Journal
ANALYTICA CHIMICA ACTA
Volume 1047, Issue -, Pages 28-35Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2018.09.042
Keywords
Palladium nanoparticles; Polyoxometalates; Nitrogen-doping hollow carbon spheres; Electroanalytical; Acetaminophen
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Funding
- National Natural Science Foundation of China [21505031]
- Natural Science Foundation of Hebei Province [B2016201018, B2018201214]
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The preparation of palladium nanoparticles (Pd NPs) attached on nitrogen-doping hollow carbon spheres (NHCSs) surface using polyoxometalates (POMs) as both the reductant and bridging molecules by a green strategy was described in this paper. The samples have been thoroughly comprehensive characterized using scanning electron microscopy, transmission electron microscopy, powder X-ray diffraction, energy-dispersive X-ray spectra, and X-ray photoelectron spectroscopy. The as-prepared Pd/POMs/NHCSs tri-component nanohybrids provide enhanced electro-catalytic activities for oxidation of acetaminophen (AP) with the catalytic rate constant (kcat) of 2.34 x 10(3) M-1 s(-1) and diffusion coefficient (D) of 6.18 x 10(-5) cm(2) s(-1), because of the synergetic effects of Pd NPs and NHCSs. We assessed the use of Pd/POMs/NHCSs as an effective sensing template for electrochemical detection of AP, which showed high analytical performance, such as a linear range of 0.02 mu M-0.63 mu M with a sensitivity of 508.46 mu AmM-1; a linear range of 0.63 mu M to 0.083 mM with a sensitivity of 154.27 mu AmM-1, and a low limit of detection of 3 nM. This strategy provides a new direction opportunity to promote the electrochemical performance of AP. (c) 2018 Elsevier B.V. All rights reserved.
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