Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 5, Pages 1574-1577Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410454
Keywords
fluorescence; hybrid materials; iron(II); spin crossover; synergetic effects
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Funding
- National Natural Science Foundation of China [21325103]
- National Basic Research Program of China (973 program) [2014CB845601, 2014CB845605]
- Specialized Research Fund for the Doctoral Program of Higher Education [20110121110012]
- Special Project of National Major Scientific Equipment Development of China [2012YQ120060]
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Hybrid materials integrated with a variety of physical properties, such as spin crossover (SCO) and fluorescence, may show synergetic effects that find applications in many fields. Herein we demonstrate a promising post-synthetic approach to achieve such materials by grafting fluorophores (1-pyrenecarboxaldehyde and Rhodamine B) on one-dimensional SCO FeII structures. The resulting hybrid materials display expected one-step SCO behavior and fluorescent properties, in particular showing a coupling between the transition temperature of SCO and the temperature where the fluorescent intensity reverses. Consequently, synergetic effect between SCO and fluorescence is incorporated into materials despite different fluorophores. This study provides an effective strategy for the design and development of novel magnetic and optical materials.
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