Catalytic Asymmetric [4+2] Annulation Initiated by an Aza-Rauhut-Currier Reaction: Facile Entry to Highly Functionalized Tetrahydropyridines

Enantioselective Synthesis of α-Alkylidene-γ-Butyrolactones: Intramolecular Rauhut-Currier Reaction Promoted by Acid/Base Organocatalysts

(2012) Shinobu Takizawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Intermolecular Rauhut-Currier Reaction of Electron-Deficient Allenes with Maleimides

(2011) Qian-Yi Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Versatile Enantioselective [3+2] Cyclization between Imines and Allenoates Catalyzed by Dipeptide-Based Phosphines

(2011) Xiaoyu Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective [3+2] Annulation of Morita-Baylis-Hillman Adducts Mediated by L-Threonine-Derived Phosphines: Synthesis of 3-Spirocyclopentene-2-oxindoles having Two Contiguous Quaternary Centers

(2011) Fangrui Zhong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Amine-Catalyzed [4+2] Annulations of Allenoates and Oxo-dienes: An Asymmetric Synthesis of Dihydropyrans

(2011) Xiaojun Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Intramolecular Crossed Rauhut-Currier Reactions through Cooperative Nucleophilic Activation and Hydrogen-Bonding Catalysis: Scope and Mechanistic Insight

(2011) Xu-Fan Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective One-Pot Synthesis of α-Amino Esters by a Phosphine-Catalyzed [3+2]-Cycloaddition Reaction

(2011) Marianne Steurer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Substrate-Controlled, Phosphine-Catalyzed Domino Reactions of Activated Conjugated Dienes: Highly Diastereoselective Synthesis of Bicyclic Skeletons

(2011) Jianze Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bifunctional N-Acyl-Aminophosphine-Catalyzed Asymmetric [4+2] Cycloadditions of Allenoates and Imines

(2011) Hua Xiao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Core-Structure-Motivated Design of a Phosphine-Catalyzed [3 + 2] Cycloaddition Reaction: Enantioselective Syntheses of Spirocyclopenteneoxindoles

(2011) Bin Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of a New Chiral Phosphepine to the Catalytic Asymmetric Synthesis of Highly Functionalized Cyclopentenes That Bear an Array of Heteroatom-Substituted Quaternary Stereocenters

(2011) Yuji Fujiwara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective [3 + 2] Cycloaddition of Allenes to Acrylates Catalyzed by Dipeptide-Derived Phosphines: Facile Creation of Functionalized Cyclopentenes Containing Quaternary Stereogenic Centers

(2011) Xiaoyu Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enzyme-catalysed [4+2] cycloaddition is a key step in the biosynthesis of spinosyn A

(2011) Hak Joong Kim et al.   NATURE

Organocatalytic Sequential Hetero-Diels–Alder and Friedel–Crafts Reaction: Constructions of Fused Heterocycles with Scaffold Diversity

(2011) Si-Li Zhou et al.   ORGANIC LETTERS

Tandem cross-Rauhut–Currier/cyclization reactions of activated alkenes to give densely functionalized 3,4-dihydropyrans

(2011) Wen Liu et al.   TETRAHEDRON

Quasi-biomimetic ring contraction promoted by a cysteine-based nucleophile: Total synthesis of Sch-642305, some analogs and their putative anti-HIV activities

(2011) Alpay Dermenci et al.   Chemical Science

Phosphine-catalyzed one-pot isomerization of 3-alkynoates and [2 + 3]-cycloaddition with imines: formal synthesis of Securinega alkaloid (±)-allosecurinine

(2011) Magesh Sampath et al.   Chemical Science

Asymmetric [3+2] Cycloadditions of Allenoates and Dual Activated Olefins Catalyzed by Simple Bifunctional N-Acyl Aminophosphines

(2010) Hua Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Isoindolines: An Organocatalyzed Domino Process Based On the aza-Morita-Baylis-Hillman Reaction

(2010) Shinobu Takizawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aminocatalytic asymmetric inverse-electron-demand aza-Diels–Alder reaction of N-Ts-1-aza-1,3-butadienes based on coumarin cores

(2010) Jun-Long Li et al.   CHEMICAL COMMUNICATIONS

Enantioselective [4+2] cycloaddition of ketenes and 1-azadienes catalyzed by N-heterocyclic carbenes

(2010) Teng-Yue Jian et al.   CHEMICAL COMMUNICATIONS

Enantioselective intramolecular Rauhut–Currier reaction catalyzed by chiral phosphinothiourea

(2010) Jing-Jing Gong et al.   CHEMICAL COMMUNICATIONS

Development of a Cysteine-Catalyzed Enantioselective Rauhut−Currier Reaction

(2010) Carrie E. Aroyan et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Aza-Morita−Baylis−Hillman Reaction of Methyl Acrylate: Role of a Bifunctional La(O-iPr)3/Linked-BINOL Complex

(2010) Takafumi Yukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rauhut–Currier type homo- and heterocouplings involving nitroalkenes and nitrodienes

(2010) Pramod Shanbhag et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Asymmetric Formal [4 + 1] Annulation Leading to Optically Activecis-IsoxazolineN-Oxides

(2010) Zugui Shi et al.   ORGANIC LETTERS

The enantioselective intramolecular Morita–Baylis–Hillman reaction catalyzed by amino acid-derived phosphinothiourea

(2010) Jing-Jing Gong et al.   TETRAHEDRON

Enantioselective synthesis of bicarbocyclic structures with an all-carbon quaternary stereocenter through sequential cross metathesis and intramolecular Rauhut–Currier reaction

(2010) Yuan Qiao et al.   TETRAHEDRON LETTERS

An enantioselective organocatalyzed aza-MBH domino process: application to the facile synthesis of tetrahydropyridines

(2010) Shinobu Takizawa et al.   TETRAHEDRON LETTERS

ortho-Acidic aromatic thiols as efficient catalysts of intramolecular Morita–Baylis–Hillman and Rauhut–Currier reactions

(2010) Philipp S. Selig et al.   TETRAHEDRON LETTERS

Highly enantio-, regio- and diastereo-selective one-pot [2 + 3]-cycloaddition reaction via isomerization of 3-butynoates to allenoates,

(2010) Magesh Sampath et al.   Chemical Science

Organocatalytic Asymmetric Synthesis of Protected α,β-Diamino Acids

(2009) Zugui Shi et al.   ADVANCED SYNTHESIS & CATALYSIS

Tertiary Amine Mediated Tandem Cross-Rauhut-Currier/Acetalization Reactions: Access to Functionalized Spiro-3,4-Dihydropyrans

(2009) Weijun Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Regio- and Stereoselective Inverse-Electron-Demand Aza-Diels-Alder Reaction of α,β-Unsaturated Aldehydes andN-Tosyl-1-aza-1,3-butadienes

(2009) Bo Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Phosphine-Catalyzed Synthesis of Highly Functionalized Diquinanes

(2009) Jonathan E. Wilson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Intermolecular Crossed-Conjugate Additions between Nitroalkenes and α,β-Enals through a Dual Activation Strategy

(2009) Cheng Zhong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PPh3-catalyzed [2 + 2 + 2] and [4 + 2] annulations: synthesis of highly substituted 1,2-dihydropyridines (DHPs)

(2009) Huimin Liu et al.   CHEMICAL COMMUNICATIONS

Enantioselective catalysis and complexity generation from allenoates

(2009) Bryan J. Cowen et al.   CHEMICAL SOCIETY REVIEWS

Crossed Intramolecular Rauhut−Currier-Type Reactions via Dienamine Activation

(2009) Eugenia Marqués-López et al.   ORGANIC LETTERS

Rational Design of Organocatalyst: Highly Stereoselective Michael Addition of Cyclic Ketones to Nitroolefins

(2009) Bin Tan et al.   ORGANIC LETTERS

Enantioselective Phosphine Organocatalysis

(2009) Angela Marinetti et al.   SYNLETT

The Rauhut–Currier reaction: a history and its synthetic application

(2009) Carrie E. Aroyan et al.   TETRAHEDRON

Catalysis of Intramolecular Morita-Baylis-Hillman and Rauhut-Currier Reactions by Fluorous Phosphines; Facile Recovery by Liquid/Solid Organic/Fluorous Biphase Protocols Involving Precipitation, Teflon®Tape, and Gore-Rastex®Fiber

(2008) Florian O. Seidel et al.   ADVANCED SYNTHESIS & CATALYSIS

Organocatalytic Asymmetric Inverse-Electron-Demand Aza-Diels-Alder Reaction ofN-Sulfonyl-1-aza-1,3-butadienes and Aldehydes

(2008) Bo Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine-triggered synthesis of functionalized cyclic compounds

(2008) Long-Wu Ye et al.   CHEMICAL SOCIETY REVIEWS

Mechanism, Regioselectivity, and the Kinetics of Phosphine-Catalyzed [3+2] Cycloaddition Reactions of Allenoates and Electron-Deficient Alkenes

(2008) Yong Liang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Aza Morita−Baylis−Hillman Reaction Catalyzed by Bifunctional β-Isocupreidine Derivatives

(2008) Nacim Abermil et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

2-Phospha[3]ferrocenophanes with Planar Chirality: Synthesis and Use in Enantioselective Organocatalytic [3 + 2] Cyclizations

(2008) Arnaud Voituriez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative, Highly Enantioselective Phosphinothiourea Catalysis of Imine−Allene [3 + 2] Cycloadditions

(2008) Yuan-Qing Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid-Catalyzed Conjugate Additions of Silyloxyallenes: A Selective Solution to the Intermolecular Rauhut−Currier Problem

(2008) Troy E. Reynolds et al.   ORGANIC LETTERS

A novel and facile stereocontrolled synthetic method for polyhydro-quinolines and pyridopyridazines via a diene-transmissive Diels–Alder reaction involving inverse electron-demand hetero Diels–Alder cycloaddition of cross-conjugated azatrienes

(2008) Satoru Kobayashi et al.   TETRAHEDRON