Influence of preparation methods of LaCoO3 on the catalytic performances in the decomposition of N2O

This study reports the potential interest of LaCoO3 in the catalytic decomposition of N2O from nitric acid plants. Typically, the exhaust gas contains NO, water and O-2 which usually induce strong inhibiting effects depending on the surface properties of the solids particularly the surface mobility of oxygen from LaCoO3. Different preparation methods have been implemented, involving citrate route, reactive grinding and the use of templates, which lead to different structural and textural properties examined by X-ray diffraction, transmission electron microscopy and N-2 physisorption. EDX analysis and XPS measurements also revealed that different surface composition may alter subsequent interactions between the surface and the reactants and related catalytic performances. LaCoO3 prepared by reactive grinding was found to be the most active catalyst due to a high specific surface area but the presence of Fe and Zn impurities inherent to the preparation method were suggested to interfere on the catalytic performances. (C) 2009 Elsevier B.V. All rights reserved.