4.7 Article

Fingerprint detection and using intercalated CdSe nanoparticles on non-porous surfaces

Journal

ANALYTICA CHIMICA ACTA
Volume 812, Issue -, Pages 228-235

Publisher

ELSEVIER
DOI: 10.1016/j.aca.2014.01.015

Keywords

Fingerprints; Fluorescent nanoparticles; Log-normal model; Nonlinear fitting; Quantum dots

Funding

  1. Ciencia 2007 program (FCT-Portugal)
  2. FCT [E-15/11]
  3. MCINN [AIB201OPT-00299]
  4. Ministry of Education, Science and Technology of the Republic of Serbia [173017]
  5. Spanish Ministry of Economy and Competitivity [CTQ2012-37925-C03-03]
  6. University of Malaga

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A fluorescent nanocomposite based on the inclusion of CdSe quantum dots in porous phosphate heterostructures, functionalized with amino groups (PPH-NH2@CdSe), was synthesized, characterized and used for fingerprint detection. The main scopes of this work were first to develop a friendly chemical powder for detecting latent fingerprints, especially in non-porous surfaces; their further intercalation in PPH structure enables not to spread the fluorescent nanoparticles, for that reason very good fluorescent images can be obtained. The fingerprints, obtained on different non-porous surfaces such as iron tweezers, mobile telephone screen and magnetic band of a credit card, treated with this powder emit a pale orange luminescence under ultraviolet excitation. A further image processing consists of contrast enhancement that allows obtaining positive matches according to the information supplied from a police database, and showed to be more effective than that obtained with the non-processed images. Experimental results illustrate the effectiveness of proposed methods. (C) 2014 Elsevier B.V. All rights reserved.

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