Article
Chemistry, Multidisciplinary
Jia-Hang Wu, Chun-Li Hu, Ting-Kun Jiang, Jiang-Gao Mao, Fang Kong
Summary: An ordered transition metal fluoroantimonite, K2SbMoO2F7, with high birefringence has been synthesized using the cationic size effect of alkali metals. The compound exhibits excellent transparency in the mid infrared range, making it a promising material for birefringent applications.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Inorganic & Nuclear
Vidyanshu Mishra, Dundappa Mumbaraddi, Abishek K. Iyer, Arthur Mar
Summary: The ternary rare-earth indium selenides RE3InSe6 were synthesized through reactions of the elements at 850 degrees C, with rare-earth substitution range determined to be RE = La-Nd, Sm, Gd, Tb. X-ray diffraction analysis of La3InSe6, Ce3InSe6, and Nd3InSe6 single crystals revealed an orthorhombic structure in space group Pnnm, with two types of linear stacks separated by RE cations. Diffuse reflectance spectroscopy showed that all members of RE3InS6 are semiconductors with optical band gaps of 1.2-1.4 eV, and magnetic measurements indicated different magnetic properties for La3InSe6 and Nd3InSe6.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Chenlin Lu, Basudev Maity, Xue Peng, Nozomi Ito, Satoshi Abe, Xiang Sheng, Takafumi Ueno, Diannan Lu
Summary: The authors synthesized and characterized a multinuclear Au nanocluster using a 4-fold symmetric axis channel of an apo-ferritin cage as a scaffold, and identified key protein residues during the Au accumulation process.
COMMUNICATIONS CHEMISTRY
(2022)
Article
Crystallography
Ihsan Ullah, Jong Won Shin, Ryuya Tokunaga, Shinya Hayami, Hye Jin Shin, Kil Sik Min
Summary: A one-dimensional (1D) and a two-dimensional (2D) coordination polymer were synthesized by reacting Cu(CH3COO)(2)·H2O/Cu(NO3)(2)·3H2O with bis(4-pyridyl)benzylamine (bpba). The Cu(II) ions in the polymers have different coordination structures leading to distinct emission properties. The type of coordination geometry significantly affects the emission behaviors in the polymers.
Article
Chemistry, Inorganic & Nuclear
Jian-Jun You, Fang-Fang Li, Xia-Yun Zeng, Yu-Peng Liu, Si-Han Lin, Neng-Bin Hua, Qian-Ting Wang, Li-An Ma, Lei Zhang
Summary: Cage-based metal-organic frameworks are in high demand due to their intriguing architectures and properties. A novel copper-organic framework has been successfully obtained and shows high CO2 selective adsorption.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Hui-Sheng Wang, Ke Zhang, Jia Wang, Zhaobo Hu, You Song, Zaichao Zhang, Zhi-Quan Pan
Summary: A novel complex and a 1D chain structure based on a specific subunit were obtained in this study. The Dy-III ions in the complexes exhibit a distorted square antiprism coordination geometry, leading to field-induced single ion magnet behavior with higher effective energy barrier values. The moderate single ion magnet performance of the complexes is attributed to the compressed coordination environment, dipole-dipole interactions, and the deviation of the anisotropic axes from the S-8 axis.
Article
Chemistry, Multidisciplinary
Daniel Ejarque, Teresa Calvet, Merce Font-Bardia, Josefina Pons
Summary: This study systematically investigated the synthesis of fluorescent coordination complexes using Cd(II) ion and various pyridine ligands. The results showed that the fluorescence enhancement effect and the electronegativity of Cd(II) ion helped to prevent fluorescence quenching.
Article
Chemistry, Physical
Christopher L. Rom, Rebecca W. Smaha, Celeste L. Melamed, Rekha R. . Schnepf, Karen N. Heinselman, John S. Mangum, Sang-Jun Lee, Stephan Lany, Laura T. Schelhas, Ann L. Greenaway, James R. . Neilson, Sage R. Bauers, Adele C. Tamboli, Jennifer S. Andrew
Summary: We predict and realize a new magnetic and semiconducting material, MnSnN2, through combinatorial sputtering of thin films. MnSnN2 exhibits a wide composition tolerance, with a single-phase region of 20% < Mn/(Mn + Sn) < 65%. The material shows a wurtzite-like crystal structure with cation disorder and has an optical absorption onset of 1 eV, consistent with the computationally predicted 1.2 eV bandgap. Resistivity and Hall effect measurements confirm the semiconducting nature of MnSnN2 and reveal complex charge transport mechanisms. Magnetic susceptibility measurements show a low-temperature magnetic ordering transition and strong antiferromagnetic correlations in MnSnN2, contrasting with previous studies on cation-ordered MnSiN2 and MnGeN2.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Ziyi Chen, Dajiang Mei, Xiaoming Jiang, Jun Zhao, Yuandong Wu, Jihu Wang, Shaoguo Wen
Summary: The quaternary chalcogenide LiGaSiS4 was prepared through a high-temperature reaction and exhibits good thermal stability and a large band gap. The crystal structure of LiGaSiS4 is based on a three-dimensional framework and the optical properties are closely related to the characteristics of the chemical bonds.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Chemistry, Physical
Xiaohui Li, Xianyi Wei, Xiaoge Wang, Chenjie Lou, Wenda Zhang, Jungu Xu, Zhaoji Luo, Mingxue Tang, Sihao Deng, Lunhua He, Xianran Xing, Junliang Sun, Xiaojun Kuang
Summary: A new mellite interstitial oxide ion conductor Ca2-xLaxGa2GeO7+x/2 was developed by substituting La3+ for Ca2+ in Ca2Ga2GeO7, and it exhibited interstitial oxide ion conductivities similar to those in pure gallate melilite interstitial oxide ion conductors but with lower conductivity due to the mixed GaO4 and GeO4 tetrahedral layers being unfavorable for the accommodation and transportation of interstitial oxygens.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Inorganic & Nuclear
Mei Yan, Ru-Ling Tang, Wenlong Liu, Sheng-Ping Guo
Summary: Regulating the O/F ratio in Nb-O-F units can improve the nonlinear optical effects of barium niobium oxyfluorides and achieve larger second harmonic generation intensities and wide band gaps.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Xian-Feng Sun, Jing-Jing Chen, Dan Gao, Li-Na Zheng, Bin Liu, Bo Liu, Tao Ding
Summary: With a symmetrical aromatic carboxylic acid ligand, three Co(ii)-based metal-organic frameworks were successfully synthesized, each possessing diverse secondary structural units. These frameworks exhibit selective adsorption for C2H2 and CO2 at 273 and 298 K, and their magnetic properties have been thoroughly examined.
Article
Chemistry, Inorganic & Nuclear
Mariia Struhatska, Iryna Olyshevets, Nataliia Kariaka, Viktoriya Dyakonenko, Irina Konovalova, Svitlana Shishkina, Sergii Smola, Nataliia Rusakova, Vladimir Ovchynnikov, Tetiana Yu Sliva, Vladimir M. Amirkhanov
Summary: New cationic lanthanide(III) complexes with the general formula [Ln(L)(2)(bipy)(2)]BPh4 (where Ln = Eu, Tb) were synthesized and characterized. The X-ray diffraction analysis revealed that both complexes have octacoordinated lanthanide ions in a square antiprismatic coordination environment. The compounds [Eu(L)(2)(bipy)(2)]BPh(4) and [Tb(L)(2)(bipy)(2)]BPh(4) exhibit intense red and green photoluminescence, respectively, with decay times over milliseconds.
INORGANICA CHIMICA ACTA
(2022)
Article
Chemistry, Multidisciplinary
Daiki Shimauchi, Takeshi Yatabe, Yuka Ikesue, Yuu Kajiwara, Taro Koide, Tatsuya Ando, Ki-Seok Yoon, Hidetaka Nakai, Seiji Ogo
Summary: The paper presents an Ir complex that can extract electrons from H-2 at room temperature and store them as a H2-derived energy carrier. Additionally, the paper demonstrates the reduction of CO2 to a metal-CO(2)(2-) species by this complex at room temperature and provides the first electrospray ionisation mass spectrum for this compound.
CHEMICAL COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Tushagu Abudouwufu, Xiangyu Zhang, Wenbin Zuo, Vasiliy Pelenovich, Jinbao Luo, Yueqiang Lan, Canxin Tian, Changwei Zou, Alexander Tolstoguzov, Dejun Fu
Summary: This study focused on the structure and ion emission behavior of a copper ion-conducting solid electrolyte, Rb4Cu16I7Cl13, prepared via mechano-chemical ball milling. The solid electrolyte showed an ionic conductivity of approximately 0.213 S/cm at room temperature and a melting temperature of 229.7 degrees C. Ion current measurements revealed a linear correlation between current and voltage, following the Schottky model. Copper nanoparticle deposition was observed on a silicon sample irradiated by the ion beam.
Article
Materials Science, Ceramics
Camila Tavares Brasileiro, Humberto Dias de Almeida Filho, Geovana Lira Santana, Ana Virginia Lot, Sonia Conte, Chiara Zanelli, Michele Dondi, Anselmo Ortega Boschi
Summary: The study investigates the effects of replacing feldspar with sericite in porcelain stoneware. Results indicate that at higher temperatures, porcelain stoneware batches made with sericite and feldspar exhibit similarities in phase composition, microstructure, melt chemical composition, and physical properties.
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2022)
Article
Green & Sustainable Science & Technology
Sossio Fabio Graziano, Chiara Zanelli, Chiara Molinari, Bruno De Gennaro, Gaspare Giovinco, Cecilia Correggia, Piergiulio Cappelletti, Michele Dondi
Summary: This study evaluates different lightweight concretes formulated with lightweight expanded aggregates produced from industrial waste for the first time, demonstrating the feasibility of using waste-based aggregates in lightweight concrete design.
JOURNAL OF CLEANER PRODUCTION
(2022)
Review
Engineering, Environmental
Matteo Ardit, Chiara Zanelli, Sonia Conte, Chiara Molinari, Giuseppe Cruciani, Michele Dondi
Summary: This study quantitatively examines the benefits and drawbacks of incorporating hazardous elements into silicate ceramics. The mobility of various HEs is parameterised, showing that silicate ceramics have high immobilisation efficiency but some elements may exceed permissible limits. Further studies are needed to develop appropriate inertisation strategies for these elements.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Elena Spagnoli, Andrea Gaiardo, Barbara Fabbri, Matteo Valt, Soufiane Krik, Matteo Ardit, Giuseppe Cruciani, Michele Della Ciana, Lia Vanzetti, Gabriele Vola, Sandro Gherardi, Pierluigi Bellutti, Cesare Malagu, Vincenzo Guidi
Summary: This study aims to design a sensing film for high-sensitivity H-2 detection. Metal-oxide solid solutions were synthesized and modified to improve the sensing properties. The sensor with the lowest content of Nb exhibited extremely high sensitivity toward H-2, paving the way for H-2 ppb detection.
Article
Engineering, Chemical
Elisa Mercadelli, Angela Gondolini, Matteo Ardit, Giuseppe Cruciani, Cesare Melandri, Sonia Escolastico, Jose M. Serra, Alessandra Sanson
Summary: This study investigated the hydrogen permeation of BCZY-GDC asymmetric membranes for 100 hours using wet 15% CO2 in Ar as the sweep gas. The results showed that the asymmetric membranes exhibited promising and stable hydrogen permeation flux values under the test conditions, and no structural or morphological changes were detected after the testing.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Materials Science, Ceramics
Matteo Ardit, Chiara Molinari, Daniele Verucchi, Alice Tintorri, Michela Migliori, Tanya Toschi, Sonia Conte, Chiara Zanelli, Giuseppe Cruciani, Michele Dondi
Summary: The advent of inkjet printing has changed the industrial decoration technology and requires companies to modify the colorant production process. This study investigates the effects of micronization on industrial ceramic colorants and finds that the efficiency and stability of the colorants are related to their intrinsic properties. The results also show that the particle breakage and deformation during comminution depend on the material's crystal habit and elastic features.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Andrea Bartoletti, Angela Gondolini, Nicola Sangiorgi, Matteo Aramini, Matteo Ardit, Marzio Rancan, Lidia Armelao, Simon A. Kondrat, Alessandra Sanson
Summary: The surface area of CaCu3Ti4O12 increased significantly after ball milling, which also introduced more structural defects. The milled sample showed notably higher photocatalytic degradation efficiency than the as-synthesized sample for both rhodamine B and cetirizine hydrochloride, even after normalisation for surface area. The improved catalytic performance can be attributed to the structural defects observed.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Sonia Conte, Chiara Molinari, Matteo Ardit, Giuseppe Cruciani, Michele Dondi, Chiara Zanelli
Summary: This study compared the sintering mechanisms and kinetics, phase and microstructure evolution, and high temperature stability of five porcelain and porcelain stoneware bodies. The results showed that porcelain and porcelain stoneware exhibited different behaviors during sintering, with distinct phase evolution and melt composition/structure. The firing behavior of porcelain was primarily controlled by microstructural features, while the sintering behavior of porcelain stoneware was mainly governed by the physical and chemical properties of the melt, which depended on the stability of quartz and mullite at high temperature.
Article
Crystallography
Nicola Precisvalle, Maura Mancinelli, Matteo Ardit, Giada Beltrami, Lara Gigli, Alfredo Aloise, Enrico Catizzone, Massimo Migliori, Girolamo Giordano, Vincenzo Guidi, Annalisa Martucci
Summary: ZSM-5 zeolite undergoes a polymorphic phase transition from monoclinic to orthorhombic upon heating, which can be influenced by adsorbate molecules. ZSM-5 zeolite has various applications, including catalysis and adsorption, where high thermal stability is required.
Article
Chemistry, Inorganic & Nuclear
Matteo Ardit, Sonia Conte, Donato Belmonte, Francesca Menescardi, Simone Pollastri, Giuseppe Cruciani, Michele Dondi
Summary: This research investigates the high-pressure behavior of the Ca(Ti0.95Ge0.05)O-3 perovskite and discovers that it exhibits both isotropic compression and nonlocked tilting. The study combines experimental data, density functional theory calculations, and X-ray techniques to understand the structural evolution of the perovskite under pressure. The findings provide valuable insights into the behavior of locked-tilt perovskites and establish an efficient method for studying complex high-pressure systems.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Physical
N. Precisvalle, G. Beltrami, M. Ardit, C. Giacobbe, L. Pasti, T. Chenet, A. Martucci
Summary: In this study, the acid form of zeolite L (H-LTL) was characterized structurally by synchrotron X-ray diffraction. The results showed significant changes in the channel aperture and host-guest interactions during heating. The formation of Lewis acid sites from the conversion of Bronsted sites was observed, indicating the high thermal stability and adaptability of the acidic L-zeolite.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Applied
Maura Mancinelli, Nicola Precisvalle, Matteo Ardit, Giada Beltrami, Lara Gigli, Enrico Catizzone, Massimo Migliori, Girolamo Giordano, Annalisa Martucci
Summary: The thermal stability and high temperature structural evolution of highly crystallized ZSM-5 zeolite were investigated using in situ synchrotron (X-Ray) powder diffraction. The results showed that template calcination does not cause significant variations in the framework geometry and channel shape, confirming the high thermal stability of the zeolite. In addition, thermal analysis provided insights into the effect of aluminum content on the interaction between the template and zeolite structure.
MICROPOROUS AND MESOPOROUS MATERIALS
(2023)
Article
Engineering, Environmental
Maura Mancinelli, Claudia Stevanin, Matteo Ardit, Tatiana Chenet, Luisa Pasti, Annalisa Martucci
Summary: The adsorption efficiency of Y-type zeolites with different silica/alumina ratios towards perfluorooctanoic acid and perfluorooctane sulfonate was studied. The results showed that these materials can be successfully used for the decontamination of water from perfluoroalkyl chemicals. Additionally, the introduction of silver onto the zeolites improved the performances in removing PFAS from water.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)