Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 27, Pages 6893-6897Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404209
Keywords
atmospheric chemistry; energetic materials; nitryl isocyanide; quantum chemistry; rocket propellants
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Funding
- Sweden-America Foundation
- Swedish Research Council
- National Science Foundation
- Office of Naval Research
- Air Force Office of Scientific Research
- Defense Threat Reduction Agency
- Fonds quebecois de la recherche sur la nature et les technologies (FQRNT)
- Natural Sciences and Engineering Research Council of Canada
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The elusive nitryl cyanide, NCNO2, has been synthesized and characterized. It was prepared in good yield, isolated by fractional condensation, characterized by NMR and vibrational spectroscopy, and studied by theoretical calculations. Nitryl cyanide holds promise as a high energy density material (HEDM) and might also prove useful as a HEDM building block. The simplicity and inherent stability of nitryl cyanide, together with the known multitude of nitriles in interstellar space, suggest that the compound might also be a potential candidate for observations in atmospheric and interstellar chemistry.
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