidisciplinary
Chang Chen, Yifan Li, Aijian Huang, Xuerui Liu, Jiazhan Li, Yu Zhang, Zhiqiang Chen, Zewen Zhuang, Yue Wu, Weng-Chon Cheong, Xin Tan, Kaian Sun, Zhiyuan Xu, Di Liu, Zhiguo Wang, Kebin Zhou, Chen Chen
Summary: Introducing a second metal species into M-N-C catalysts to construct DASs is an effective strategy. We developed a two-step specific adsorption strategy to construct FeCo-MHs catalyst and directly identified individual FeCo-MHs through in situ rotation. The FeCo-MHs catalyst exhibits exceptional ORR activity and can be used for high-performance cathodes in fuel cells and zinc-air batteries.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Nanoscience & Nanotechnology
Guo-Bi Li, Jing Chen, Hao-Ran Liu, Bai-Qiao Song, Shuang Ni, Rong-Kai Pan, Qing-Yuan Yang
Summary: In this study, a newly developed coordination framework [Zn(4-pmntd)(opa)] is presented, which shows a high adsorption capacity for chloroform and an excellent ability to separate chloroform from water. The effectiveness of chloroform extraction by [Zn(4-pmntd)(opa)] was confirmed through various methods. A filtration film created using natural rubber successfully separated chloroform from water with high purity. Therefore, [Zn(4-pmntd)(opa)] has significant potential for low-energy separation and recycling of chloroform from water under ambient conditions.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Yuji Hamamoto, Hiroyuki Sawada, Sasfan Arman Wella, Kouji Inagaki, Ikutaro Hamada, Yoshitada Morikawa
Summary: The structural and electronic properties of lead phthalocyanine (PbPc) adsorbed on graphene are studied theoretically using the van der Waals density functional method. It is found that an extended state similar to an image potential state (IPS) emerges in a close-packed PbPc monolayer, hybridizing with the lowest IPS of graphene to form bonding and antibonding states at the PbPc-graphene interface. The effective masses of the hybrid IPSs are increased due to the adsorption of PbPc.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Physical
Yeongdae Lee, Jang Hyuk Ahn, Haeseong Jang, Jisu Lee, Subhin Yoon, Dong-Gyu Lee, Min Gyu Kim, Jun Hee Lee, Hyun-Kon Song
Summary: The strong interaction between molecular catalyst (FePc) and support (1L-Ti3C2) was found to decrease the potential required for reducing oxygen, facilitating the oxygen reduction reaction (ORR) via a four-electron process.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Engineering, Environmental
Wen Si Lee, Hamidi Abdul Aziz, Husnul Azan Tajarudin
Summary: This paper reviews recent developments in the application of iron-oxidizing bacteria (IOB) in water and wastewater treatment, discussing oxidation processes, species variations, applications, challenges, issues, and future prospects. Although IOB technology is preferred for its low cost and environmental friendliness, the presence of IOB in piping systems may cause microbiologically influenced corrosion (MIC).
JOURNAL OF WATER PROCESS ENGINEERING
(2022)
Article
Environmental Sciences
Ekaterina Pleshakova, Clement Ngun, Mikhail Reshetnikov, Maxim Viktorovich Larionov
Summary: The study investigated the ability of microorganisms isolated from highly magnetic soil in the city of Mednogorsk to oxidize Fe (II) under liquid cultivation conditions. Two microbial isolates with the strongest iron-oxidizing activity were selected and identified, showing potential for future use in biotechnological processes for water purification.
Article
Engineering, Environmental
Daniele Scheres Firak, Luca Farkas, Mate Nafradi, Tunde Alapi
Summary: The chlorination used in water treatment plants can promote the formation of toxic compounds, which can be minimized by substituting free available chlorine (FAC) with chlorine dioxide (ClO2).UV radiation in combination with ClO2 can efficiently eliminate organic substances. The study investigated the efficiency of the UVA/ClO2 process and the formation of hydroxylated and chlorinated products during the degradation of phenol and coumarin.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Multidisciplinary
Mario Urso, Martina Ussia, Martin Pumera
Summary: A novel method utilizing self-propelled light-powered magnetic field-navigable microbots for actively moving, capturing, and degrading polymers is proposed in a recent study. These microbots exhibit fuel-free motion capability, and the motion can be controlled by light and directionality by a magnetic field. The efficient degradation of polymers is demonstrated, showing promising potential for degrading polymers and plastics effectively using light.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Tom Klaproth, Martin Knupfer, Anna Isaeva, Maria Roslova, Bernd Buechner, Andreas Koitzsch
Summary: This study investigates the interface of manganese(II) phtalocyanine (MnPc) with an alpha-RuCl3 single crystal using photoelectron spectroscopy. The results show that alpha-RuCl3 has similar electronic properties to common fluorinated acceptor molecules, but with the potential to absorb more electrons at interfaces. This makes it a promising strong acceptor material for organic molecules at interfaces.
Article
Chemistry, Analytical
Darya Klyamer, Alexandr Sukhikh, Dmitry Bonegardt, Pavel Krasnov, Pavel Popovetskiy, Tamara Basova
Summary: Halogenated metal phthalocyanines are promising materials for chemiresistive sensors. In this study, films of novel tetrachlorosubstituted vanadyl phthalocyanine derivatives were prepared and studied to investigate the effect of substituent position on the chemiresistive response to low concentrations of NH3. It was found that films with substituents in the peripheral position exhibited a higher sensor response to NH3 than films with nonperipheral substituents.
Article
Electrochemistry
Soichiro Yoshimoto, Shunta Hashiguchi, Yukina Maruyama, Sakura Origuchi, Yuri Katagiri, Michito Yoshizawa
Summary: The electrochemical properties of water-insoluble Fe-tetraphenylporphyrins and Fe-phthalocyanines encapsulated in molecular capsules were improved in acidic and alkaline solutions. These capsules enhanced the O-2 reduction reaction and acted as electrochemical nanoreactors.
ELECTROCHEMISTRY COMMUNICATIONS
(2022)
Article
Engineering, Chemical
Petr Kluson, Petr Stavarek, Vera Penkavova, Hana Vychoclilova, Stanislav Hejda, Magdalena Bendova, Marek Dosek
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2020)
Article
Engineering, Chemical
Matthieu Weber, Martin Drobek, Bertrand Rebiere, Christophe Charmette, Jim Cartier, Anne Julbe, Mikhael Bechelany
JOURNAL OF MEMBRANE SCIENCE
(2020)
Article
Engineering, Chemical
Anita Haeussier, Stephane Abanades, Anne Julbe, Julien Jouannaux, Martin Drobek, Andre Ayral, Bruno Cartoixa
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2020)
Article
Chemistry, Multidisciplinary
Ismael Pellejero, Fernando Almazan, Marta Lafuente, Miguel A. Urbiztondo, Martin Drobek, Mikhael Bechelany, Anne Julbe, Luis M. Gandia
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2020)
Article
Environmental Sciences
Pavel Krystynik, Pavel Masin, Zuzana Krusinova, Petr Kluson
Article
Environmental Sciences
Tereza Cerna, Katerina Prazanova, Hynek Benes, Ivan Titov, Katerina Klubalova, Alena Filipova, Petr Kluson, Tomas Cajthaml
Summary: The study found that biodegradable polyurethane microplastics exhibited strong accumulation of polycyclic aromatic hydrocarbons in soil over time, while conventional polyurethane microplastics showed lower sorption capacity for PAHs and did not change their sorption behavior after aging.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Engineering, Chemical
Pavel Krystynik, Petr Kluson, Michal Vesely, Petr Dzik, Josef Krysa
Summary: The concept of active sites in heterogeneous catalysis and photocatalysis differs, with the former being stable and constant, while the latter depends on the availability of photons and the catalyst's varying ability to utilize them. A dynamic active site concept for heterogeneous oxidation photocatalysts has been elaborated, allowing for straightforward application of standard kinetic models.
CHEMICAL ENGINEERING & TECHNOLOGY
(2021)
Review
Chemistry, Multidisciplinary
Pavel Krystynik, Katarina Strunakova, Michal Syc, Petr Kluson
Summary: The paper provides a brief overview of the most tested methods of microplastics removal, pointing out the frequent reports on the occurrence of microplastic particles in water but less frequent complex reviews on methods of their removal.
APPLIED SCIENCES-BASEL
(2021)
Review
Chemistry, Physical
Susmita Dolai, Susanta Kumar Bhunia, Petr Kluson, Petr Stavarek, Anna Pittermannova
Summary: Graphitic carbon nitride (g-C3N4)-based photocatalysts, known for their unique carbon and nitrogen atom arrangement, have diverse applications such as batteries and photovoltaics. Recent research has focused on solvent-assisted supramolecular-assembled carbon nitride synthesis for visible light induced hydrogen evolution. The study discusses non-covalent interactions, the crucial role of solvents, and mechanistic pathways of supramolecular assembly.
Article
Nanoscience & Nanotechnology
Nikos Kyriakou, Louis Winnubst, Martin Drobek, Sissi de Beer, Arian Nijmeijer, Marie-Alix Pizzoccaro-Zilamy
Summary: Polyimide networks are crucial for developing stable, resilient, and efficient membranes for separation applications under demanding conditions. A simple nanofabrication approach was presented to achieve controlled nanoconfinement, growth, and attachment of PI networks inside the mesopores of gamma-alumina layers. These hybrid PI/ceramic membranes showed stable performance in various solvents, making them highly efficient in challenging separations of small organic dye molecules. This technique opens up possibilities for a multitude of separations and other applications requiring porosity and stability control.
ACS APPLIED NANO MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Wanda Kellouai, Patrick Judeinstein, Marie Plazanet, Simon Baudoin, Martin Drobek, Anne Julbe, Benoit Coasne
Summary: Molecular simulations and experiments were conducted to investigate methane adsorption in MFI zeolite. The results showed qualitative and quantitative differences in adsorption behavior between internal porosity and external surface of the zeolite. A thermodynamic formalism was proposed to predict methane adsorption in nanoporous solids, providing a general rational framework for fluid adsorption in finely divided materials.
Article
Energy & Fuels
Pavel Krystynik, Petr Kluson, Pavel Masin, Michal Syc, Josef Jadrny, Zuzana Krusinova
Summary: This paper focuses on the full-scale operation of electrocoagulation for removing Zn from wastewater originated from a municipal incineration plant. The process was custom designed for continuous operation at a capacity of 1200-1400 L/h. Residual concentrations of Zn in the treated water were consistently below 0.5 mg/L. The cost analysis revealed electricity consumption of 0.75-1.1 kWh/m3 of purified water and a significant expense for electrode cartridges.
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
(2023)
Article
Environmental Sciences
S. Hejda, D. Buzek, P. Kluson, O. Bajt
Summary: This study focuses on the detailed investigation of photocatalyzed degradation of dibutyl phthalate (DBP) in the presence of alpha-FeOOH and different carboxylic acids. The influence of various parameters on the degradation efficiency is examined, and the reaction mechanism involving the formation of reactive species and Fe-ligands is explained. Overall, the photodegradation of DBP with goethite and suitable carboxylic acids under optimized conditions proves to be an efficient process for decontaminating polluted waters.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2023)
Article
Engineering, Chemical
Zuzana Krusinova, Michaela Prokopova, Pavel Krystynik, Petr Kluson, Martin Pivokonsky
Summary: Electrocoagulation (EC) is a viable method for removing various pollutants, including humic substances, from drinking water. However, its efficacy in removing algal organic matter (AOM) is not well-documented. This review outlines the properties of AOM, the principles of chemical coagulation and EC, and the current knowledge of AOM coagulation. Although EC shows promise for AOM removal, there is a lack of consistent approaches and thorough optimization of operating conditions and reporting of residual metal concentrations in existing studies. Future research should focus on fully optimizing EC for AOM removal, comparing it directly with chemical coagulation, and testing EC for the removal of mixtures of AOM, humic substances, and inorganic particles.
CHEMBIOENG REVIEWS
(2023)
Review
Materials Science, Multidisciplinary
Susmita Dolai, Susanta Kumar Bhunia, Sathish Rajendran, Varsha UshaVipinachandran, Sekhar Chandra Ray, Petr Kluson
Summary: Carbon dots are emerging nanomaterials with environmental friendliness, brightness, tunable fluorescence, and low toxicity, offering potential applications in various fields. Their synthesis, fluorescence properties, and applications in sensing and recognition of volatile organic compounds have been extensively researched.
CRITICAL REVIEWS IN SOLID STATE AND MATERIALS SCIENCES
(2021)
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)