CF Bond Activation of Unactivated Aliphatic Fluorides: Synthesis of Fluoromethyl-3,5-diaryl-2-oxazolidinones by Desymmetrization of 2-Aryl-1,3-difluoropropan-2-ols

Umpolung of Fluoroform by CF Bond Activation: Direct Difluoromethylation of Lithium Enolates

(2012) Toshiaki Iida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Synthesis of Trifluoromethyl-substituted Diarylpyrrolines: Enantioselective Conjugate Cyanation of β-Aryl-β-trifluoromethyl-disubstituted Enones

(2012) Hiroyuki Kawai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Substitution and Cross-Coupling of Benzylic Fluorides

(2012) George Blessley et al.   ORGANIC LETTERS

Platinum-Catalyzed Substitution of Allylic Fluorides

(2012) Elena Benedetto et al.   ORGANOMETALLICS

Trifluoromethylation of Aromatic Isoxazoles: Regio- and Diastereoselective Route to 5-Trifluoromethyl-2-isoxazolines

(2011) Hiroyuki Kawai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Generation of Radiofluorinated Pyrimidine-2,4,6-triones as MMP-Targeted Radiotracers for Positron Emission Tomography

(2011) Daniela Schrigten et al.   JOURNAL OF MEDICINAL CHEMISTRY

Activation of Alkyl C–F Bonds by B(C6F5)3: Stoichiometric and Catalytic Transformations

(2011) Christopher B. Caputo et al.   ORGANOMETALLICS

Net Oxidative Addition of C(sp3)-F Bonds to Iridium via Initial C-H Bond Activation

(2011) J. Choi et al.   SCIENCE

Enantioselective Synthesis of Trifluoromethyl-Substituted 2-Isoxazolines: Asymmetric Hydroxylamine/Enone Cascade Reaction

(2010) Kazutaka Matoba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of CF Bonds in Preference to CI Bonds: Difluoromethylation of Lithium Enolates with Trifluoromethyl Iodide

(2010) Koichi Mikami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Titanium-Catalyzed C-F Activation of Fluoroalkenes

(2010) Moritz F. Kühnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A catalytic CC bond-forming reaction between aliphatic fluorohydrocarbons and arylsilanes

(2010) Nicole Lühmann et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Selective α-defluorination of polyfluorinated esters and amides using SmI2/Et3N/H2O

(2010) Jenny Wettergren et al.   CHEMICAL COMMUNICATIONS

Trihaloacetaldehyde N,O-acetals: useful building blocks for dihalomethylene compounds

(2010) Hikaru Yanai et al.   TETRAHEDRON

Catalytic CF Activation and Hydrodefluorination of Fluoroalkyl Groups

(2009) Gregor Meier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Substitution of Allylic Fluorides

(2009) Amaruka Hazari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of Allylic CF bonds: Palladium-Catalyzed Allylic Amination of 3,3-Difluoropropenes

(2009) Xavier Pigeon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

A Cascade Approach to Captodative Trifluoromethylated Enamines or Vinylogous Guanidinium Salts: Aromatic Substituents as Switches of Reaction Direction

(2009) Alexander Yu. Rulev et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Fluorinated isatin derivatives. Part 3. New side-chain fluoro-functionalized pyrrolidinyl sulfonyl isatins as potent caspase-3 and -7 inhibitors

(2009) Anil Kumar Podichetty et al.   Future Medicinal Chemistry

Fluorinated Isatin Derivatives. Part 2. NewN-Substituted 5-Pyrrolidinylsulfonyl Isatins as Potential Tools for Molecular Imaging of Caspases in Apoptosis

(2009) Anil K. Podichetty et al.   JOURNAL OF MEDICINAL CHEMISTRY

C−F Bond Cleavage by Intramolecular SN2 Reaction of Alkyl Fluorides with O- and N-Nucleophiles

(2009) Laijun Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Carbon−Carbon Coupling of C(sp3)−F Bonds Using Alumenium Catalysis

(2009) Weixing Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−F Bond-Cleavage Reactions of Fluoroalkanes with Magnesium Reagents and without Metal Catalysts

(2009) Kouki Matsubara et al.   ORGANIC LETTERS

Csp3–F bond activation by nucleophilic attack of the {Pt2S2} core assisted by non-covalent interactions

(2008) Ainara Nova et al.   CHEMICAL COMMUNICATIONS

Novel defluorinative alkylation of trifluoroacetaldehyde N,O-acetal derivatives and its application to multi-component reaction

(2008) Hikaru Yanai et al.   CHEMICAL COMMUNICATIONS

Use of Fluoroalkyl as a Latent Group for Internal Alkylation: Application to the Synthesis of Bridged Tetrahydrofluorenones

(2008) Dann L. Parker et al.   ORGANIC LETTERS

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS