Asymmetric Hydrogenation of 2,4-Disubstituted 1,5-Benzodiazepines Using Cationic Ruthenium Diamine Catalysts: An Unusual Achiral Counteranion Induced Reversal of Enantioselectivity

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of β-ketoesters: An Unusual Counterion Effect

(2011) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Brønsted Acid Catalysis: Hydrogen Bonding versus Ion Pairing in Imine Activation

(2011) Matthias Fleischmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Michael Addition of Pyrazolin-5-ones Catalyzed by Chiral Metal/N,N′-Dioxide Complexes: Metal-Directed Switch in Enantioselectivity

(2011) Zhen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalysis: Enantioselective Formal [2+2] Cycloaddition of Ketenes and N-Sulfinylanilines

(2011) Teng-Yue Jian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Sulfoxide-Olefin Ligands: Completely Switchable Stereoselectivity in Rhodium-Catalyzed Asymmetric Conjugate Additions

(2011) Guihua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective hydrovinylation via asymmetric counteranion-directed ruthenium catalysis

(2011) Gaoxi Jiang et al.   CHEMICAL COMMUNICATIONS

Asymmetric Hydrogenation of N-Alkyl Ketimines with Phosphine-Free, Chiral, Cationic Ru-MsDPEN Catalysts

(2011) Fei Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of 2-Substituted-1,5-Benzodiazepines through Domino Reaction of o-Phenylenediamine and Chalcone Derivatives

(2011) Xuan Fu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of 4-Substituted 4,5-Dihydro-1H-[1,5]benzodiazepin-2(3H)-ones by the Lewis Base-Catalyzed Hydrosilylation

(2011) Xing Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective Hydrogenation of Quinolines Using Phosphine-Free Chiral Cationic Ruthenium Catalysts: Scope, Mechanism, and Origin of Enantioselectivity

(2011) Tianli Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Hydrogenation of 2- and 2,3-Substituted Quinoxalines with Chiral Cationic Ruthenium Diamine Catalysts

(2011) Jie Qin et al.   ORGANIC LETTERS

Highly Effective Asymmetric Hydrogenation of CyclicN-Alkyl Imines with Chiral Cationic Ru-MsDPEN Catalysts‡

(2011) Fei Chen et al.   ORGANIC LETTERS

First Highly Enantioselective Synthesis of Benzodiazepinones by Catalytic Hydrogenation

(2010) Magnus Rueping et al.   ADVANCED SYNTHESIS & CATALYSIS

Reversal of Enantioselectivity by Tuning the Conformational Flexibility of Phase-Transfer Catalysts

(2010) Ming-Qing Hua et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Orthogonal Enantioselectivity Approaches Using Homogeneous and Heterogeneous Catalyst Systems: Friedel-Crafts Alkylation of Indole

(2010) Hun Young Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Iron-Catalyzed Hydrosilane Reduction of Ketones: Effect of Zinc Metal upon the Absolute Configuration

(2010) Tomohiko Inagaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unifying Metal and Brønsted Acid Catalysis-Concepts, Mechanisms, and Classifications

(2010) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Hydrogenation of Cyclic N-Sulfonylimines with Phosphine-Free Chiral Cationic Ru-MsDPEN Catalysts

(2010) Fei Chen et al.   CHINESE JOURNAL OF CHEMISTRY

Phosphine-free chiral metal catalysts for highly effective asymmetric catalytic hydrogenation

(2010) Yan-Mei He et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Cooperative Catalysis of Strong Bronsted Acid-Promoted Reactions Using Chiral Ureas

(2010) H. Xu et al.   SCIENCE

Axial Chirality Control of Gold(biphep) Complexes by Chiral Anions: Application to Asymmetric Catalysis

(2009) Kohsuke Aikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversal of Enantioselectivity between the Copper(I)- and Silver(I)-Catalyzed 1,3-Dipolar Cycloaddition Reactions Using a Brucine-Derived Amino Alcohol Ligand

(2009) Hun Young Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dynamic kinetic asymmetric transfer hydrogenation of racemic 2,4-diaryl-2,3-dihydrobenzo[b][1,4]diazepines catalyzed by chiral phosphoric acids

(2009) Zhi-Yong Han et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Asymmetric Induction by Chiral Borate Anions in Enantioselective Hydrogenation using a Racemic RhBinap Catalyst

(2009) Dianjun Chen et al.   ChemCatChem

A new approach to switching of enantioselectivity in NHC–Cu-catalyzed conjugate addition of alkylzincs to cyclic enones

(2009) Masaki Okamoto et al.   CHEMICAL COMMUNICATIONS

Chiral anion-mediated asymmetric ion pairing chemistry

(2009) Jérôme Lacour et al.   CHEMICAL COMMUNICATIONS

Unexpected Inversions in Asymmetric Reactions: Reactions with Chiral Metal Complexes, Chiral Organocatalysts, and Heterogeneous Chiral Catalysts

(2009) Mihály Bartók   CHEMICAL REVIEWS

Highly enantioselective hydrogenation of quinolines under solvent-free or highly concentrated conditions

(2009) Zhi-Jian Wang et al.   GREEN CHEMISTRY

Structure-Based Design of a Benzodiazepine Scaffold Yields a Potent Allosteric Inhibitor of Hepatitis C NS5B RNA Polymerase

(2009) Koen Vandyck et al.   JOURNAL OF MEDICINAL CHEMISTRY

Metal−Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

(2009) Chaoqun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Invertible Enantioselectivity in 6′-Deoxy-6′-acylamino-β-isocupreidine-Catalyzed Asymmetric Aza-Morita−Baylis−Hillman Reaction: Key Role of Achiral Additive

(2009) Nacim Abermil et al.   ORGANIC LETTERS

Remarkable Positive Effect of Silver Salts on Asymmetric Hydrogenation of Acyclic Imines with Cp*Ir Complexes Bearing Chiral N-Sulfonylated Diamine Ligands

(2009) Shin-yo Shirai et al.   ORGANOMETALLICS

Hydrogenation of Quinolines Using a Recyclable Phosphine-Free Chiral Cationic Ruthenium Catalyst: Enhancement of Catalyst Stability and Selectivity in an Ionic Liquid

(2008) Haifeng Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,5-Benzodiazepines, a Novel Class of Hepatitis C Virus Polymerase Nonnucleoside Inhibitors

(2008) O. Nyanguile et al.   ANTIMICROBIAL AGENTS AND CHEMOTHERAPY

Phosphine-Free Cp*Ru(Diamine) Catalysts in the Hydrogenation of Imines

(2008) Pradeep Cheruku et al.   Chemistry-An Asian Journal

Chiral Counteranion-Aided Asymmetric Hydrogenation of Acyclic Imines

(2008) Chaoqun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative Catalysis with Chiral Brønsted Acid-Rh2(OAc)4: Highly Enantioselective Three-Component Reactions of Diazo Compounds with Alcohols and Imines

(2008) Wenhao Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Dramatic Switch of Enantioselectivity in Asymmetric Heck Reaction by Benzylic Substituents of Ligands

(2008) Wen-Qiong Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Hydrogenation of Cyclic Imines with an Ionic Cp*Rh(III) Catalyst

(2008) Chaoqun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Air-Stable and Phosphine-Free Iridium Catalysts for Highly Enantioselective Hydrogenation of Quinoline Derivatives†

(2008) Zhi-Wei Li et al.   ORGANIC LETTERS