Article
Biochemistry & Molecular Biology
Zhongwei Zhao
Summary: This Mini-review summarizes the latest evidence of hydroxyl radical generation from physiologically relevant Fenton-like reactions of iron(II) complexes with physiological ligands in human blood plasma. The findings strongly challenge the previous proposal.
FREE RADICAL BIOLOGY AND MEDICINE
(2023)
Article
Engineering, Environmental
Nayara de Melo Costa-Serge, Rosembergue Gabriel Lima Goncalves, Hernan Dario Rojas-Mantilla, Celso Valentim Santilli, Peter Hammer, Raquel Fernandes Pupo Nogueira
Summary: The catalytic activity of layered double hydroxides, with and without copper insertion, was evaluated for the degradation of sulfathiazole. The insertion of copper increased the specific area of the material and degradation kinetics, achieving complete removal of STZ. The presence of Cu(II) and Cu(I) surface sites contributed to the generation of radicals crucial for the degradation process.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Engineering, Environmental
Zhongyi Fang, Jie Zhao, Yuan Li, Yu Wang, Tian Qiu, Yanlin Wu, Wenbo Dong, Gilles Mailhot
Summary: This study demonstrated that the environmental-friendly component (+)-catechin (CAT) was an efficient promoter of Fenton-like system for Bisphenol A (BPA) degradation. The modified system achieved high BPA removal efficiency and the reaction mechanism between CAT and Fe(III) as well as the degradation pathways were studied.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Xiru Chen, Xinyue Gu, Chao Wang, Liuqing Huang, Dingding Wu, Hao Wu, Sijia Liang, Jingyi Ling, Cheng Gu
Summary: Phthalic acid esters (PAEs), commonly used as plasticizers to improve the flexibility of materials, are widely distributed in soil and wastewater, raising public concerns due to their endocrine-disrupting effects. A ferrihydrite-H2O2-bisulfite ternary system was developed for efficient degradation of dimethyl phthalate (DMP) in this study. Hydroxyl radical (・OH) was identified as the dominant reactive species for DMP degradation. The study also showed that bisulfite-assisted heterogeneous Fenton-like reactions could be a potential in-situ soil remediation technology for efficient degradation of PAEs.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Giuk Lee, Chan Woo Kim, Jeong Ryul Choi, Kyung Hyun Min, Hong Jae Lee, Kyu Hwan Kwack, Hyeon-Woo Lee, Jae-Hyung Lee, Seo Young Jeong, Kiyuk Chang, Sang Cheon Lee
Summary: CuAS-PMs is a new class of Fenton-like catalytic nanosystems that can manipulate ROS for anticancer therapy. It can effectively kill cancer cells by releasing highly cytotoxic hydroxyl radicals and suppress solid tumor growth without systemic toxicity, showing great potential for cancer-specific therapy.
JOURNAL OF CONTROLLED RELEASE
(2022)
Article
Engineering, Environmental
Zhaojie Jiao, Haifeng Gong, Ye Peng, Guilin Zhou, Xianming Zhang, Xu Gao, Yunqi Liu
Summary: This paper investigates a novel Fenton-like reaction system with copper sulfate as a catalyst for the degradation of quinoline, a target pollutant in water treatment. The results show that under specific conditions of catalyst dosage, H2O2 dosage, reaction temperature, and initial concentration, the removal effect of quinoline and total organic carbon (TOC) is significant. Moreover, the system exhibits good adaptability to pH values within a certain range. The study provides technical support for the treatment of organic wastewater.
ENVIRONMENTAL ENGINEERING RESEARCH
(2022)
Article
Engineering, Environmental
Zhichao Yang, Chao Shan, Bingcai Pan, Joseph J. Pignatello
Summary: The study utilized the biodegradable chelating agent PICA to accelerate the efficiency of the Fenton reaction in acidic conditions, and found that PICA-Fe-III-OOH may be an effective oxidant. Compared to HO center dot, PICA-Fe-III-OOH is less sensitive to scavengers in environmental water samples.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2021)
Review
Engineering, Environmental
Yangxian Liu, Shuo Shi, Yan Wang
Summary: Removal of pollutants from gas streams using Fenton-like oxidation systems has gained attention for its promising multi-pollutant removal capability. However, challenges like metal ion recovery, low radical utilization, and system stability remain to be addressed. Strategies like catalyst synthesis, mass transfer enhancement, and reactor optimization are proposed to overcome the existing defects and improve the efficiency of these technologies.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Engineering, Environmental
Liang Liu, Jiajun Li, Xiaoxi Guo, Hongyang Wu, Jiabao Wu, Yongzhen Dong, Yunfang Li, Yao Lu
Summary: This study investigates the influence of ethylene glycol (EG) solvent on the performance of Cu-Co catalyst for MNZ degradation. The use of EG solvent enhances catalyst surface area, exposing more active sites with higher Cu+ and Cu2+ content, resulting in improved MNZ degradation efficiency. This research provides valuable insights into catalyst design and optimization, highlighting the potential of EG solvent for industrial application in antibiotic organic pollutant remediation.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Engineering, Environmental
Nannan Wang, Liangwei Li, Yuhang Zhang, Yanhe Han, Zaixing Li
Summary: Fe2O3/CFA, prepared by loading Fe2O3 onto raw coal fly ash (RCFA), exhibits excellent catalytic performance in the treatment of refractory organic wastewater, showing high removal efficiency for p-nitrophenol (PNP) simulated wastewater under optimal conditions. The Fenton-like process involves the generation of various reactive oxygen species, with hydroxyl radicals (center dot OH) playing a crucial role in PNP degradation. Fe2O3/CFA maintains its catalytic capability in the advanced treatment of real coking wastewater, and further optimization of the preparation process can reduce the treatment cost.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Applied
Zuzana Lomozova, Marcel Hrubsa, Palma Federica Conte, Eugenia Papastefanaki, Monika Moravcova, Maria Carmen Catapano, Ilaria Proietti Silvestri, Jana Karlickova, Radim Kucera, Katerina Macakova, Premysl Mladenka
Summary: Structural differences in flavonoids can result in different effects on copper reduction, Fenton reaction, and erythrocyte lysis, showing varied antioxidant or prooxidant behavior depending on the model.
Article
Environmental Sciences
Xiao-Yuan Lv, Guan-Ping Jin, Ding-Kun Yuan, Yan-Feng Ding, Peng-Xing Long
Summary: Copper hexacyanocobaltate was electro-deposited on amino-graphene-coated indium-tin-oxide glass to form a multifunctional heterogeneous catalyst, which was utilized to establish a novel heterogeneous photo-electro-Fenton-like system capable of generating hydrogen peroxide and hydroxyl radical simultaneously. The system showed high productivity of hydroxyl radicals and efficient degradation of levofloxacin in neutral media.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Review
Chemistry, Physical
Negin Farhadian, Shiquan Liu, Anvar Asadi, Mohsen Shahlaei, Sajad Moradi
Summary: Fenton reactions, classified as homogeneous and heterogeneous, are efficient processes used in water remediation. Heterogeneous Fenton processes, using solid catalysts containing iron instead of dissolved iron, have shown higher catalytic activity compared to unsupported iron oxides. Iron-containing silica composites have been widely used for the removal of organic pollutants from aqueous solutions.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Environmental Sciences
Kaiqi Lu, Mingming Gao, Bo Sun, Mei Wang, Shuguang Wang, Xinhua Wang
Summary: This study established a coupling effect of Cr-Fenton-like reaction and Cr flocculation for simultaneous removal of Cr and organic pollutants. The formation of Cr flocs was crucial in providing heterogeneous catalytic regions for the coupling effect. Application of this coupling effect achieved high removal rates for Cr and organic carbon in simulated wastewater, presenting a sustainable and eco-friendly strategy for remediation.
Article
Engineering, Environmental
Chongqing Wang, Rong Huang, Ruirui Sun, Hui Wang
Summary: A novel Cu-C3N4 was synthesized and used as an effective Fenton-like catalyst for dye degradation. The degradation of MB reached 96% within 30 minutes in the Cu-C3N4/H2O2/ultrasound system. Cu-C3N4 showed good reusability and effectiveness in degrading dyes over a broad pH range.
WATER SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Roberto Nistico, Flavia Franzoso, Federico Cesano, Domenica Scarano, Giuliana Magnacca, Maria E. Parolo, Luciano Carlos
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2017)
Article
Chemistry, Physical
Jorge A. Donadelli, Luciano Carlos, Antonio Arques, Fernando S. Garcia Einschlag
APPLIED CATALYSIS B-ENVIRONMENTAL
(2018)
Article
Environmental Sciences
Roberto Nistico, Federico Cesano, Flavia Franzoso, Giuliana Magnacca, Domenica Scarano, Israel G. Funes, Luciano Carlos, Maria E. Parolo
Article
Biophysics
Jorge A. Donadelli, Fernando S. Garcia Einschlag, Enzo Laurenti, Giuliana Magnacca, Luciano Carlos
COLLOIDS AND SURFACES B-BIOINTERFACES
(2018)
Article
Engineering, Environmental
Roberto Nistico, Luisella R. Celi, Alessandra Bianco Prevot, Luciano Carlos, Giuliana Magnacca, Elena Zanzo, Maria Martin
JOURNAL OF HAZARDOUS MATERIALS
(2018)
Article
Materials Science, Multidisciplinary
Alejandro Koffman-Frischknecht, Marcos Soldera, Flavio Soldera, Mauricio Troviano, Luciano Carlos, M. Dolores Perez, Kurt Taretto
Editorial Material
Nanoscience & Nanotechnology
Maria Giulia Faga, Roberto Nistico, Jana Kukutschova, Giuliana Magnacca, Luciano Carlos
JOURNAL OF NANOMATERIALS
(2018)
Article
Chemistry, Physical
Marcos E. Peralta, Roberto Nistico, Flavia Franzoso, Giuliana Magnacca, Laura Fernandez, Maria E. Parolo, Emilio Garcia Leon, Luciano Carlos
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
(2019)
Article
Chemistry, Physical
Marcos E. Peralta, Sushilkumar A. Jadhav, Giuliana Magnacca, Dominique Scalarone, Daniel O. Martire, Maria E. Parolo, Luciano Carlos
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2019)
Article
Chemistry, Analytical
Roberto Nistico, Luciano Carlos
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2019)
Article
Chemistry, Multidisciplinary
Francisca Aparicio, Juan Pablo Escalada, Eduardo De Geronimo, Virginia C. Aparicio, Fernando S. Garcia Einschlag, Giuliana Magnacca, Luciano Carlos, Daniel O. Martire
Article
Engineering, Environmental
Marcos E. Peralta, Daniel O. Martire, M. Sergio Moreno, Maria E. Parolo, Luciano Carlos
Summary: This study developed new magnetic silica-based nanoadsorbents and evaluated their potential application in removing various organic pollutants. The results showed that MMST-Ph was more efficient in adsorbing PAHs and aliphatic hydrocarbons, demonstrating the promising potential of surface-modified magnetic silica nanoparticles for water pollution control.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Review
Chemistry, Inorganic & Nuclear
Marcos E. Peralta, Santiago Ocampo, Israel G. Funes, Florencia Onaga Medina, Maria E. Parolo, Luciano Carlos
Article
Engineering, Environmental
Jorge A. Donadelli, Bruno Caram, Maria Kalaboka, Margarita Kapsi, Vasilios A. Sakkas, Luciano Carlos, Fernando S. Garcia Einschlag
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2020)
Article
Engineering, Environmental
Flavia Franzoso, Roberto Nistico, Federico Cesano, Ingrid Corazzari, Francesco Turci, Domenica Scarano, Alessandra Bianco Prevot, Giuliana Magnacca, Luciano Carlos, Daniel O. Martire
CHEMICAL ENGINEERING JOURNAL
(2017)
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)