Catalytic Asymmetric Intramolecular Homologation of Ketones with α-Diazoesters: Synthesis of Cyclic α-Aryl/Alkyl β-Ketoesters

Toward a Symphony of Reactivity: Cascades Involving Catalysis and Sigmatropic Rearrangements

(2014) Amanda C. Jones et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Euphorbia Diterpenes: Isolation, Structure, Biological Activity, and Synthesis (2008–2012)

(2014) Andrea Vasas et al.   CHEMICAL REVIEWS

Development of a Concise Synthesis of (+)-Ingenol

(2014) Steven J. McKerrall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Unsymmetrical Ketones from Tosylhydrazones and Aromatic Aldehydes via Formyl C–H Bond Insertion

(2014) Daniel M. Allwood et al.   ORGANIC LETTERS

Chiral N,N′-dioxide ligands: synthesis, coordination chemistry and asymmetric catalysis

(2014) Xiaohua Liu et al.   Organic Chemistry Frontiers

Recent Developments in Asymmetric Phase-Transfer Reactions

(2013) Seiji Shirakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Free Intramolecular Formal Carbon Insertion into σ-CC Bonds: A New Approach toward Phenanthrols and Naphthols

(2013) Ying Xia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Homologation of α-Ketoesters with α-Diazoesters: Synthesis of Succinate Derivatives with Chiral Quaternary Centers

(2013) Wei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development of Synthetic Transformations by Control of Acid-Catalyzed Reactions of Diazocarbonyl Compounds

(2013) Takuya Hashimoto et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Catalytic asymmetric semipinacol rearrangements

(2013) Shao-Hua Wang et al.   CHEMICAL COMMUNICATIONS

Towards the Synthesis of Lyngbyaloside B: Stereoselective Synthesis of the C1-C16 Macrolactone Core Segment

(2013) Jhillu S. Yadav et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

(2013) Allen Y. Hong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Acyclic Ketones by Catalytic, Bidirectional Homologation of Formaldehyde with Nonstabilized Diazoalkanes. Application of a Chiral Diazomethyl(pyrrolidine) in Total Syntheses of Erythroxylon Alkaloids

(2013) Andrew J. Wommack et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Insertion of Diazoesters into Aryl-CHO Bonds: Highly Enantioselective Construction of Chiral All-Carbon Quaternary Centers

(2013) Lizhu Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Approach to the Tricyclic Core of the Tigliane–Daphnane Diterpenes. Concerning the Utility of Transannular Aldol Additions

(2013) Arthur J. Catino et al.   ORGANIC LETTERS

A Catalytic Asymmetric Ring-Expansion Reaction of Isatins and α-Alkyl-α-Diazoesters: Highly Efficient Synthesis of Functionalized 2-Quinolone Derivatives

(2012) Wei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis and Biosynthetic Implications of (+)-Fusarisetin A

(2012) Jun Yin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of α-Alkyl-β-ketoesters: Asymmetric Roskamp Reaction Catalyzed by an Oxazaborolidinium Ion

(2012) Lizhu Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Progress toward the Syntheses of (+)-GB 13, (+)-Himgaline, and Himandridine. New Insights into Intramolecular Imine/Enamine Aldol Cyclizations

(2012) David A. Evans et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Imine Acylation: Synthesis of the Proposed Structures of ‘Upenamide

(2012) William P. Unsworth et al.   ORGANIC LETTERS

Scandium-Catalyzed Preparation of Cytotoxic 3-Functionalized Quinolin-2-ones: Regioselective Ring Enlargement of Isatins or Imino Isatins

(2012) Benito Alcaide et al.   ChemPlusChem

ChiralN,N′-Dioxides: New Ligands and Organocatalysts for Catalytic Asymmetric Reactions

(2011) XiaoHua Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Trifluoroethyl-Substituted Ketones from Aldehydes and Cyclohexanones

(2011) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Semipinacol Rearrangement in Natural Product Synthesis

(2011) Zhen-Lei Song et al.   CHEMICAL REVIEWS

Isothiourea-Catalysed Asymmetric C-Acylation of Silyl Ketene Acetals

(2011) Philip A. Woods et al.   CHEMISTRY-A EUROPEAN JOURNAL

Exploring the Synthetic Versatility of the Lewis Acid Induced Decomposition Reaction of α-Diazo-β-hydroxy Esters. The Case of Ethyl Diazo(3-hydroxy-2-oxo-2,3-dihydro-1H-indol-3-yl)acetate

(2011) Antimo Gioiello et al.   JOURNAL OF ORGANIC CHEMISTRY

New Electrophilic Addition of α-Diazoesters with Ketones for Enantioselective C–N Bond Formation

(2011) Wei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Desymmetrizing Asymmetric Ring Expansion of Cyclohexanones with α-Diazoacetates Catalyzed by Chiral Aluminum Lewis Acid

(2011) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Acylation of Silyl Ketene Acetals through Fluoride Anion-Binding Catalysis

(2011) James A. Birrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Studies on transannulation reactions across a nine-membered ring: the synthesis of natural product-like structures

(2011) Mudassar Iqbal et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Toward the Synthesis of Norzoanthamine: Building Carbocyclic Core by a Transannular Michael Reaction Cascade

(2011) Haoran Xue et al.   ORGANIC LETTERS

An Enantioselective Synthesis of 2-Aryl Cycloalkanones by Sc-Catalyzed Carbon Insertion

(2011) Victor L. Rendina et al.   ORGANIC LETTERS

Desymmetrizing asymmetric ring expansion: stereoselective synthesis of 7-membered cyclic β-keto carbonyl compounds with an α-hydrogen

(2010) Takuya Hashimoto et al.   CHEMICAL COMMUNICATIONS

Synthesis of β-Keto Esters In-Flow and Rapid Access to Substituted Pyrimidines

(2010) Hannah E. Bartrum et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Roskamp Reaction of α-Alkyl-α-diazoesters with Aromatic Aldehydes: Highly Enantioselective Synthesis of α-Alkyl-β-keto Esters

(2010) Wei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expedient Enantioselective Synthesis of the Δ4-Oxocene Cores of (+)-Laurencin and (+)-Prelaureatin‡

(2010) Jim Li et al.   ORGANIC LETTERS

Catalytic and Regioselective Ring Expansion of Arylcyclobutanones with Trimethylsilyldiazomethane. Ligand-Dependent Entry to β-Ketosilane or Enolsilane Adducts

(2010) Jennifer A. Dabrowski et al.   ORGANIC LETTERS

Enantioselective synthesis of (2S,3′R,7′Z)-N-(3′-hydroxy-7′-tetradecenoyl)-homoserine lactone

(2010) Gullapalli Kumaraswamy et al.   TETRAHEDRON LETTERS

A Total Synthesis of Norhalichondrin B

(2009) Katrina L. Jackson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

(2009) Yan Zhang et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides

(2009) Fabio Bellina et al.   CHEMICAL REVIEWS

Catalytic Homologation of Cycloalkanones with Substituted Diazomethanes. Mild and Efficient Single-Step Access to α-Tertiary and α-Quaternary Carbonyl Compounds

(2009) David C. Moebius et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Construction of Seven-Membered Rings with an All-Carbon Quaternary Center by Direct Tiffeneau−Demjanov-type Ring Expansion

(2009) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of α-Alkyl-β-keto Imides via Asymmetric Redox C−C Bond Formation between α-Alkyl-α-diazocarbonyl Compounds and Aldehydes

(2009) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted Acid-Catalyzed Insertion of Aryldiazoacetates to sp2Carbon−CHO Bond:  Facile Construction of Chiral All-Carbon Quaternary Center

(2008) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent studies on the reactions of α-diazocarbonyl compounds

(2008) Zhenhua Zhang et al.   TETRAHEDRON

Dramatic Solvent Effect on the Diastereoselectivity of Michael Addition:  Study toward the Synthesis of the ABC Ring System of Hexacyclinic Acid

(2007) Julie Toueg et al.   ORGANIC LETTERS

A Formal Synthesis of the Callipeltoside Aglycone

(2007) James A. Marshall et al.   ORGANIC LETTERS