4.7 Article

Lanthanides determination in red wine using ultrasound assisted extraction, flow injection, aerosol desolvation and ICP-MS

Journal

ANALYTICA CHIMICA ACTA
Volume 710, Issue -, Pages 33-39

Publisher

ELSEVIER
DOI: 10.1016/j.aca.2011.10.039

Keywords

Red wine; Flow injection; Sonication; Lanthanides; ICP-MS; Aerosol desolvation

Funding

  1. CNPq
  2. CAPES

Ask authors/readers for more resources

This paper deals with the determination of the fourteen naturally occurring elements of the lanthanide series in red wine. Ultrasound (US) was used for sample preparation prior lanthanides determination using ICP-MS. Flow injection (FI) and pneumatic nebulization/aerosol desolvation were used for nebulization of aliquots of 50 mu L of sample and its subsequent transportation to plasma. Sample preparation procedures, matrix interference and time of sonication were evaluated. Better results for lanthanides in red wine were obtained by sonication with US probe for 90s and sample 10-fold diluted. The limits of detection of La, Ce, Nd, Sm, Gd, Pr, Eu, Tb, Dy, Ho, Er, Tm, Lu and Yb were 6.57, 10.8, 9.97, 9.38, 2.71, 1.29, 1.22, 0.52, 2.35, 0.96, 2.30, 0.45. 0.24 and 1.35 ng L-1, respectively. Red wines of different varieties from three countries of South America were discriminated according to the country of origin by means of multivariate analysis of lanthanides concentration. (C) 2011 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Analytical

Microwave-assisted extraction for further Cl, Br, and I determination in medicinal plants by ICP-MS: a study of carbon interferences

Mariele S. Nascimento, Gabriel T. Druzian, Leticia S. F. Pereira, Marcia F. Mesko, Rochele S. Picoloto, Paola A. Mello, Erico M. M. Flores

Summary: A microwave-assisted extraction method was developed for determining Cl, Br, and I in medicinal plants. The method showed accurate and reliable results compared to a reference method using ICP-MS. Care should be taken to control the carbon content to avoid interference.

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY (2022)

Article Food Science & Technology

Viability and stability evaluation of Lactobacillus casei LC03 co-encapsulated with red onion (Allium cepa L.) peel extract

Greice Carine Raddatz, Vitor Ramires Fonseca, Alexandre Jose Cichoski, Leila Queiroz Zepka, Eduardo Jacob-Lopes, Paulo Cezar Bastianello Campagnol, Roger Wagner, Edson Irineo Muller, Erico Marlon de Moraes Flores, Cristiane de Bona da Silva, Cristiano Ragagnin de Menezes

Summary: The study found that adding red onion peel extract can increase the survival rate of probiotics under simulated gastrointestinal conditions and thermal treatments, with the best effect seen in microparticles containing 20% extract. Under storage conditions at 25 degrees Celsius, the formulations with 5% and 20% extract performed better, and all microparticle formulations remained stable at -18 degrees Celsius for 90 days.

LWT-FOOD SCIENCE AND TECHNOLOGY (2022)

Article Green & Sustainable Science & Technology

Ultrasound-Assisted Demineralization Process of Sugarcane Straw and Its Influence on the Further Biomass Conversion

Daniel Santos, Karen Giacobe, Carolina M. Silva, Loisleini F. Saldanha, Ayrton F. Martins, Erico M. M. Flores, Cezar A. Bizzi

Summary: Lignocellulosic materials are a promising alternative source for producing liquid biofuel and fine chemicals with low environmental impact, but they can be contaminated with metals and nonmetals. This study successfully utilized ultrasound energy to remove impurities from sugarcane straw, increasing fermentable sugars' production and demonstrating high efficiency in demineralization. The scaling up experiments also showed the potential applicability of ultrasound-assisted procedure for large-scale demineralization.

SUSTAINABILITY (2022)

Article Green & Sustainable Science & Technology

Microwave-Assisted Solid Sampling Analysis Coupled to Flame Furnace Atomic Absorption Spectrometry for Cd and Pb Determination in Food-Contact Polymers

Alessandra Schneider Henn, Angelica Chaiani Frohlich, Matheus Felipe Pedrotti, Vitoria Hagemann Cauduro, Marcos Leandro Silva Oliveira, Erico Marlon de Moraes Flores, Cezar Augusto Bizzi

Summary: The study utilized microwave-assisted solid sampling analysis coupled to flame furnace atomic absorption spectrometry for Cd and Pb determination in food-contact polymer samples, aiming to minimize reagents and laboratory waste. The method showed accurate results with minimal waste generation, making it suitable for Cd and Pb determination in food-contact polymers.

SUSTAINABILITY (2022)

Article Chemistry, Analytical

Imaging of Elements Distribution in Rice by Laser Ablation Inductively Coupled Plasma Mass Spectrometry

Cristian Killing Pereira, Vinicius Machado Neves, Graciela Marini Hidrich, Henrique Faccin, Dirce Pozebon, Valderi Luiz Dressler

Summary: In this study, laser ablation inductively coupled plasma mass spectrometry (LAICP-MS) was used to determine and image the concentrations of various elements in white, parboiled, and brown rice. The distribution of these elements within the grains was evaluated, and it was found that they were not evenly distributed.

BRAZILIAN JOURNAL OF ANALYTICAL CHEMISTRY (2023)

Article Environmental Sciences

Detection of new phytochemical compounds from Vassobia breviflora (Sendtn.) Hunz: antioxidant, cytotoxic, and antibacterial activity of the hexane extract

Altevir Rossato Viana, Bruna Godoy Noro, Daniel Santos, Katianne Wolf, Yasmin Sudatti Das Neves, Rafael Noal Moresco, Aline Ferreira Ourique, Erico Marlon Moraes Flores, Cristiano Rodrigo Bohn Rhoden, Luciana Maria Fontanari Krause, Bruno Stefanello Vizzotto

Summary: This study investigated the phytochemical compositions and biological activities of Vassobia breviflora extract. The extract exhibited excellent antioxidant and antimicrobial activities, as well as cytotoxic effects against various tumor cells. Moreover, it also increased the production of reactive oxygen species.

JOURNAL OF TOXICOLOGY AND ENVIRONMENTAL HEALTH-PART A-CURRENT ISSUES (2023)

Article Chemistry, Analytical

A miniaturized liquid-liquid extraction method for further Na, K, Ca, and Mg determination in crude oil by FAAS

Felipe A. Silva, Beatriz R. Rigui, Cristian R. Andriolli, Erico M. M. Flores, Paola A. Mello, Rochele S. Picoloto

Summary: A miniaturized liquid-liquid extraction (LLE) method was proposed for pre-concentration of Na, K, Ca, and Mg in crude oil. The method showed no statistical difference compared to the reference values, with relative standard deviations lower than 6%. The proposed miniaturized LLE method presents several advantages, such as ease-of-use, high throughput, and low limits of quantification, making it an environmentally friendly and cost-effective alternative for routine analyses.

TALANTA (2023)

Article Chemistry, Analytical

Determination of Cl and S in crude oil by ICP-OES after sample digestion by microwave-induced combustion in disposable vessels

Jaime S. Mandlate, Alessandra S. Henn, Paola A. Mello, Erico M. M. Flores, Juliano S. Barin, Fabio A. Duarte

Summary: A simple and fast sample preparation method called microwave-induced combustion in disposable vessels (MIC-DV) was developed for Cl and S determination in crude oil using ICP-OES. The method allows efficient digestion of up to 10 mg of crude oil per cycle, reaching a total sample mass of 50 mg.

ANALYTICA CHIMICA ACTA (2023)

Article Environmental Sciences

Toxicity Assessment of Urban Dust from Barranquilla, a Colombian Caribbean City, using Caenorhabditis elegans

Jorge Osorio-Martinez, Luis F. F. Silva, Erico M. M. Flores, Gabriel T. T. Druzian, Jesus Olivero-Verbel

Summary: This study assessed the concentrations and toxicity of potentially toxic elements (PTEs) in urban dust from Barranquilla, Colombia. The results showed that the PTEs in the dust had negative effects on the physiological parameters of Caenorhabditis elegans, indicating that it can be used as a sensitive organism for warning systems related to biota risks associated with air pollution.

WATER AIR AND SOIL POLLUTION (2023)

Article Multidisciplinary Sciences

Thick layer drying and storage of rice grain cultivars in silo-dryer-aerator: Quality evaluation at low drying temperature

Rosana Santos de Moraes, Paulo Carteri Coradi, Marcela Trojahn Nunes, Marisa Menezes Leal, Edson Irineu Muller, Paulo Eduardo Teodoro, Erico Marlon Moraes Flores

Summary: Drying rice in a silo-dryer-aerator using single-layer loading at low temperatures resulted in uniform drying. This study evaluated the physical, physicochemical, and morphological quality of rice grain cultivars in the lower and upper layers of the silo-dryer-aerator. The results showed that drying rice in silo-dryer-aerator attenuated the moisture diffusivity in the grains and preserved the physicochemical constituents and morphology of starch, especially in the lower layers throughout the 2-month drying. The Guri INTA and BRS Pampeira cultivars exhibited the highest resistance to drying and had the most uniform final quality.

HELIYON (2023)

Article Chemistry, Analytical

Mercury determination in bioresorbable calcium phosphate using a new electrothermal vaporization system coupled to ICP-MS

Jussiane S. S. Silva, Graciela M. M. Heidrich, Bruno O. O. Poletto, Jose N. G. Paniz, Valderi L. L. Dressler, Erico M. M. Flores

Summary: A direct solid sampling method using ETV-ICP-MS was developed for determining mercury in bioresorbable calcium phosphate-based materials. The method involved fast sample heating with a halogen lamp, followed by vaporization and cooling steps. Mercury vaporized at a low temperature and did not co-vaporize the main matrix. External calibration using aqueous solutions was used for quantification. The method showed good accuracy, precision, and sample throughput, making it suitable for routine analyses.

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY (2023)

Article Chemistry, Analytical

On a single method for determining As and Hg in dietary supplements by CVG-MIP OES: optimization of the multimode sample introduction system

Gustavo Rossato Bitencourt, Fabio Andrei Duarte, Valderi Luiz Dressler, Rodrigo Cordeiro Bolzan, Erico Marlon de Moraes Flores, Paola Azevedo Mello

Summary: A single method using chemical vapor generation coupled with microwave-induced plasma optical emission spectrometry was developed for the determination of As and Hg in dietary supplements. The method complied with the maximum concentration requirements set by the United States Pharmacopeia and showed no statistical difference compared to comparative methods. The proposed method can be considered an alternative for the quality control of As and Hg in dietary supplements.

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY (2023)

Article Food Science & Technology

Ultrasonic _assisted extraction of phenolic compounds with evaluation of red onion skin (Allium cepa L.) antioxidant capacity

Vanessa Bordin Viera, Natieli Piovesan, Renius De Oliveira Mello, Juliano Smanioto Barin, Aline De Oliveira Fogaca, Cezar Augusto Bizzi, Erico Marlon De Moraes Flores, Ana Carolina Dos Santos Costa, Diego Elias Pereira, Juliana Kessia Barbosa Soares, Ernesto Hashime Kubota

Summary: This study determined the antioxidant activity of red onion peel extract using ultrasound extraction, and found that different ultrasound power and solvent concentration had varying effects on different antioxidant indicators.

JOURNAL OF CULINARY SCIENCE & TECHNOLOGY (2023)

Article Chemistry, Analytical

Ultra-trace Hg determination in crude oils by CV-ICP-MS: overcoming the limitations of sample preparation to determine sub-ppb levels

Gabriel T. Druzian, Mariele S. Nascimento, Rochele S. Picoloto, Marcia F. Mesko, Erico M. M. Flores, Paola A. Mello

Summary: A method for determining sub-ppb levels of mercury in crude oil using cold vapor generation inductively coupled plasma mass spectrometry (CV-ICP-MS) was developed by optimizing the operational parameters for crude oil digestion and evaluating the accuracy of the method. The optimized conditions allowed for the complete digestion of up to 1.2 g of crude oil and achieved a very low limit of detection.

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY (2022)

Article Agronomy

Extraction of antioxidant and antimicrobial phytochemicals from corn stigma: a promising alternative to valorization of agricultural residues

Caroline Pagnossim Boeira, Deborah Cristina Barcelos Flores, Bruna Nichelle Lucas, Daniel Santos, Erico Marlon Moraes Flores, Frederico Luiz Reis, Liziane Maria Barassuol Morandini, Ademir Farias Morel, Claudia Severo da Rosa

Summary: This study investigated the feasibility of ultrasound-assisted extraction of antioxidant compounds from corn stigma and optimized the extraction conditions. The results showed that ultrasound-assisted extraction increased the antioxidant activity and reduced the extraction time. The characterized extract exhibited promising antifungal and antibacterial activities.

CIENCIA RURAL (2022)

Article Chemistry, Analytical

Native top-down mass spectrometry for monitoring the rapid chymotrypsin catalyzed hydrolysis reaction

Yujia Ying, Huilin Li

Summary: Enzymes play a crucial role as biological catalysts in accelerating biochemical reactions in living organisms. This study proposes a convenient method for monitoring enzymatic catalytic processes using native top-down mass spectrometry. By exploring the heterogeneity of the chymotrypsin sample and using tandem mass spectrometry, the researchers were able to monitor covalent and noncovalent enzymatic complexes, substrates, and products during catalysis. The results demonstrate that this method has the potential to be a promising tool for characterizing biocatalysts.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

A dynamic Eu(III)-macrocycle served as the turn-on fluorescent probe for distinguishing H2O from D2O

Kang Yang, Shuaibo Shi, Jinyu Wu, Shaolong Han, Shengdi Tai, Shishen Zhang, Kun Zhang

Summary: H2O and D2O are important analogues closely related to various industries and monitoring fields. This study successfully distinguishes and detects H2O and D2O by designing a novel eu(III)-macrocycle with dual emitters, Eu-2a, and conducting fluorescence titration experiments.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

Cluster-Partial Least Squares (c-PLS) regression analysis: Application to miRNA and metabolomic data

Julia Kuligowski, Alvaro Perez-Rubio, Marta Moreno-Torres, Polina Soluyanova, Judith Perez-Rojas, Ivan Rienda, David Perez-Guaita, Eugenia Pareja, Ramon Trullenque-Juan, Jose Castell, Marcha Verheijen, Florian Caiment, Ramiro Jover, Guillermo Quintas

Summary: This study introduces a novel variable selection approach called cluster PLS (c-PLS) to assess the joint impact of variable groups selected based on biological characteristics on the predictive performance of a multivariate model. The usefulness of c-PLS is shown using miRNomic and metabolomic datasets obtained from the analysis of liver tissue biopsies.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

Carbon fiber-based multichannel solid-contact potentiometric ion sensors for real-time sweat electrolyte monitoring

Meixue Lai, Lijie Zhong, Siyi Liu, Yitian Tang, Tingting Han, Huali Deng, Yu Bao, Yingming Ma, Wei Wang, Li Niu, Shiyu Gan

Summary: This study presents a method for constructing wearable sweat electrolyte sensors using carbon fiber-based solid-contact ion-selective electrodes (SC-ISEs). By using carbon fibers extracted from commercial cloth as electrode material, the cost and reproducibility issues of flexible SC-ISEs were addressed. The results showed that the carbon fiber-based SC-ISEs exhibited reversible voltammetric and stable impedance performances, and had high reproducibility of standard potentials between normal and bending states.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

Imaging peroxynitrite in endoplasmic reticulum stress and acute lung injury with a near-infrared fluorescent probe

Ke Yang, Ying Liu, Min Deng, Peipei Wang, Dan Cheng, Songjiao Li, Longwei He

Summary: A near-infrared fluorescent probe has been developed to accurately measure the levels of peroxynitrite (ONOO-) in the endoplasmic reticulum (ER) in acute lung injury (ALI). The probe demonstrated rapid response, high selectivity, good sensitivity, and enhanced fluorescence intensity in response to ONOO-. It was successfully used to detect changes in ONOO- levels and showed significant increases in an ALI cell model and an ALI mouse model.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

Miniaturized ascorbic acid assay platform based on point discharge atomic emission spectrometry coupling with gold filament enrichment

Yanping Wang, Yuemei Chen, Kejun Li, Jinrong Zhou, Xin Yuan, Mei Zhang, Ke Huang

Summary: In this work, a portable analytical system based on point discharge chemical vapor generation atomic emission spectrometry (PD-CVG-AES) coupling with gold filament enrichment was designed. The highly sensitive analysis of Hg2+ indirectly realized the detection of ascorbic acid (AA). The measurement is based on the fact that Ag+ can decrease the concentration of Hg2+ by forming Ag-Hg amalgam in the presence of the reductant SnCl2, while AA can pre-reduce Ag+ to Ag0, leading to the generation of silver nanoparticles (Ag NPs). The developed novel analytical strategy broadens the application of microplasma-based AES and offers a higher level of sensitivity compared to current AA detection techniques.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

Time-gated luminescent probes for lysosomal singlet oxygen: Synthesis, characterizations and bioimaging applications

Yundi Huang, Bo Song, Kaiwen Chen, Deshu Kong, Jingli Yuan

Summary: This study developed two lysosome-targetable background-free TGL probes for efficient and accurate detection of 1O2, which can be used for monitoring endogenous 1O2 concentrations in lysosomes and discriminating variability induced by different photosensitizers. Furthermore, a smart luminescent sensor film was successfully prepared for on-site 1O2 production detection during PDT processes, offering a promising clinical monitoring tool for skin diseases.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

A novel polymer-based probe for fluorescently ratiometric sensing of hydrogen sulfide with multiple applications

Wei Lang, Jia-Mei Qin, Qian-Yong Cao

Summary: A novel polymer-based probe P1 was successfully synthesized for fluorescently ratiometric sensing of H2S with high selectivity and sensitivity. A smartphone sensing platform was constructed to conduct visual quantitative detection of H2S. P1 can be employed in evaluating the level fluctuations of H2S in living cells, testing water samples/wine samples, and monitoring food freshness.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

Split aptamer-based sandwich-type ratiometric biosensor for dual-modal photoelectrochemical and electrochemical detection of 17β-estradiol

Yuanyuan Qin, Shuda Liu, Shuyun Meng, Dong Liu, Tianyan You

Summary: The study developed a split aptamer-based sandwich-type ratiometric biosensor for the detection of 17 beta-estradiol (E2) using photoelectrochemical and electrochemical assays. The biosensor utilized split aptamer fragments to recognize E2 and trigger a hybridization chain reaction, resulting in the production of double-stranded DNA labeled with CdTe quantum dots. This DNA complex was able to sensitize CdTe quantum dots and generate response signals for E2 detection. The developed biosensor demonstrated high sensitivity and accuracy with two linear ranges and low detection limits.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

A highly sensitive hyperbranched Au plasmonic blackbody immunochromatographic assay for detection of leucomalachite green in fish and shrimp

Siriwan Teepoo, Jongjit Jantra, Khaunnapa Panapong, David Taiwo Ajayi

Summary: A novel immunochromatographic assay based on hyperbranched Au plasmonic blackbodies with a smartphone readout was developed for rapid and sensitive detection of leucomalachite green residues in fish and shrimp products.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

A plasmonic MNAzyme signal amplification strategy for quantification of miRNA-4739 breast cancer biomarker

Andrea L. Larraga-Urdaz, Borja Moreira-Alvarez, Jorge Ruiz Encinar, Jose M. Costa-Fernandez, Maria Luisa Fernandez-Sanchez

Summary: A major challenge in the 21st century is the development of point-of-care diagnostic tools. In this study, a highly sensitive and simple bioassay using AuNPs and MNAzymes was developed for rapid detection and quantification of miRNA-4739. The proposed strategy shows potential for breast cancer diagnosis.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

Magnetic solid phase extraction coupled to HPLC-UV for highly sensitive analysis of mono-hydroxy polycyclic aromatic hydrocarbons in urine

Xiaohan Zhao, Anyu Wang, Lingzi Zhai, Jiuhe Gao, Sizhe Lyu, Yingshan Jiang, Tian Zhong, Ying Xiao, Xi Yu

Summary: A novel method using polystyrene-coated magnetic nanoparticles for extracting monohydroxy polycyclic aromatic hydrocarbons from urine samples was investigated. The proposed method is simple, sensitive, and efficient, with desirable sensitivity for analyzing low-abundance metabolites in large volumes of complex urine samples.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

One-step, reagent-free construction of nano-enzyme as visual and reusable biosensor for oxidase substrates

Ke Quan, Yuqing Zeng, Wenke Zhang, Fengfeng Li, Mengjiao Li, Zhihe Qing, Linlin Wu

Summary: In this study, a visual and reusable biosensor was developed for detecting substrates that are closely associated with human physiological health. The immobilized oxidase showed higher stability and sensitivity under harsh conditions, enabling reliable detection of substrates in complex fluids.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

A three-in-one versatile sensor for concise detecting biogenic amines and beef freshness

Dongjuan Wang, Xiuqian Ding, Jinling Xie, Juan Wang, Guanhao Li, Xin Zhou

Summary: In this study, a three-in-one sensor was developed for real-time detection of biogenic amines (BAs) with high sensitivity and selectivity. The sensor showed multimodal responses and could be used to fabricate portable devices for on-site non-destructive assessment of food spoilage indicators.

ANALYTICA CHIMICA ACTA (2024)

Article Chemistry, Analytical

Development of a regenerable dual-trigger tripedal DNA walker electrochemical biosensor for sensitive detection of microRNA-155

Jinting Meng, Zihao Xu, Shasha Zheng, Hongqun Yang, Tianfu Wang, Hong Wang, Yingwei Zhang

Summary: This study demonstrates the development of a cascade signal amplification system using a multi-pedal DNA walker and strand displacement reactions for the electrochemical detection of miRNA-155. The biosensor exhibited high sensitivity, selectivity, and the potential for clinical applications.

ANALYTICA CHIMICA ACTA (2024)