4.7 Article

Combined effects of environmental vibrations and hygrothermal fatigue on mechanical damage in PEM fuel cells

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 40, Issue 4, Pages 1911-1922

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2014.11.125

Keywords

Vibration; Damage propagation; Humidity and temperature cycles; Fatigue; Polymer electrolyte membrane fuel cell; Cohesive elements

Funding

  1. Natural Sciences and Engineering Research Council of Canada (NSERC)
  2. Canada Foundation for Innovation (CFI)
  3. University of Toronto
  4. Ontario Ministry of Research and Innovation (Early Researcher Award)
  5. Ontario Graduate Scholarship (OGS) program
  6. Bert Wasmund Graduate Fellowship

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Automotive polymer electrolyte membrane (PEM) fuel cells are exposed to high magnitude road-induced impact loads and vibrations as well as high-level cyclic stresses due to humidity and temperature (hygrothermal) variations. The consequent plastic strain can exacerbate defects and may result in operational failure. In this study, a two-dimensional finite element model based on cohesive zone theory was employed to investigate the combined effects of hygrothermal cycle amplitude and amplitude and frequency of external vibrations on damage propagation. The simultaneous presence of hygrothermal cycles and vibrations severely intensified damage propagation within the expected fuel cell lifetime. Compared with applied vibrations, hygrothermal cycles produced a dominating effect on degradation. Under hygrothermal cycling, membrane cracks experienced more severe propagation compared to delaminations, while vibrations had a more significant effect on delaminations compared to cracks. The presence of a channel offset led to a 2.5-fold increase in delamination length compared to a case with no channel offset. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

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