Zircon U-Pb age and O isotope evidence for Neoproterozoic low-O-18 magmatism during supercontinental rifting in South China: Implications for the snowball Earth event

Identification of Neoproterozoic low delta O-18 igneous rocks is a key to demonstrate that high-T water-rock interaction and low-O-18 magmatism in rift tectonic zones can serve as an efficient interface to transport heat and material from the Earth's interior to exterior at the onset of the snowball Earth event. Low delta O-18 values of - 10.9 to +4.4 permil characteristic of meteoric origin were observed, on an areal extent over 30,000 km(2), for mid-Neoproterozoic metaigneous zircons from the ultrahigh-pressure eclogite-facies metamorphic belt of Triassic ages along the Dabie-Sulu orogenic belt, China. Although the zircon O isotope system could be reset to acquire its low delta O-18 values by exchange with matrix minerals during wet eclogite-facies metamorphism, the abnormal O-18 depletion is confirmed by occurrence of Neoproterozoic low delta O-18 zircons in low-grade metaigneous rocks in the same belt. Cathodoluminscence imaging of zircons from low-grade metagranitoid and metavolcanic rocks shows preservation of the internal structures of oscillatory zoning typical of magmatic origin. Hornblende from two granites of low delta O-18 zircons gave Ar-Ar plateau ages of 747 +/- 6 and 776 +/- 12 Ma, ruling out that Phanerozoic metamorphism effected mineral 0 isotope values. Two groups of U-Pb ages were measured at 756 +/- 5 Ma and 782 +/- 5 Ma, respectively, for the low delta O-18 zircons. This indicates that low delta O-18 zircons crystallized during two episodes of low-O-18 magmatism in response to tectonic evolution from supercontinental rifting at similar to 780 Ma to breakup at similar to 750 Ma. The second episode of low-O-18 magmatism is contemporaneous with the continental Kaigas iceage. A plate-rift model is advanced to account for the tectonic connection between the low-O-18 magmatism, the continental glaciation and the supercontinental. rifting during the Cryogenian period. High-T meteoric water-rock interaction occurred prior to low-O-18 magmatism in rift tectonic zones, and caldera collapse was responsible for melting of hydrothermally altered low delta O-18 rocks during rifting of the South China Block from the Rodinia supercontinent.