4.6 Review Book Chapter

The Density Matrix Renormalization Group in Quantum Chemistry

Journal

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 62
Volume 62, Issue -, Pages 465-481

Publisher

ANNUAL REVIEWS
DOI: 10.1146/annurev-physchem-032210-103338

Keywords

strong correlation; multireference; active space; matrix product states; tensor networks

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The density matrix renormalization group is a method that is useful for describing molecules that have strongly correlated electrons. Here we provide a pedagogical overview of the basic challenges of strong correlation, how the density matrix renormalization group works, a survey of its existing applications to molecular problems, and some thoughts on the future of the method.

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