Article
Materials Science, Multidisciplinary
Laura I. Holz, Vanessa C. D. Graca, Francisco J. A. Loureiro, Sergey M. Mikhalev, Diogo Mendes, Adelio Mendes, Duncan P. Fagg
Summary: Transition metal (oxy)nitrides are attractive materials with notable catalytic and electronic properties. This study investigates the effect of ammonolysis temperature on the composition and physical properties of vanadium (oxy)nitrides. It shows that by controlling the ammonolysis temperature, the composition of the anionic sublattice can be adjusted, which in turn impacts the resultant properties of the materials for potential applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Materials Science, Multidisciplinary
Yuta Ito, Isao Tsuyumoto
Summary: Nanocrystalline lithium niobate, LiNbO3, is prepared through an aqueous solution process, starting from peroxo - polyniobic acid solution. The crystalline LiNbO3 has the same structure as conventional LiNbO3 with a small crystallite size. The nanocrystalline LiNbO3 prepared at 500 degrees Celsius exhibits a high ionic conductivity.
MATERIALS CHEMISTRY AND PHYSICS
(2021)
Article
Materials Science, Multidisciplinary
Kathrin Kulmus, Sibylle Gemming, Michael Schreiber, Dimitar Pashov, Swagata Acharya
Summary: The study demonstrates that NbO2 is essentially a Peierls-type material through advanced electronic structure calculations, successfully replicating experimental values for electronic properties by simulating different phases with the Bethe-Salpeter equation. The anisotropic nature of the rutile structure and nesting vectors in the Fermi surfaces in certain planes were also observed.
Article
Chemistry, Inorganic & Nuclear
Jean-Louis Hodeau, Massimo Marezio
Summary: This reinvestigation study reveals the structural connection between the twinning process in the CeNbO4 phase and the commensurate and incommensurate modulations in the CeNbO4+x phases resulting from their oxidation. Anionic insertion occurs by the formation of oxygen clusters propagating through the structure via a slight distortion of the cationic sub-structure and rotation of the coordinating oxygen edges of some niobium sites. These distortions and rotations are common features of the twinned CeNbO4 and CeNbO4+x phases. The inserted oxygens' location is related to a local distortion of the cationic sub-structure, similar to that observed in nano-twinned areas, explaining the relationship between the directions of the incommensurate vectors of CeNbO4.08 and the twinning walls. The CeNbO4.08 and CeNbO4.25 phases are discrete and the continuity of the oxidation/reduction process comes from the mixing of these two phases, which share a connection with the distortions induced by the twinning process guiding the distribution of distorted areas.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Chemistry, Physical
Luca Spiridigliozzi, Mauro Bortolotti, Gianfranco Dell'Agli
Summary: Fluorite-structured Entropy-Stabilized Oxides (F-ESO) can be obtained using a multicomponent equimolar system based on cerium, zirconium, and other rare earth elements. The phase transition from multiple phases to a single-phase fluorite structure was confirmed through calcination at 1500 degrees C for 1 hour. High temperature X-ray diffraction analysis revealed an inverse correlation between the standard deviation and the entropy-driven transition temperature, indicating that higher standard deviation leads to lower transition temperature. These findings support the empirical predictor developed by the authors and suggest that high standard deviation contributes to the overall entropy of the system.
Article
Materials Science, Multidisciplinary
Michael K. Eusterholz, Torben Boll, Julian Gebauer, Anja Weidner, Alexander Kauffmann, Peter Franke, Hans Juergen Seifert, Horst Biermann, Christos G. Aneziris, Martin Heilmaier
Summary: Coarse-grained composites of refractory ceramics and refractory metals are a promising option for high-temperature applications, as they can enhance thermal shock capability. During fabrication, it is important to consider possible phase interactions and reactions with the environment. X-Ray diffraction and scanning electron microscopy reveal the formation of NbO in Al2O3-Nb composite while aluminum tantalate (AlTaO4) is found in Al2O3-Ta. Thermodynamic calculations explain the oxygen solubility changes and the absence of a corresponding niobate phase (AlNbO4). AlTaO4 is identified as the disordered tetragonal high-temperature modification.
ADVANCED ENGINEERING MATERIALS
(2022)
Article
Materials Science, Ceramics
Hari Singh, Saurabh Kumar Sharma, P. K. Kulriya
Summary: The cubic phasic CeO2-ZrO2 system with Ce0.8Zr0.2O2 composition was synthesized at room temperature. Highly dense pellets were obtained and analyzed using X-ray diffraction and electron microscopy. The structural damage caused by irradiation with 100 MeV I7+ ions was investigated through diffraction patterns. The results revealed the damaged regions and provided insights into the structural properties of the CeO2-ZrO2 system.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Yubin Wen, Yufu Liu
Summary: High-entropy fluorite oxides (HEFOs) are promising thermal barrier coatings (TBCs) with improved performance. The thermal expansion coefficient (TEC) plays a crucial role in the direct contact between TBCs and metal substrates. This study investigates the evolutionary behavior of lattice and thermal expansion of a specific HEFO (Zr0.2Ce0.2Hf0.2Y0.2Al0.2)O2-8 during heating and cooling in an inert atmosphere.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Chenkai Qu, Lin Chen, Liang Lv, Yuncheng Wang, Xiaolan Ji, Haitao Yun, Chaoqun Su, Jing Feng
Summary: In this study, (Gd1-xYx)TaO4 ceramics were synthesized by solid-phase synthesis reaction and their properties were optimized by adjusting the ratio of Gd/Y. The ceramics exhibited low high-temperature thermal conductivity and high phase transition temperature, with thermal expansion coefficients comparable to yttria-stabilized zirconia. Controlling preferred orientation can minimize the thermal expansion mismatch when (Gd1-xYx)TaO4 coatings are used as thermal barrier coatings on different substrates.
JOURNAL OF ADVANCED CERAMICS
(2022)
Article
Materials Science, Multidisciplinary
Shengkai Wang, Bangzhi Ge, Jiabin Hu, Wenqi Xie, Yi Liu, Shunjian Xu, Zhongqi Shi
Summary: Highly textured TiN ceramic was successfully prepared using the edge-free spark plasma sintering method, and the phase and crystalline evolutions from anisotropic Ti2AlN to textured bulk TiN were revealed. The obtained TiN ceramic exhibited anisotropic mechanical and physical properties due to its highly textured microstructure.
MATERIALS SCIENCE AND TECHNOLOGY
(2022)
Article
Crystallography
Yongzhao Yao, Koji Sato, Yoshihiro Sugawara, Narihito Okada, Kazuyuki Tadatomo, Kohei Sasaki, Akito Kuramata, Yukari Ishikawa
Summary: This paper introduces a method for visualizing crystal plane curving in wide bandgap semiconductor wafers using a laboratory X-ray diffractometer, providing characteristic CCP for different commercial substrates. The results aid crystal growers in understanding the shape and radius of curvature of crystal planes, allowing for optimization of crystal growth conditions and wafer planarization processes.
JOURNAL OF CRYSTAL GROWTH
(2022)
Article
Materials Science, Multidisciplinary
K. Piskorski, M. Wzorek, M. Ekielski, L. Dobrzanrski, J. Gaca, A. Malinowska, P. Michalowski, M. A. Borysiewicz
Summary: In this study, thin Pd2Si layers were fabricated using magnetron sputtering deposition, and their properties were extensively studied using spectroscopic ellipsometry and various microscopy techniques, providing essential information about the optical parameters, microstructure, and electron energy levels of the layer.
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Gabriel Spartacus, Joel Malaplate, Denis Menut, Caroline Toffolon-Masclet, Denis Sornin, Raphaelle Guillou, Amelie Gangloff, Stephane Urvoy, Frederic De Geuser, Alexis Deschamps
Summary: ODS steels are candidate materials for fission and fusion nuclear reactors. The study characterized the microstructure of ferritic and ferritic/martensitic ODS steels processed via Hot Extrusion and Hot Isostatic Pressing, revealing the presence of Ti-rich precipitates and intergranular carbides. The elongated shapes of Cr-carbides in Fe-14Cr HE specimens may negatively impact the mechanical behavior of the material.
Article
Chemistry, Inorganic & Nuclear
Madiha Batool, Shazia Khurshid, Zahid Qureshi, Ali Hassan, Muhammad Bilal Ahmed Siddique, Sabiha Naveed, Sabir Ali Siddique
Summary: The study analyzed the antimicrobial activity of nanoparticles synthesized by aloe barbadensis leaves extract on oral infectious pathogens. Zinc oxide nanoparticles showed the highest antimicrobial activity, suggesting potential use in oral infectious disease treatment in the future.
INORGANIC AND NANO-METAL CHEMISTRY
(2021)
Article
Mechanics
A. S. Sokolov, V. D. Borzosekov, E. V. Voronova, D. V. Malakhov, V. D. Stepakhin, E. A. Obraztsova, O. N. Shishilov
Summary: This study presents experimental information on obtaining oxide, nitride, and oxynitride materials with a given composition and a complex surface using high-power pulsed gyrotron discharges in mixtures of Al/AlN and Al/Si3N4 powders. The synthesis of nanosized and microparticles with a complex surface is demonstrated, and micrographs of the obtained particles and their morphological composition are presented. The obtained materials are considered as carriers for catalysts.