4.8 Article

Multifunctional Redox Polymers: Electrochrome, Polyelectrolyte, Sensor, Electrode Modifier, Nanoparticle Stabilizer, and Catalyst Template

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 32, Pages 8445-8449

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201403062

Keywords

biferrocenes; click chemistry; heterogeneous catalysis; nanoparticles; polymers

Funding

  1. Univ. Bordeaux and Toulouse III
  2. CNRS
  3. Ministere de l'Enseignement Superieur et de la Recherche

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Simple click polycondensation metallopolymers of redox-robust bis(ethynyl) biferrocene (biFc) and di(azido) poly(ethylene glycol) (PEG400 and PEG1000) were designed for multiple functions including improvement of water solubility and biocompatibility, the introduction of mixed valency and sensing capabilities, and as nanoparticle stabilizers for catalysis.

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